木质素催化转化制备异丙苯

Cumene is an important intermediate and chemical in chemical industry.In this work,directional preparation of cumene using lignin was achieved by a three-step cascade process.The mixture aromatics were first produced by the catalytic pyrolysis of lignin at 450℃ over 1% Zn/HZSM-5 catalyst,monocyclic aromatics with the selectivity of 85.7 wt% were obtained.Then,the catalytic dealkylation of heavier aromatics resulted in benzene-rich aromatics with 93.6 wt% benzene at 600℃ over Hβ catalyst.Finally,the cumene synthesis was performed by the aromatic alkylation,giving cumene selectivity of 91.6 C-mol% using the[bmim]Cl-2AlCl₁₃ ionic liquid at room temperature for 15 min.Besides,adding a small amount of methanol to the feed can efficiently suppress the coke yield and enhance the aromatics yield.The proposed transformation potentially provides a useful route for production of cumene using renewable lignin.     

利用金属筛网拓展光栅衍射实验

为拓展大学物理实验中光栅衍射实验的内容,使其更贴近生活,实验现象形式多样,利用生产生活中常用的金属筛网作为二维光栅设计实验内容。通过筛网的衍射,可直观地观察到二维光栅的衍射现象,并分析了不同衍射图像产生的原因。通过两种不同的方案测量衍射角,从而计算出筛网的关键参数-网孔尺寸。     

增益饱和在整形放大啁啾脉冲中的作用

根据线性啁啾脉冲的特点，利用增益介质的受激发射谱特性，及脉冲在饱和放大时的放大特点，从理论上提出一种获得强度分布前后沿对称放大啁啾脉冲输出的方法，并利用数值模拟对该方法的可行性进行了研究，具体给出了在利用该种方法产生强度前后沿对称的放大啁啾脉冲输出时，应该遵循的部分规律。     

Elastic analysis of a mode II crack in a decagonal quasi—crystal

The elastic analysis of a mode II Griffith crack penetrating through a decagonal quasi-crystal along the periodic axis is made within the context of the continuum theory. By using a general solution obtained previously, the problem in the case of uniform shear stress at infinity is solved, and the analytical expressions for the entire stress field disturbed by an internal crack are derived in an explicit form. The asymptotic fields of the displacement and stress around a crack tip in both phonon and phason fields indicate that the stresses near a crack tip exhibit the square-root singularity. The formula for evaluating the energy release rate is also given. If imposing that the phason field is absent, the well-known results of a mode II crack in a conventional material are recovered from the present results.     

The Effective Degree of Freedom of Low Energy QCD

The adiabatic effective baryon-baryou interactions and dibaryon candidates are studied systematically with three constituent quark models based on different effective degrees of freedom:Glozman-Riska-Brown Goldstone boson exchange model based on constituent quark and Goldstone boson coupling;Fujiwara model based on constituent quark gluon coupling and Nijmegen one-boson exchange;QDCSM based on constituent quark and gluon coupling with quark delocalization and color screening.We find that the three models predicted the similar effective baryon-baryon interactions for roughly two thirds among the 64 states consisted of octet and decuplet baryons.The differences among three models and their separate characteristics are also studied.     

连续时间稳定线性系统的混沌反控制研究

从混沌反控制定义的本质出发,利用传统的控制方法,研究了连续时间稳定线性系统的混沌反控制问题.通过巧妙地引入跟踪控制,成功地实现了连续时间稳定线性系统的混沌化.该方法无需计算系统的Lyapunov指数,大大降低了混沌反控制的计算量,从而在实际中也更易于应用 关键词： 线性系统 混沌 反控制     

应用高温计测量氩等离子体温度

应用多通道辐射高温计测量了冲击产生的氩等离子体的温度,并与理论计算结果进行了比较.测量结果与Saha方程加Debye-Huckel修正模型的计算结果符合较好.     

多孔球层内核态沸腾过程特性的实验观察

本文以水为实验工质,对从底部加热多孔球层内核态沸腾过程进行可视化观察。通过高速图像采集系统;拍摄和观察了孔隙内汽泡的成长过程,在实验观察的基础上,对多孔球层内核态沸腾过程的一些基本特性进行了分析和讨论。     

15.14MeV/u 136Xe离子引起的单粒子效应

研究了15.14MeV/u ¹³⁶Xe离子在不同批次的32k×8bits静态存储器中所引起的单粒子效应.获得了单粒子翻转和单粒子闭锁截面与入射角度的依赖关系.将单粒子效应截面与灵敏区中沉积的能量相联系,而不是线性能量转移(LET)值.估计了灵敏体积的深度和死层的厚度.     

考虑流体湿润性影响的核沸腾RohsenoW修正模型

添加界面活性剂的核沸腾在改变蒸气泡生长特性的同时，主要是强化了对流换热．本文考虑流体湿润性影响，对核沸腾换热沿用最广的对流类比模型－Ｒｏｈｓｅｎｏｗ模型进行了修正．通过对实验数据的检验，表明修正后的模型预示值与实测结果吻合很好．