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991.
Huffer DM Chang HF Cho BP Zhang LK Chiarelli MP 《Journal of the American Society for Mass Spectrometry》2001,12(4):376-380
The product ion formation characteristics of the four diastereomeric tetrahydroxy benzo[ghi]fluoranthene compounds formed by hydrolysis of the syn and anti diastereomers of trans-3,4-dihydroxy-5,5a-epoxy-3,4,5,5a-tetrahydrobenzo[ghi]fluoranthene are studied using matrix-assisted laser desorption/ionization and post-source decay (PSD) to determine a correlation between the fragmentation characteristics of these tetraols and the structures of the diol-epoxide diastereomers from which they are hydrolyzed. The tetraols formed by the trans ring opening of the diol epoxides during hydrolysis yield product ion spectra specific for the syn and anti configurations of their precursor diol epoxides. All four diastereomeric tetraols form product ions by the losses of one and/or two water molecules in varying proportions when lithium-cationized molecule ions (m/z 301) are selected for PSD product ion analysis. The differences in the PSD spectra of these four Li+-cationized molecules are rationalized in terms of a water loss mechanism that involves the 1,2 elimination of a hydrogen atom and hydroxyl group that are cis with respect to each other on adjacent carbons. 相似文献
992.
二水草酸锌脱水的热分解动力学研究 总被引:10,自引:0,他引:10
提出一种多升温速率-等温法确定机理函数g(α)的新方法;并用迭代的等转化率法求出较为可靠的活化能Ea;在Ea和g(α)的基础上计算出指前因子A.用该法对二水草酸锌(ZnC2O4•2H2O)脱水反应的热分解动力学三因子进行了求算,得出Ea为87.22 kJ•mol-1, A为4.2120×108~7.2328×108 s-1;以及随机成核和随后生长型机理函数Am(Avrami-Erofeer),其积分形式g(α)=[-ln(1-α)] 1/m和微分形式f(α)=m(1-α)•[-ln(1-α)](1-1/m),调节因子m=1.85~2.00. 相似文献
993.
蒙旦树脂化学组成的研究 总被引:7,自引:5,他引:7
采用阴离子交换色谱和硅胶-氧化铝柱色谱对云南寻甸蒙旦树脂(XDSZ)、潦浒蒙旦树脂(LHSZ)、昭通蒙旦树脂(ZTSZ)和吉林舒兰蒙旦树脂(SLSZ)进行了族组分的分离。树脂游离酸,树脂结合酸,树脂烃和树脂醇在各树脂中的百分含量分别为XDSZ11.86,8.76,12.30,45.99;LHSZ15.89,13.91,4.90,45.99;SLSZ25.46,8.07,17.40,36.22;ZT 相似文献
994.
用具有流通池的分光光度计作测定装置,建立了由平衡移动法测定络合反应中质子释放数的新方法。方法简单、快速,仅用一个标准溶液,适于在变更pH值范围内金属离子不发生水解和没有其他副反应的体系。 相似文献
995.
多相催化反应原位红外系统及其应用 总被引:1,自引:0,他引:1
设计和建立了一套能耐高温的用于多相催化反应研究的原位红外系统,反应温度从室温到1150K,系统真空为1.0*10^5-1.0-10^-4Pa,红外光谱检测范围为4800-200cm^-1。此系统扩展了原仪器的功能,提高了仪器利用率和效率。 相似文献
996.
制备1┐氰基┐2,3,5┐三┐O┐苯甲酰基┐β┐D┐呋喃核糖的简便方法张万轩*雷策南黄锦霞陈家威(湖北大学化学系武汉430062)关键词鸟苷,制备,氰基三苯甲酰基-β-D-呋喃核糖,三甲基氯硅烷1996-08-12收稿,1997-03-05修回1-氰... 相似文献
997.
Recent breakthrough in synthesizing arbitrary vertical heterostructures of Ruddlesden–Popper (RP) perovskites opens doors to myriad quantum optoelectronic applications. However, it is not clear whether moiré excitons and flat bands can be formed in such heterostructures. Here, we predict from first principles that twisted homobilayers of RP perovskite, MA2PbI4, can host moiré excitons and yield flat energy bands. The moiré excitons exhibit unique and hybridized characteristics with electrons confined in a single layer of a striped distribution while holes localized in both layers. Nearly flat valence bands can be formed in the bilayers with relatively large twist angles, thanks to the presence of hydrogen bonds that strengthen the interlayer coupling. External pressures can further increase the interlayer coupling, yielding more localized moiré excitons and flatter valence bands. Finally, electrostatic gating is predicted to tune the degree of hybridization, energy, position and localization of moiré excitons in twisted MA2PbI4 bilayers.Excitonic states in twisted MA2PbI4 bilayers were calculated by first-principles calculations. 相似文献
998.
Klumpp DA Rendy R Zhang Y McElrea A Gomez A Dang H 《The Journal of organic chemistry》2004,69(23):8108-8110
A variety of aminoalkynes and related heterocycles are reacted in the Bronsted superacid CF(3)SO(3)H (triflic acid), and products are obtained in generally good yields (69-99%) from Friedel-Crafts-type reactions. The reactions are consistent with the formation of novel dicationic intermediates having a vinyl cationic site and an adjacent protonated N-heterocycle or ammonium cation. 相似文献
999.
1000.
Zhang Z Wang J Yuan H Gao Y Liu D Song L Xiang Y Zhao X Liu L Luo S Dou X Mou S Zhou W Xie S 《The journal of physical chemistry. B》2005,109(39):18352-18355
At a low temperature of 450 degrees C, ZnS nanoribbons have been synthesized on Si and KCl substrates by a simple chemical vapor deposition (CVD) method with a two-temperature-zone furnace. Zinc and sulfur powders are used as sources in the different temperature zones. X-ray diffraction (XRD), selected area electron diffraction (SEAD), and transmission electron microscopy (TEM) analysis show that the ZnS nanoribbons are the wurtzite structure, and there are two types-single-crystal and bicrystal nanoribbons. Photoluminescence (PL) spectrum shows that the spectrum mainly includes two parts: a purple emission band centering at about 390 nm and a blue emission band centering at about 445 nm with a weak green shoulder around 510 nm. 相似文献