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91.
Guo P Zhu G Song H Chen X Zhang S 《Physical chemistry chemical physics : PCCP》2011,13(39):17818-17824
Graphene nanosheets (GNSs) loading graphene-encapsulated iron microspheres (GEIMs) were fabricated by heat treatment of graphene oxide nanosheets (GONs) with ferric trichloride (FeCl(3)). The special pentagon-hexagonal graphene shells have been produced by precipitation of carbon from metal carbide solutions, thanks to the high reactivity of GONs and ferric nanoparticles dispersing homogeneously between graphene layers. The morphology, structure and elemental composition of GEIMs were investigated by scanning electron microscope, X-ray diffraction and electron energy disperse spectroscope, respectively. The formation mechanism of GEIMs was proposed. Hollow graphene microspheres (HGMs) on the GNSs were obtained with the removal of ferric species in GEIMs. When used as the anode materials for lithium-ion batteries, the almost graphitic HGMs exhibit stable voltage platform at ca. 0.2 V, excellent cycle capability and higher reversible capacity of about 440 mAh g(-1) after 50 cycles and possess great potential application in lithium-ion batteries. 相似文献
92.
苄嘧磺隆印迹聚合物的波谱分析及吸附性能研究 总被引:2,自引:0,他引:2
以苄嘧磺隆为模板分子, α-甲基丙烯酸为功能单体, 三甲氧基丙烷三甲基丙烯酸酯为交联剂, 二氯甲烷为致孔剂, 在20 ℃温度下, 采用紫外引发沉淀聚合方法制备了苄嘧磺隆分子印迹聚合物. 紫外光谱和核磁共振氢谱实验提示了聚合前模板分子与功能单体之间的相互作用主要是分子间氢键, 分子间氢键相互作用能和双氢键的键距由Hyperchem 7.0和Gaussian 03W软件分别计算为: -28.6163 kJ/mol和0.179~0.181 nm. 制备的印迹聚合物在高效液相色谱和吸附动力学实验中都表现出对模板分子有较强的吸附作用. 相似文献
93.
94.
多孔介质结构对渗流惯性效应的影响规律研究 总被引:1,自引:0,他引:1
本文通过局部展开算法研究了多孔介质中排列结构对非线性渗流规律的影响.计算结果表明:规则排列结构的渗流标度律和渗流方向相关,然而非规则排列结构的渗流标度律不依赖于渗流方向而只依赖于多孔介质的几何结构.伴随着排列结构的非规则程度增强,不同方向的渗流阻力变化规律的差异性减小.当流场输运区域较为复杂且不存在较宽直通道时,渗流阻力在较宽雷诺数范围内体现出较为明显的标度律特性.周期性强非规则排列结构中不同区域大小的模型却具有相似的渗流阻力的标度律特性,同时标度律特性与孔隙度的大小相关性不大.阻力非线性标度律由多孔介质结构的不同而取值为2至3之间. 相似文献
95.
新兴有机污染物(Emerging organic contaminants,EOCs)是对人体健康及生态环境具有潜在或实质威胁的新型化学污染物.由于其被频繁使用且能在水生生态系统中持久性存在而对水生生物健康和安全造成严重威胁,故引起大众越来越多的关注.以活性污泥法为代表的传统水处理工艺通常不足以消除这些新兴有机污染物.... 相似文献
96.
In this study,218Ac and 221Th nuclides were produced via the heavy-ion induced fusion evaporation reaction 40Ar+186W.Their decay properties were studied with the help of the gas-filled recoil spectrometer SHANS and a digital data acquisition system.The cross section ratio between 222Pa and 218Ac was extracted experimentally,withmeasured value 0.69(9).Two new possible α decay branches to 221Th are suggested.The valence neutron configurations for the daughter 217Ra are discussed in terms of the hindrance factors. 相似文献
97.
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99.
Xiaohong YangHaitao Fu Aibing YuXuchuan Jiang 《Journal of colloid and interface science》2012,387(1):74-83
This study demonstrates a facile and effective method to generate mono-dispersed titanium dioxide spheres at ambient conditions. The size of the colloids can be controlled from 60 to 500 nm by optimizing experimental parameters (e.g., concentration, time, and temperature). Anatase TiO2 can be obtained through titanium glycolate colloids generated in acetone via two ways: water boiling approach and calcination at a high temperature of 500 °C. Particle characteristics (shape, size, and size distribution) were measured by advanced techniques, including transmission electron microscope (TEM), thermo-gravimetric analysis (TGA), UV/Vis absorption spectrum, nitrogen gas adsorption and desorption isotherms Brunauer-Emmett-Teller (BET) surface area measurement, and X-ray diffraction technique (XRD). The possible mechanism of nucleation and growth of such colloids was discussed. The role of acetone in the formation and growth of titanium glycolate colloids was also investigated by Fourier transform infrared (FT-IR) spectroscopy. Finally, the photocatalysis performance of such anatase TiO2 particles was tested and proved to be efficient in degradation of organic dyes (e.g., phenolphthalein and methly orange). 相似文献
100.
High-throughput approaches for the discovery and optimization of new olefin polymerization catalysts
Murphy V Bei X Boussie TR Brümmer O Diamond GM Goh C Hall KA Lapointe AM Leclerc M Longmire JM Shoemaker JA Turner H Weinberg WH 《Chemical record (New York, N.Y.)》2002,2(4):278-289
The discovery of new olefin polymerization catalysts is currently a time-intensive trial-and-error process with no guarantee of success. A fully integrated high-throughput screening workflow for the discovery of new catalysts for polyolefin production has been implemented at Symyx Technologies. The workflow includes the design of the metal-ligand libraries using custom-made computer software, automated delivery of metal precursors and ligands into the reactors using a liquid-handling robot, and a rapid primary screen that serves to assess the potential of each metalligand-activator combination as an olefin polymerization catalyst. "Hits" from the primary screen are subjected to secondary screens using a 48-cell parallel polymerization reactor. Individual polymerization reactions are monitored in real time under conditions that provide meaningful information about the performance capabilities of each catalyst. Rapid polymer characterization techniques support the primary and secondary screens. We have discovered many new and interesting catalyst classes using this technology. 相似文献