Gemini表面活性剂烷烃尾链在吸附和聚集过程中的疏水协同效应(英文)

以表面张力法测定了系列Gemini表面活性剂m-6-m以及对应单体表面活性剂CmTABr的临界胶束浓度(cmc)和降低水表面张力20mN·m-1需要的浓度(pC20).比较这些参数表明m-6-m胶束化和在界面吸附的能力均强于CmTABr,这被归结为Gemini表面活性剂烷烃尾链间的疏水协同效应.与不对称Gemini表面活性剂12-6-m比较,对称的Gemini结构更有利于表面活性剂的聚集和吸附.     

不同产地珠子参中微量元素含量分析

分析不同产地珠子参中微量元素的含量变化情况。应用电感耦合等离子体-原子发射光谱法（ICP-AES）测定不同产地珠子参中Ca、Cr、Cu、Fe、Ga、Li、Mg、Mn、Ni、Sn、Sr、Ti、Tl、V、Zn、Pb 16种微量元素的含量。结果表明,不同产地珠子参中各微量元素含量有所差异,陕西宁强产珠子参中Ca、Mg、Mn、Zn、Cu等含量高于其他产地。珠子参中微量元素的含量与产地的土壤、水质等有关。     

近红外光谱法预测粗皮桉木材气干密度的影响因素分析

采用近红外光谱分析技术,对粗皮桉木材气干密度校正模型的影响因素进行比较研究.使用直接测量法测量了粗皮桉木材的气干密度,并用近红外光谱仪采集试样的近红外漫反射光谱,对不同切面、厚度、含水率和粗糙度的粗皮桉木材试样的原始光谱进行二阶导数预处理并选择一定光谱段建立回归模型.以50～140个试样作为校正集建立木材气干密度的偏最...     

考虑交通出行惯例的双向行人流模型研究

推广了Baek等人最近提出的一个双向行人流模型,提出了两种改进策略,并从行人平均速度-密度关系、行人空间分布密度和位置分布等方面进行了数值分析. 研究发现,引入的两个新策略不仅可以提高行人流的平均速度,而且可以提高道路系统(尤其是道路中央区域)利用率,减轻拥堵状况,有效避免严重堵塞的发生. 改进的策略对行人的心理特点和行为特性等方面考虑更加全面,而且可以较好地模拟高密度的双向行人流. 关键词： 元胞自动机模型 双向行人流 交通惯例     

Enantioselective Michael addition of anthrone to nitroalkenes catalyzed by bifunctional thiourea-tertiary amines

A highly bifunctional thiourea-tertiary amine-catalyzed enantioselective Michael addition reaction of anthrone to a wide variety of nitroalkenes has been developed, and the corresponding adducts were obtained smoothly in high yields (up to 97%) and good enantioselectivities (up to 94% ee).     

物理学类中文核心期刊的研究

文章详细介绍了综合测定中文物理学核心期刊的研究方法，并对所测定出的中文物理学核心期刊结论做了客观的评价，以及扼要阐述了它的对物理学科的作用．     

PW11Cu/TiO2膜光催化剂的制备及可见光催化性能

以PW₁₁Cu为可见光活性组分,TiO₂为载体结构组分,采用溶胶-凝胶法制备了PW₁₁Cu/TiO₂复合膜可见光催化剂,并用UV-Vis DRS、IR、Raman、XRD、SEM、TEM等手段对催化剂的光吸收性质、化学组成、晶相、表面结构和形貌进行了表征,同时,以模型污染物RhB的可见光降解为探针评估了它的光催化活性,考察了膜处理温度、PW₁₁Cu含量和溶液酸性对催化活性的影响,最后,通过催化剂循环降解RhB试验评估了PW₁₁Cu/TiO₂膜的稳定性。实验结果表明,PW₁₁Cu/TiO₂膜对可见光有明显吸收,低温(100℃)处理的膜为无定形态,高温(500℃)处理的膜为多晶态;低温处理的膜具有较高的可见光催化活性,用于RhB的可见光催化降解,在中性条件下反应80 min,RhB的降解率为100%,TOC去除达32%(4 h);提高溶液酸性有利于催化剂活性的提高,在pH=2.5的条件下,达到100%的RhB降解仅需30 min。在本实验条件下,PW₁₁Cu的最佳剂量是3.0 g。经过10次循环降解RhB,催化剂的光催化活性仍保留约90%。     

Disjoint hypercyclic powers of weighted translations on groups

Let G be a locally compact group and let 1 ≤ p < 1. Recently, Chen et al. characterized hypercyclic, supercyclic and chaotic weighted translations on locally compact groups and their homogeneous spaces. There has been an increasing interest in studying the disjoint hypercyclicity acting on various spaces of holomorphic functions. In this note, we will study disjoint hypercyclic and disjoint supercyclic powers of weighted translation operators on the Lebesgue space L ^p(G) in terms of the weights. Sufficient and necessary conditions for disjoint hypercyclic and disjoint supercyclic powers of weighted translations generated by aperiodic elements on groups will be given.     

A simple and eco-friendly method for the aminomethylation of 3-substituted oxindoles via three-component Mannich reaction in aqueous media

A simple and eco-friendly method for the aminomethylation of various 3-substituted oxindoles via three-component Mannich reaction in aqueous media has been established. A variety of oxindoles containing a quaternary carbon center, which comprises an aminomethyl group were obtained smoothly in good yields (up to 93%) with this method. Particularly valuable features, such as employing cheap and readily available formalin as a useful aminomethylation C1 unit and using water as a reaction medium, are embodied in this method.     

辛巴蓝F-3GA修饰的啤酒废酵母菌亲和吸附溶菌酶

利用j嗪染料辛巴蓝F-3GA修饰经戊二醛交联的啤酒废酵母菌,得到一种新型染料亲和吸附剂.辛巴蓝F-3GA的固载量为161.1 mg/g.以溶菌酶为研究对象,考察吸附时间、酶初始浓度、pH值、离子强度等因素对吸附率的影响.结果表明:当pH=7.0时,其对溶菌酶有较高的吸附量(229.1 mg/g),吸附性能明显优于未接枝...