全文获取类型
收费全文 | 147475篇 |
免费 | 13135篇 |
国内免费 | 7615篇 |
专业分类
化学 | 73062篇 |
晶体学 | 1385篇 |
力学 | 11032篇 |
综合类 | 310篇 |
数学 | 39410篇 |
物理学 | 43026篇 |
出版年
2024年 | 279篇 |
2023年 | 1601篇 |
2022年 | 2717篇 |
2021年 | 2787篇 |
2020年 | 3105篇 |
2019年 | 2907篇 |
2018年 | 12307篇 |
2017年 | 11953篇 |
2016年 | 9238篇 |
2015年 | 4272篇 |
2014年 | 4415篇 |
2013年 | 5597篇 |
2012年 | 10306篇 |
2011年 | 16738篇 |
2010年 | 9859篇 |
2009年 | 9983篇 |
2008年 | 10887篇 |
2007年 | 12547篇 |
2006年 | 3949篇 |
2005年 | 4384篇 |
2004年 | 3887篇 |
2003年 | 3818篇 |
2002年 | 2718篇 |
2001年 | 1704篇 |
2000年 | 1643篇 |
1999年 | 1682篇 |
1998年 | 1490篇 |
1997年 | 1432篇 |
1996年 | 1483篇 |
1995年 | 1164篇 |
1994年 | 994篇 |
1993年 | 855篇 |
1992年 | 726篇 |
1991年 | 641篇 |
1990年 | 550篇 |
1989年 | 442篇 |
1988年 | 393篇 |
1987年 | 331篇 |
1986年 | 306篇 |
1985年 | 250篇 |
1984年 | 185篇 |
1983年 | 138篇 |
1982年 | 121篇 |
1981年 | 105篇 |
1980年 | 111篇 |
1979年 | 77篇 |
1978年 | 64篇 |
1977年 | 58篇 |
1976年 | 46篇 |
1973年 | 53篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
31.
32.
Mesoscopic modeling at the pore scale offers great promise in exploring the underlying structure transport performance of flow through porous media. The present work studies the fluid flow subjected to capillarity-induced resonance in porous media characterized by different porous structure and wettability. The effects of porosity and wettability on the displacement behavior of the fluid flow through porous media are discussed. The results are presented in the form of temporal evolution of percentage saturation and displacement of the fluid front through porous media. The present study reveals that the vibration in the form of acoustic excitation could be significant in the mobilization of fluid through the porous media. The dependence of displacement of the fluid on physicochemical parameters like wettability of the surface, frequency along with the porosity is analyzed. It was observed that the mean displacement of the fluid is more in the case of invading fluid with wetting phase where the driving force strength is not so dominant. 相似文献
33.
34.
Sarah Peluse 《Israel Journal of Mathematics》2018,227(1):379-396
We prove that the group of diffeomorphisms of the interval [0, 1] contains surface groups whose action on (0, 1) has no global fix point and such that only countably many points of the interval (0, 1) have non-trivial stabiliser. 相似文献
35.
36.
Richiro Ushimaru Zhang Chen Houyuan Zhao Po-hsun Fan Prof. Dr. Hung-wen Liu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(9):3586-3590
Albomycin δ2 is a sulfur-containing sideromycin natural product that shows potent antibacterial activity against clinically important pathogens. The l -serine-thioheptose dipeptide partial structure, known as SB-217452, has been found to be the active seryl-tRNA synthetase inhibitor component of albomycin δ2. Herein, it is demonstrated that AbmF catalyzes condensation between the 6′-amino-4′-thionucleoside with the d -ribo configuration and seryl-adenylate supplied by the serine adenylation activity of AbmK. Formation of the dipeptide is followed by C3′-epimerization to produce SB-217452 with the d -xylo configuration, which is catalyzed by the radical S-adenosyl-l -methionine enzyme AbmJ. Gene deletion suggests that AbmC is involved in peptide assembly linking SB-217452 with the siderophore moiety. This study establishes how the albomycin biosynthetic machinery generates its antimicrobial component SB-217452. 相似文献
37.
Jie Lu Ju-Kang Wu Yao Jiang Dr. Peng Tan Lin Zhang Yu Lei Prof. Xiao-Qin Liu Prof. Lin-Bing Sun 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(16):6490-6496
Hierarchically porous metal–organic frameworks (HP-MOFs) are promising in various applications. Most reported HP-MOFs are prepared based on the generation of mesopores in microporous frameworks, and the formed mesopores are connected by microporous channels, limiting the accessibility of mesopores for bulky molecules. A hierarchical structure is formed by constructing microporous MOFs in uninterrupted mesoporous tunnels. Using the confined space in as-prepared mesoporous silica, highly dispersed metal precursors for MOFs are coated on the internal surface of mesoporous tunnels. Ligand vapor-induced crystallization is employed to enable quantitative formation of MOFs in situ, in which sublimated ligands diffuse into mesoporous tunnels and react with metal precursors. The obtained hierarchically porous composites exhibit record-high adsorption capacity for the bulky molecule trypsin. The thermal and storage stability of trypsin is improved upon immobilization on the composites. 相似文献
38.
Lijuan Shen Li Li Sheng Lu Xiaohan Zhang Jie Liu Junlin An Guojun Zhang Bo Wu Fei Wang 《中国颗粒学报》2015,(3):10-15
We conducted measurements of black carbon(BC) aerosol in Jiaxing,China during autumn from September 26 to November 30,2013.We investigated temporal and diurnal variations of BC,and its correlations with meteorological parameters and other major pollutants.Results showed that hourly mass concentrations of BC ranged from 0.2 to 22.0 μg/m3,with an average of 5.1 μg/m3.The diurnai variation of BC exhibited a bimodal distribution,with peaks at 07:00 and 18:00.The morning peak was larger than the evening peak.The mass percentages of BC in PM2.5 and PM10 were 7.1%and 4.8%,respectively.The absorption coefficient of BC was calculated to be 44.4 Mm-1,which accounted for 11.1%of the total aerosol extinction.BC was mainly emitted from local sources in southwestern Jiaxing where BC concentrations were generally greater than 11 μg/m3 during the measurement period.Correlation analysis indicated that the main sources of BC were motor vehicle exhaust,and domestic and industrial combustion. 相似文献
39.
40.
Mass concentration and isotopic values δ13C and 14C are presented for the water-insoluble refractory carbon(WIRC) component of total suspended particulates(TSP),collected weekly during 2003,as well as from October 2005 to May 2006 at the WMO-GAW Mt.Waliguan(WLG) site.The overall average WIRC mass concentration was(1183±120)ng/m3(n = 79),while seasonal averages were 2081 ±1707(spring),454±205(summer),650±411(autumn),and 1019±703(winter) ng/m3.Seasonal variations in WIRC mass concentrations were consistent with black carbon measurements from an aethalometer,although WIRC concentrations were typically higher,especially in winter and spring.The δ13C PDB value(-25.3 ± 0.8)%.determined for WIRC suggests that its sources are C3 biomass or fossil fuel combustion.No seasonal change in δ13C PDB was evident.The average percent Modern Carbon(pMC) for 14C in WIRC for winter and spring was(67.2 ± 7.7)%(n = 29).Lower pMC values were associated with air masses transported from the area east of WLG,while higher pMC values were associated with air masses from the Tibetan Plateau,southwest of WLG.Elevated pMC values with abnormally high mass concentrations of TSP and WIRC were measured during a dust storm event. 相似文献