胶束增稳荧光法同时测定厚朴酚及和厚朴酚同分异构体

作者首次提出在十二烷基硫酸钠（ＳＤＳ）的醋酸－醋酸钠（ｐＨ＝４）缓冲溶液中,利用厚朴主和厚朴的荧光光谱差异性特征,建立了胶束增稳荧光法,可在二者同时存在下,不增加分离手续,达到同时测定的目的。该法具有灵敏度高、检测限低、线性范围宽等特点。本文 此新方法应用于兔血中痕量厚朴酚及和厚朴酚含量的２４ｈ检测,绘制了药时曲线,结果令人满意。     

Effect of Elastomeric Nanoparticles on Toughness and Heat Resistance of Epoxy Resins

A new composite consisting of epoxy resin and elastomeric nanoparticles with high toughness and high heat‐distortion temperature is prepared. The size of the nanoparticles used was less than 90 nm. The excellent properties of the composite seem to be due to stronger interactions between the carboxyl groups of the nanoparticles and the epoxy groups of the resin, and to enhanced hydrogen bonding between the nitrile groups of the rubber and the hydroxyl groups of the resin.     

A highly selective and sensitive chemiluminescent probe for leucine aminopeptidase detection in vitro,in vivo and in human liver cancer tissue

Leucine aminopeptidase (LAP) is involved in tumor cell proliferation, invasion, and angiogenesis, and is a well-known tumor marker. In recent years, chemiluminescence has been widely used in the field of biological imaging, due to it resulting in a high sensitivity and excellent signal-to-noise ratio. Here, we report the design, synthesis, and evaluation of the first LAP-activated chemiluminescent probe for LAP detection and imaging. The probe initially had no chemiluminescence but produced an extremely strong chemiluminescence after the release of the dioxetane intermediate in the presence of LAP. The probe had high selectivity over other proteases and higher signal-to-noise ratios than commercial fluorophores. Real-time imaging results indicated that the chemiluminescence was remarkably enhanced at the mice tumor site after the probe was injected. Furthermore, the chemiluminescence of this probe in the cancerous tissues of patients was obviously improved compared to that of normal tissues. Taken together, this study has developed the first LAP-activable chemiluminescent probe, which could be potentially used in protein detection, disease diagnosis, and drug development.

The first chemiluminescent probe for the detection of LAP is described. It shows a highly selective, sensitive and rapid chemiluminescence response for the detection of LAP in vitro and in vivo, and enables the differentiation of liver cancer.     

101Pd的能级结构研究以及与其邻近核素的系统性对比

在本工作中,我们主要研究了101Pd核中$ \nu_{11/2} $带的能级结构,并与临近同位素相对应的能级结构进行了对比。研究发现在Pd同位素链,即$ N\!= \!Z\! =\! 50 $的壳附近,三轴形变的演变符合很好的系统性,即从小的不稳定形变逐渐演变为稳定的长椭形变。同时,我们也做了总势能面(TRS)随着原子核转动频率以及中子数变化的系统计算,结果也支持该核区不稳定三轴形变演化的规律。     

飞秒条纹变相管的设计

设计了一种飞秒条纹变相管.采用静电聚焦,用Monte Carlo方法对光电子的初能量、初角度以及初位置进行抽样;用有限差分法计算阴极和栅极之间以及偏转板之间的电场分布;用四阶Lunge-Kutta法模拟跟踪大量（3000个）光电子的运行轨迹;统计分析了3000个电子在最佳像面上的时间分布、位置分布;给出了变相管的空间调制传递函数、时间分辨能力等基本参量.其时间分辨能力可望达到290.4 fs.     

碘量法测定维生素C含量微型实验研究

对大学分析化学实验中维生素C的碘量法测定进行了微型化设计及可行性研究,与常量法比较,微型实验的精密度与准确度符合分析实验要求.     

纳米碳酸钙的生产和用途

碳酸钙是自然界广泛存在的一种很普通的非金属材料,也是一种传统的无机盐化工产品。近年来,随着碳酸钙的超细化及表面改性技术的发展,纳米碳酸钙制备技术及应用,已成为国内外竞相开发的研究热点。本文就有关纳米碳酸钙的主要生产技术及其应用领域作一简介。     

淹没磨料射流的空泡运动分析

通过对淹没条件下磨料射流的空泡运动分析研究,建立了淹没磨料射流的空泡运动方程,揭示了淹没磨料射流中空泡的溃灭特性,数值模拟了淹没磨料射流的磨料体积浓度以及空泡所处流场压力对空泡运动及溃灭的影响规律.分析表明:淹没磨料射流中磨料的存在增大流体的粘性系数,增大空泡溃灭历时,减弱射流的空蚀破坏能力;流场压力的改变对空泡溃灭过程影响显著,压力越高,空泡溃灭历时越短.     

Dynamics of a plastic-impact system with oscillatory and progressive motions

A mathematical model is developed to describe oscillatory and progressive motions in dynamics of a plastic impact oscillator with a frictional slider. Dynamics of the impact oscillator is analyzed by a five-dimensional map, which describes free flight and sticking solutions of two masses of the system, between impacts, supplemented by transition conditions at the instants of impacts. Piecewise property and singularity are found to exist in the Poincaré map. The piecewise property is caused by the transitions of free flight and sticking motions of impacting masses immediately after the impact, and the singularity of the map is generated via the grazing contact of impacting masses immediately before the impact. These properties of the map have been shown to exhibit particular types of sliding and grazing bifurcations of periodic-impact motions under parameter variation. The influence of piecewise property, grazing singularities and various parameters on dynamics of the vibro-impact system is analyzed. The global bifurcation diagrams for before-impact velocity versus forcing frequency are plotted to predict much of the qualitative behavior of the system. The global bifurcations of period-n single-impact motions of the plastic-impact oscillator are found to exhibit extensive and systematic characteristics.     

Evanescent energy in square and circular fibers

A finite element method is presented to find the propagation characteristics of an optical fiber with arbitrary cross section. This method uses a non-local boundary operator to reduce the infinite problem (open waveguide) to a bounded one. Evanescent energy in circular and square fibers of the same core area are computed and compared to show that square fibers can be effectively used in single molecule detection.