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991.
电镀液和电镀层中钯和钴的分光光度法同时测定 总被引:2,自引:0,他引:2
在PH=4.5的HAc-NaAc介质中,钴和钯都能与2-「2-(6-甲基苯并噻唑)偶氮」-5-「N-甲基-N-乙羧基」苯甲酸(简称MCB)形成络合物。在λ=710nm处Co-MCB不吸收;在610.5nm处Co-MCB有最大吸收,而Pd-MCB也有一定的吸收值。利用这一差异,在可610.5nm处测定Pd和Co的合量,而在710nm处测定Pd的含量学与化学传感再利用系数法算出Co的含量。测定了纯性范 相似文献
992.
993.
994.
Xiao‐Ding Xu Bing‐Bing Lin Jun Feng Ya Wang Si‐Xue Cheng Xian‐Zheng Zhang Ren‐Xi Zhuo 《Macromolecular rapid communications》2012,33(5):426-431
A glucose oxidase (GOx)‐mediated glucose metabolism was in vitro mimicked and employed to regulate the self‐assembly of peptide‐based building blocks. In this new stimuli‐responsive self‐assembly system, two peptide‐based building blocks, respectively, having aspartic acid (gelator 1 ) and lysine (gelator 2 ) residues were designed and prepared. When adding glucose and GOx to the aqueous solution of gelator 1 or the self‐assembled fibrillar hydrogel of gelator 2 to construct glucose metabolism system, the metabolic product (gluconic acid) can trigger the protonation of the peptide molecules and induce the phase transitions of gelators 1 (sol‐gel) and 2 (gel‐sol). Because this glucose metabolism regulated peptide self‐assembly is built on the oxidation of glucose, it can be used as a simple visual biosensor for glucose detection. 相似文献
995.
Nanosized Spinel Li4Ti5O12 Anode Material Prepared by Gel-polymer Method using Furfuryl Alcohol as Polymerizable Solvent 下载免费PDF全文
Nanosized Li4Ti5O12 powders are synthesized by a polymerization-based method using ti-tanium butoxide and lithium nitrate as precursors and furfuryl alcohol as a polymerizable solvent. The prepared samples are characterized by X-ray diffraction, scanning electron mi-croscopy, transmission electron microscopy and Braunauer-Emmett-Teller (BET) analysis. The electrochemical performances of these Li4Ti5O12 powders are also studied. The effect of different surfactants including citric acid, polyvinylpyrrolidone, and cetyltrimethyl am-monium bromide on the structure and properties is also investigated. It is found that pure spinel phase of Li4Ti5O12 is obtained at an annealing temperature of 700 oC or higher. The use of surfactants can improve the powder morphology of nanosized particles with less ag-glomeration. With suitable annealing temperature and the addition of surfactant, Li4Ti5O12 powders with high BET surface area and favorable electrochemical performance can be ob-tained. 相似文献
996.
NBR/ORGANOMODIFIED BENTONITE INTERCALATED HYBRIDS AND THEIR EFFECTS ON THE TOUGHNESS OF PVC 总被引:4,自引:0,他引:4
Hybrids of intercalative nitrile-butadiene rubber/organomodified bentonite (NBR/OMB) were prepared by thelatex intercalation technique. Investigation of their mechanical properties and the microstructore of NBR/OMB showed thatthe organomodified bentonite is an effective toughener for NBR. Transmission electronic microscopy (TEM) and X-rnydiffraction (XRD) tests showed that the NBR macromolecule could be intercalated into the galleries of bentonite.Incorporation of NBR/OMB hybrids as tougheners into poly(vinyl chloride) (PVC) results in a substantial increase in theimpact strength of PVC, but little decrease in its tensile strength and flexural strength, compared to the unmodified PVC. 相似文献
997.
Yong Ding Antisar R. Hlil Allan S. Hay 《Journal of polymer science. Part A, Polymer chemistry》1998,36(8):1201-1208
Novel poly(arylene ether)s, poly(arylene thioether)s, and poly(arylene sulfone)s were synthesized from the dihydroxy(imidoarylene) monomer 1 . The syntheses of poly(arylene ether)s were carried out in DMAc in the presence of anhydrous K2CO3 by a nucleophilic substitution reaction between the bisphenol and activated difluoro compounds. Poly(arylene thioether)s were synthesized according to the recently discovered one-pot polymerization reaction between a bis(N,N′-dimethyl-S-carbamate) and activated difluoro compounds in the presence of a mixture of Cs2CO3 and CaCO3. The bis(N,N′-dimethyl-S-carbamate) 3 was synthesized by the thermal rearrangement reaction of bis(N,N′-dimethylthiocarbamate) 2 , which was synthesized from 1 by a phase-transfer catalyzed reaction. The poly(arylene thioether)s were further oxidized to form poly(arylene sulfone)s, which would be very difficult, if not impossible, to synthesize by other methods. All of the polymers described have extremely high Tgs and thermal stability as determined from DSC and TGA analysis. Poly(arylene sulfone)s have the highest Tgs and they are in the range of 298–361°C. © 1998 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 36: 1201–1208, 1998 相似文献
998.
红外光谱法研究LB膜中的分子取向 总被引:1,自引:0,他引:1
The structure information of orientation and packing of molecular chains can be obtained from infrared transmission and reflection-absorbance (RA) spectra. In the present paper, on the basis of Umemura et al., their FORTRAN program of minicomputer was developed and can be run on 486 personal computer. By comparison of infrared transmission and RA intensities, surface enhancement factors and molecular orientation angle were calculated using the above program, and the influence of complex refractive index, angle of incidence, and thickness of LB film were discussed. These results are consistent with that of Umemura et al. 相似文献
999.
A series of Ba1-xSrxMyTi1-yO3 (M = Zr, Sn, 0?x?0.4, 0?y?0.3) solid solutions were synthesized with the soft chemical method below 100 °C. XRD pattern and cell parameters-composition figures of the prepared powder demonstrate that they are completely miscible solid solutions based on BaTiO3. Furthermore, TEM shows that they have a shape of uniform, substantially spherical particles with an average particle size of 70 nm in diameter. The sintered ceramics of the powder doped with Sr2+and Zr4+ or Sn4+ have dielectric constant eight times higher and dielectric loss thirty per cent lower than those of pure BaTiO3 phase at room temperature. 相似文献
1000.
Xianjun Liu Yi Liu Zongbiao Ding Quanrui Wang Chengzhi Zhang 《Journal of heterocyclic chemistry》2000,37(2):287-290
The title compound 4 , i.e. 9‐chloro‐4,5‐dihydro‐2‐ethyl‐1‐(2,4,6‐trichlorophenyl)‐1H‐1,2,4‐triazolo[3,2‐d]‐[1,5]benzoxazepinium hexachloroantimonate, is a novel 6‐7‐5 tricyclic heterocycle. C18H14Cl4N3O·SbCJ6, M = 764.61, P21/c(#14), a = 13.457(4), b = 11.583(2), c = 18.992(3) Å α = 90, β = 110.11(1)°, Z = 4, V = 2780(1) Å3, Dc = 1.827 g/cc, μ (MoKα) = 19.69 cm?1, F(000) = 1488.00, T = 293 K, Rint = 0.055 for 3094 independent reflections with I>3.00σ(I). The five‐membered heterocyclic ring is nearly planar, with the trichlorophenyl ring at N(2) almost perpendicular to it. However, the seven‐membered ring is not planar, but adopts a twist‐boat conformation. 相似文献