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191.
A Kinetic Evidence for the Nitroxyl Radicals Recycling Mechanism in the Photostabilizing Process of HALS 总被引:1,自引:0,他引:1
XiaoXuanLIU XingHongZHANG GuangGuoWU JianWenYANG ZhaoHuaZENG YongLieCHEN 《中国化学快报》2003,14(10):1085-1088
The photoinduced bulk polymerization of a reactive-hindered amine fight stabilizers(r-HALS), 4-acryloyl-2, 2, 6, 6-tetramethylpiperidinyl (ATMP), was performed at 80℃ by using a DPC technique. An unique periodic exponential attenuation-type oscillating curve was found when the polymerization was carried out in air, but this phenomenon was not found in nitrogen.It is supposed that this unique kinetic performance may be attributed to nitroxyl radicals that are produced in situ from the oxidation of ATMP. ATMP polymer with narrow polydispersity (d =1.03) can be obtained by photoinduced solution polymerization of ATMP. The signal detected in ESR may be assigned to the nitroxyl radicals in the matrix of ATMP polymer. Since this kind of recycling of nitroxyl radicals is well documented for the photostabilizing mechanism of HALS, the present results may serve as a kinetic evidence for this mechanism. 相似文献
192.
Two new compounds from Zingiber officinale 总被引:1,自引:0,他引:1
Yu Zhao Qiao Feng Tao Rong Ping Zhang Chang Xin Zhou Hui Dou Shu Yun Shi Ye Cheng Xiao Lian Li Sun Su Zeng Ke Xin Huang Xiao Dong Zhang Xiao Kun Li 《中国化学快报》2007,18(10):1247-1249
A new cyclic diarylheptanoid,1,5-epoxy-3-hydroxy-1-(3-methoxy-4,5-dihydroxyphenyl)-7-(4-hydroxyphenyl)-heptane (1),as well as a new monoterpene,10-O-β-D-glucopyranosyl-hydroxy cineole (2) were isolated from the rhizomes of Zingiber officinale. The structures of compounds 1 and 2 were established based on their spectral data.In addition,the antioxidant activities of these compounds were also measured. 相似文献
193.
利用场诱导光电压谱(简称FISPS)和瞬态光伏(简称TPV)技术研究了TiO2的光生电荷的产生和传输机制.发现光生电荷在体块TiO2上的迁移机制不同于在纳米TiO2上的迁移机制,也不同于在结界面空间电荷区的迁移机制. 400 ℃处理的TiO2颗粒表面具有大量的表面态,光生电荷被表面态捕获-释放机制控制着光伏行为的过程是慢过程. 800 ℃处理的TiO2已经形成了完整的能带结构,光伏响应除了表现带-带跃迁外,还有一个在带边的自由激子带,光生电荷被表面自建场驱动进行传递的过程是快过程. 600 ℃处理的TiO2混晶由锐钛矿型和金红石型两种构型组成,在两相之间存在着较低势垒的结界面.它的光伏响应受控于两种机制 :光生电荷在两相间结界面空间电荷区的传输和在表面自建场驱动下的传输.当激发光强较小时,界面空间电荷区的光生电子由于积累的浓度较小而不能隧穿过结界面,这种场助隧穿只有在外场作用下才能发生. 相似文献
194.
Determination of cadmium in water samples by graphite furnace atomic absorption spectrometry after cloud point extraction 总被引:3,自引:0,他引:3
The formation of a complex with 2-(5-brom-2-pyridylazo)-5-(diethylamino)-phenol (5-Br-PADAP) and cloud point extraction have
been applied to the preconcentration of cadmium followed by its determination by graphite furnace atomic absorption spectrometry
(GFAAS) using octylphenoxypolyethoxyethanol (TritonX-114) as surfactant. The chemical variables affecting the separation were
optimized. At pH 7.0, preconcentration of only 10 mL of sample in the presence of 0.05% TritonX-114 and 2.5 × 10−6 M 5-Br-PADAP enabled the detection of 0.04 μg/L cadmium. The enrichment factor was 21 for cadmium. The regression equation
was A = 0.0439C(μg/L) + 7.2 × 10−3. The correlation coefficient was 0.9995. The precision for 10 replicate determinations at 10 μg/L Cd was 2.7% relative standard
deviation (RSD). The proposed method has been applied to the determination of cadmium in water samples.
The text was submitted by the authors in English. 相似文献
195.
Bi HC Zhong GP Zhou S Chen X Huang M 《Rapid communications in mass spectrometry : RCM》2005,19(20):2911-2917
A liquid chromatography/tandem mass spectrometry (LC/MS/MS) method was developed and validated to determine the concentrations of adefovir [9-(2-phosphonylmethoxyethyl)adenine, PMEA] in human plasma. After one-step protein precipitation of plasma samples by methanol, adefovir was analyzed by LC/MS/MS using positive electrospray ionization. Chromatography was performed on a C18 column. The extraction recoveries of adefovir were found to be 85.1-89.3%. Adefovir was stable under routine laboratory conditions. A minimal matrix effect resulting in a slight ionization enhancement of adefovir (<10.9%) was observed, which did not markedly affect the behavior of the calibrations curves and accuracy and precision data. The method had a chromatographic run time of 7.8 min and a linear calibration curve over the concentration range 1.5-90 ng/mL for adefovir. The lower limit of quantification of the method was 1.5 ng/mL. The intra- and inter-day precision was less than 8.4%. These results indicated that this LC/MS/MS method has high selectivity and efficiency, and acceptable accuracy, precision and sensitivity. The validated LC/MS/MS method has been successfully used in a pharmacokinetic study in healthy volunteers treated with oral adefovir dipivoxil at 10 and 20 mg. 相似文献
196.
Tong X Benz L Kemper P Metiu H Bowers MT Buratto SK 《Journal of the American Chemical Society》2005,127(39):13516-13518
Experiments in which mass-selected gold clusters were deposited on a surface have found that the catalytic properties depend strongly on cluster size. However, these experiments have not established definitively that the clusters maintain their size after deposition. We report here work in which we deposit low kinetic energy, mass-selected Aun+ (n = 1-8) clusters on a rutile TiO2(1 x 1) surface and use ultrahigh vacuum scanning tunneling microscopy (UHV-STM) to determine their size and shape. 相似文献
197.
合成了新型手性Salen配体(H3L)及新型手性Salen双核锌配合物(主体).通过研究主体对咪唑类客体及氨基酸酯类客体的分子识别行为,测定了这些配位反应的缔合常数.主体对咪唑类客体分子识别的缔合常数顺序为:K(Im) >K(2-MeIm) >K(2-Et-4-MeIm).主体对氨基酸酯类客体分子识别的缔合常数顺序为:K(LeuOCH3) >K(ValOCH3) >K(AlaOCH3) >K(SerOCH3),配位数均为2.主体与D、 L型氨基酸酯分子识别反应在不同温度下的缔合常数结果表明,随着温度的升高,对映选择性下降.实验发现反应体系中存在焓熵补偿关系. CD光谱的研究结果也反映了主体对不同客体识别能力的差异. 相似文献
198.
Dong L Liu YC Tong YH Xiao ZY Zhang JY Lu YM Shen DZ Fan XW 《Journal of colloid and interface science》2005,283(2):380-384
Colloidal ZnO particles with narrow size distribution were prepared via a sol-gel process by base-catalyzed hydrolysis of zinc acetate. The morphology of ordered arrays of the particles was recorded by SEM. SEM also reveals that these uniform particles were composed of tiny ZnO subunits (singlets) sized of several nanometers. The size of the singlets, which is confirmed by X-ray diffraction and UV-vis absorption spectra, increases as the aging time is prolonged. The size-selective formation of colloids by aggregation of nanosized subunits is proposed to consist of two-stage growth by nucleation of nanosized crystalline primary particles and their subsequent aggregation into polycrystalline secondary colloids. The aggregates are all spherical because the internal rearrangement processes are fast enough. The ZnO colloids, i.e., the aggregates, tend to self-assemble into well-ordered hexagonal close-packed structures. Room-temperature photoluminescence was characterized for green and aged ZnO. 相似文献
199.
Recycling Chiral Organocatalyst (4S)-Phenoxy-(S)-proline for Direct Asymmetric Aldol Reaction in Ionic Liquid (bmim)PF6 总被引:1,自引:0,他引:1
Room temperature ionic liquid (bmim)PF6 was evaluated for recycling an organocatalyst (4S)-phenoxy-(S)-proline for direct asymmetric aldol reactions. The desired aldol products were obtained with good yields up to 93.2% and enantioselectivities up to 88.5%, and isolation of the products by simple extraction allowed recycling the ionic liquid containing the immobilized catalyst in subsequent reactions without significant decrease of yields and enantioselectivities. 相似文献
200.
Regioselectively produced 2- and 3-acetyl-1-(phenylsulfonyl)pyrroles can be reduced to the corresponding alcohols and subsequently dehydrated to afford N-protected vinylpyrroles. These remarkably stable vinylpyrroles can then serve as heterodienes in [4 + 2] cycloaddition reactions with electron deficient dienophiles to afford tetrahydroindole derivatives. 相似文献