首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   14942篇
  免费   2609篇
  国内免费   2521篇
化学   11799篇
晶体学   202篇
力学   702篇
综合类   256篇
数学   1575篇
物理学   5538篇
  2024年   45篇
  2023年   275篇
  2022年   478篇
  2021年   490篇
  2020年   603篇
  2019年   632篇
  2018年   529篇
  2017年   508篇
  2016年   792篇
  2015年   838篇
  2014年   892篇
  2013年   1181篇
  2012年   1312篇
  2011年   1386篇
  2010年   992篇
  2009年   1012篇
  2008年   1085篇
  2007年   953篇
  2006年   935篇
  2005年   840篇
  2004年   662篇
  2003年   585篇
  2002年   619篇
  2001年   456篇
  2000年   411篇
  1999年   314篇
  1998年   196篇
  1997年   179篇
  1996年   169篇
  1995年   135篇
  1994年   119篇
  1993年   99篇
  1992年   70篇
  1991年   51篇
  1990年   43篇
  1989年   36篇
  1988年   23篇
  1987年   26篇
  1986年   24篇
  1985年   19篇
  1984年   8篇
  1983年   9篇
  1982年   5篇
  1981年   6篇
  1980年   4篇
  1975年   3篇
  1974年   2篇
  1973年   4篇
  1957年   5篇
  1936年   3篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
The main mission the HL-2A tokamak is of the experiments on to explore the divertor physics and to investigate the plasma confinement, transport and instabilities with high power auxiliary heating and advanced fuelling, it is necessary to develop more new diagnostics and increase the spatial and temporal resolutions of the measurements for exist system. Up to now, about 30 diagnostic systems have been moved from HL-1M to HL-2A tokamak. Other 10 diagnostic systems are being designed and installed on the device. In developed in last 2 years, will be presented.  相似文献   
42.
As a computationally effective tool, the first-order term of the radiative perturbation theory has been computed successfully, and has been applied in a number of areas. In this article, we develop the computational expressions for the higher-order terms of the perturbation expansion in a plane parallel atmosphere. These expressions are then implemented, and numerical results for some typical cases are presented. These results indicate that the computation is successful and that the higher-order terms are essential in cases where the first-order term alone cannot predict the perturbation with sufficient accuracy.  相似文献   
43.
Coaxial cavities are used in high power gyrotrons as the beam-wave interaction structure. Much research has been devoted to their mode selective properties. A coaxial cavity lacks a sharp boundary at its open end, so it has some physical features that can only be observed using a spectral model, such as frequency-dependent field profiles and mode overlapping effects. These properties are important since cold tests are usually conducted in the frequency domain. This study applies the incident/reflected wave boundary condition to the wave equation of a weakly irregular coaxial waveguide. The resistivity of the wall is considered in the analysis. Calculations reveal that the fixed-position spectrum yields an uncertain resonant frequency and quality factor. Although the maximum-field spectrum can uniquely determine the properties of the coaxial cavity, the resonant frequency obtained using the maximum-field spectral model is inconsistent with that obtained using the temporal model. The field-energy spectrum explains the low Q nature of the coaxial cavity. Moreover, resonant frequencies evaluated using the field-energy spectrum agree precisely with those evaluated using the temporal model.  相似文献   
44.
N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine was synthesized from N‐(4‐nitrophenyl)‐diphenylamine by the Vilsmeier‐Haack reaction. Soluble aromatic poly(azomethine)s (PAMs) were prepared by the solution polycondensation of N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine and aromatic diamine in N‐methyl‐2‐pyrrolidone (NMP) at room temperature under reduced pressure. All the PAMs are highly soluble in various organic solvents, such as N,N‐dimethylacetamide (DMAc), chloroform (CHCl3), and tetrahydrofuran (THF). Differential scanning calorimetry (DSC) indicated that these PAMs had glass‐transition temperatures (Tgs) in the range of 170–230 °C, and a 10% weight‐loss temperatures in excess of 490 °C with char yield at 800 °C in nitrogen higher than 60%. These PAMs in NMP solution showed UV‐Vis charge‐transfer (CT) absorption at 405–421 nm and photoluminescence peaks around 462–466 nm with fluorescence quantum efficiency (ΦF) 0.10–0.99%. The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energy levels of these PAMs can be determined from cyclic voltammograms as 4.86–5.43 and 3.31–3.34 eV, respectively. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4921–4932, 2007  相似文献   
45.
A problem in extremal quasiconformal extensions   总被引:2,自引:0,他引:2  
A constantK 0 (m) (h) is introduced for every quasisymmetric mappingh of the unit circle and every integerm≥4 which contains the constantK 0(h) (indicated by the change in module of the quadrilaterals with vertices on the circle) as a special case. A necessary and sufficient condition is established forK 0 (m) (h) =K 1(h). It is shown that there are infinitely many quasisymmetric mappings of the unit circle having the property thatK 0 (m) (h)<K 1(h), wherek 1(h) is the maximal dilatation ofh.  相似文献   
46.
关于E-凸函数及E-凸规划几个错误结论的修正   总被引:2,自引:0,他引:2  
覃义  简金宝 《数学杂志》2006,26(2):177-180
本文研究Youness在1999年建立的有关E凸函数和E规划的结论.利用E凸函数和E凸规划的基本性质和优化分析技术,获得了有关E凸函数E凸规划的几个错误结论的修正..  相似文献   
47.
灰色模型的最优化及其参数的直接求法   总被引:2,自引:0,他引:2  
基于灰色模型的内涵表达式和白化方程响应式均为等比级数的观点,提出了一种不用求ago值、均值,不涉及灰色微分方程,白化微分方程概念,直接求灰色模型参数a,c的方法,通过此方法建立的新模型不仅从理论上可保证是在满足给定评价标准为模拟绝对误差平方和最小(或模拟相对误差平方和最小)、给定精度条件下的最优化模型,从而结束了灰色模型只有更优,没有最优的历史.并从理论上证明了新模型具有白化指数律重合性、白化系数律重合性,伸缩变换一致性.最后通过实例编程验证该方法具有可操作性,且预测精度高,效果好.  相似文献   
48.
49.
In this paper, using Fourier series, we study the problem of the existence of periodic solutions of a type of periodic neutral differential difference system. Some necessary and sufficient conditions for the existence of periodic solutions of a type of neutral functional equation system are obtained, and at the same time, we present a method with formula shows how to find the periodic solutions.  相似文献   
50.
In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号