全文获取类型
收费全文 | 782篇 |
免费 | 142篇 |
国内免费 | 106篇 |
专业分类
化学 | 568篇 |
晶体学 | 8篇 |
力学 | 53篇 |
综合类 | 2篇 |
数学 | 77篇 |
物理学 | 322篇 |
出版年
2023年 | 24篇 |
2022年 | 12篇 |
2021年 | 31篇 |
2020年 | 46篇 |
2019年 | 31篇 |
2018年 | 21篇 |
2017年 | 17篇 |
2016年 | 46篇 |
2015年 | 44篇 |
2014年 | 31篇 |
2013年 | 57篇 |
2012年 | 69篇 |
2011年 | 89篇 |
2010年 | 57篇 |
2009年 | 63篇 |
2008年 | 56篇 |
2007年 | 42篇 |
2006年 | 49篇 |
2005年 | 33篇 |
2004年 | 17篇 |
2003年 | 10篇 |
2002年 | 11篇 |
2001年 | 13篇 |
2000年 | 10篇 |
1999年 | 12篇 |
1998年 | 14篇 |
1997年 | 11篇 |
1996年 | 8篇 |
1995年 | 15篇 |
1994年 | 6篇 |
1993年 | 17篇 |
1992年 | 13篇 |
1991年 | 11篇 |
1990年 | 5篇 |
1989年 | 7篇 |
1988年 | 7篇 |
1987年 | 4篇 |
1986年 | 1篇 |
1985年 | 4篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1980年 | 4篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1968年 | 2篇 |
排序方式: 共有1030条查询结果,搜索用时 93 毫秒
141.
In this paper, we consider the quantile linear regression models with autoregressive errors. By incorporating the expectation–maximization algorithm into the considered model, the iterative weighted least square estimators for quantile regression parameters and autoregressive parameters are derived. Finally, the proposed procedure is illustrated by simulations and a real data example. 相似文献
142.
对液体冷媒融霜系统的回液时间进行实验研究。在保温体温度-15℃工况下分别对回液时间7s、27s、25s、30s、40s、50s进行实验,记录并分析被融霜蒸发器融霜前和回液时间内压缩机吸气口的温度和压力变化,相机拍摄制冷压缩机吸气口和机身的结霜状况。实验表明:回液时间7s时,压缩机吸气过潮,回液时间在27s左右可以避免压缩机吸气过潮,确保系统安全正常的运行,大于27s被融霜蒸发器恢复制冷时间过长将影响库房温度的稳定并降低制冷系统的效率。 相似文献
143.
研究了液体冷媒融霜系统应用于小型冷库制冷系统的性能;介绍了液体冷媒融霜原理和控制操作过程、液体冷媒融霜实验的装置和方法;对实验结果进行了分析;重点通过库温变化、蒸发器进出口温度压力变化、过冷度对系统的影响、系统COP几个方面,研究了液体冷媒融霜应用于小型冷库制冷系统的性能。 相似文献
144.
We investigate the Goos–Hänchen (GH) shifts of reflected light from Kerr-like slabs, whose permittivities are inhomogeneous in space as well as light intensity dependent. The GH shifts exhibit bistable, multivalued properties or a more complicated hysteretic response to the input light intensity, and the different spatial dependences of the permittivity have a great effect on the hysteretic response. The bistable or multivalued GH shifts can be modulated by various parameters, such as the angle of incidence and the thickness of slab. 相似文献
145.
Yan Jin Si Li Zhen Han Bing‐Jie Yan Hai‐Yang Li Xi‐Yan Dong Shuang‐Quan Zang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(35):12271-12276
Chiral assembly and asymmetric synthesis are critically important for the generation of chiral metal clusters with chiroptical activities. Here, a racemic mixture of [K(CH3OH)2(18‐crown‐6)]+[Cu5(StBu)6]? ( 1?CH3OH ) in the chiral space group was prepared, in which the chiral red‐emissive anionic [Cu5(StBu)6]? cluster was arranged along a twofold screw axis. Interestingly, the release of the coordinated CH3OH of the cationic units turned the chiral 1?CH3OH crystal into a mesomeric crystal [K(18‐crown‐6)]+[Cu5(StBu)6]? ( 1 ), which has a centrosymmetric space group, by adding symmetry elements of glide and mirror planes through both disordered [Cu5(StBu)6]? units. The switchable chiral/achiral rearrangement of [Cu5(StBu)6]? clusters along with the capture/release of CH3OH were concomitant with an intense increase/decrease in luminescence. We also used cationic chiral amino alcohols to induce the chiral assembly of a pair of enantiomers, [d /l ‐valinol(18‐crown‐6)]+[Cu5(StBu)6]? ( d /l ‐Cu5V ), which display impressive circularly polarized luminescence (CPL) in contrast to the CPL‐silent racemic mixture of 1?CH3OH and mesomeric 1 . 相似文献
146.
Li Ya-Hui Huang Ren-Wu Luo Peng Cao Man Xu Hong Zang Shuang-Quan Mak Thomas C. W. 《中国科学:化学(英文版)》2019,62(3):331-335
A new 1D silver cluster-assembled complex Ag_(10)bpy-CH_3CN exhibiting intense photoluminescence was reported. Upon the loss of coordinated acetonitrile, Ag_(10)bpy-CH_3CN form Ag_(10)bpy with Ag_(10)S_6 cores slightly distorted, being accompanied with photoluminescence quenching. Inverse process can be realized by treating Ag_(10)bpy with acetonitrile and shows a selectively erasable photoluminescent switch. 相似文献
147.
In this paper, we investigate the influences of 3-photon absorption on discrete X-waves in nonlinear normally dispersive waveguide arrays. It is found that 3-photon absorption can cause the decrease of the total power, which results in the appearances of the discrete diffraction for an intermediate input peak-power and the discrete X-wave for a higher input peak-power. Also, the interaction between pulses for different waveguide excitation are studied in detail. The results show that for the in-phase waveguide excitation of neighboring channels, the bound states can be formed by choosing properly the initial peak-power; for the in-phase waveguide excitation of distant channels, however, the bound states can not be formed. For the out-of-phase multiple waveguide excitation, due to interplay the repulsive force and nonlinearity, the interaction of two pulses can form the X-like wave or the double X-like wave as long as choosing the proper input peak-power. 相似文献
148.
We have presented a discussion on the guided waves in the indefinite-medium waveguides. The characteristic equations describing TE and TM guided waves have been derived. Aiming mainly at the TE guided waves, we have analyzed the existence conditions for the guided and surface modes for four distinct cases, respectively. A number of exotic properties have been revealed in such waveguides, such as the coexistence of forward and backward modes, the absence of fundamental modes, the existence of surface modes and the relaxed requirements for waveguide core constitutive parameters. Numerical results have confirmed our analyses. 相似文献
149.
ZnO films doped with different contents of indium were prepared by radio frequency sputtering technique. The structural, optical and emission properties of the films were characterized at room temperature using XRD, XPS, UV-vis-NIR and PL techniques. Results showed that the indium was successfully incorporated into the c-axis preferred orientated ZnO films, and the In-doped ZnO films are of over 80% optical transparency in the visible range. Furthermore, a double peak of blue-violet emission with a constant energy interval (∼0.17 eV) was observed in the PL spectra of the samples with area ratio of indium chips to the Zn target larger than 2.0%. The blue peak comes from the electron transition from the Zni level to the top of the valence band and the violet peak from the InZn donor level to the VZn level, respectively. 相似文献
150.