全文获取类型
收费全文 | 58910篇 |
免费 | 9708篇 |
国内免费 | 7326篇 |
专业分类
化学 | 41887篇 |
晶体学 | 751篇 |
力学 | 3683篇 |
综合类 | 543篇 |
数学 | 6950篇 |
物理学 | 22130篇 |
出版年
2024年 | 210篇 |
2023年 | 1165篇 |
2022年 | 2020篇 |
2021年 | 2077篇 |
2020年 | 2380篇 |
2019年 | 2347篇 |
2018年 | 2001篇 |
2017年 | 1836篇 |
2016年 | 2810篇 |
2015年 | 2797篇 |
2014年 | 3346篇 |
2013年 | 4190篇 |
2012年 | 5065篇 |
2011年 | 5201篇 |
2010年 | 3618篇 |
2009年 | 3517篇 |
2008年 | 3895篇 |
2007年 | 3441篇 |
2006年 | 3162篇 |
2005年 | 2598篇 |
2004年 | 2102篇 |
2003年 | 1875篇 |
2002年 | 1904篇 |
2001年 | 1615篇 |
2000年 | 1376篇 |
1999年 | 1276篇 |
1998年 | 1042篇 |
1997年 | 954篇 |
1996年 | 944篇 |
1995年 | 859篇 |
1994年 | 717篇 |
1993年 | 578篇 |
1992年 | 576篇 |
1991年 | 474篇 |
1990年 | 423篇 |
1989年 | 315篇 |
1988年 | 263篇 |
1987年 | 219篇 |
1986年 | 190篇 |
1985年 | 194篇 |
1984年 | 130篇 |
1983年 | 86篇 |
1982年 | 65篇 |
1981年 | 43篇 |
1980年 | 18篇 |
1979年 | 12篇 |
1977年 | 2篇 |
1959年 | 3篇 |
1957年 | 6篇 |
1936年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
51.
52.
53.
For approximate wave functions, we prove the theorem that there is a one‐to‐one correspondence between the constraints of normalization and of the Fermi–Coulomb and Coulomb hole charge sum rules at each electron position. This correspondence is surprising in light of the fact that normalization depends on the probability of finding an electron at some position. In contrast, the Fermi–Coulomb hole sum rule depends on the probability of two electrons staying apart because of correlations due to the Pauli exclusion principle and Coulomb repulsion, while the Coulomb hole sum rule depends on Coulomb repulsion. We demonstrate the theorem for the ground state of the He atom by the use of two different approximate wave functions that are functionals rather than functions. The first of these wave function functionals is constructed to satisfy the constraint of normalization, and the second that of the Coulomb hole sum rule for each electron position. Each is then shown to satisfy the other corresponding sum rule. The significance of the theorem for the construction of approximate “exchange‐correlation” and “correlation” energy functionals of density functional theory is also discussed. © 2006 Wiley Periodicals, Inc. Int J Quantum Chem, 2007 相似文献
54.
Longlan Cui Hong Xu Ping He Keiko Sumitomo Yoshinori Yamaguchi Hongchen Gu 《Journal of polymer science. Part A, Polymer chemistry》2007,45(22):5285-5295
A hybrid emulsion polymerization was formulated for synthesizing Fe3O4/polystyrene composite latex. This system, containing binary droplets that are magnetic (Mag)‐droplets with a diameter of 100–200 nm and styrene (St)‐droplets with a diameter of 3–4 μm, was obtained by mixing Mag‐miniemulsion and St‐macroemulsion. With extremely low surfactants concentration (?critical micelle concentration, CMC), the nucleated loci are selectively controlled in the Mag‐droplets, as the result of smaller droplet size and larger surface ratio. Both water‐soluble potassium persulfate (KPS) and oil‐soluble 2,2′‐azobis(2‐isobutyronitrile) was adopted to initiate the polymerization. In the presence of KPS, magnetic polystyrene latices with particles size of 60–200 nm, narrow size distribution, and high magnetite content (86 wt % measured by TGA) were attained successfully. The synthesized magnetic Fe3O4/polystyrene latices assembled into well‐ordered hexagonal structure in the surface of a carbon supported copper grid. The influence of various parameters on various aspects of the as‐synthesized Fe3O4/polystyrene was investigated in detail: type of initiator on composite morphology, feed ratio of Mag‐miniemulsion and St‐macroemulsion on magnetite content, and hydrophobic agent or amount of surfactant on size and size distribution. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5285–5295, 2007 相似文献
55.
本文对近20年来多复变函数的一个发展迅速的数学热门分支-逆紧映照作了一个回顾和整理。这是作者继续从事此方向研究的先声,也希望本文能为有志于此的研究者提供一些便利。本文从经典的结果开始,通过对逆紧映照在边界上的开拓及分支点的分布的讨论,详细地阐述了这些年来关于逆紧映照何时成为双全纯映照的若干结果。最后,对近年来关于逆紧映照另外的一些工作进行了简单的介绍。 相似文献
56.
应用七级目测法对浙江中部地区27个夏熟作物田样点的杂草进行了优势等级调查,将所得数据转换成重要值,以杂草在27个样点中的重要值为运算指标,应用主成分分析法和图论聚类中的最小生成树法,对24种杂草的生态学相似性进行了比较,指出了长期使用单一的除草剂导致农田杂草种群迅速更迭的原因:杂草对除草剂的敏感性差异及不同杂草间的生态学特性的差异。 相似文献
57.
文章详细描述了航空兵机场塔台辅助指挥系统之通信分系统设计的特点与功能、硬件结构、软件设计原则以及接口通信协议等问题。该分系统设计已在航空兵塔台辅助指挥系统研究中得到应用 ,并达到了良好的控制效果。 相似文献
58.
M. Gutowski I. Dabkowska J. Rak S. Xu J.M. Nilles D. Radisic K.H. Bowen Jr 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,20(3):431-439
The photoelectron spectra (PES) of anions of uracil-glycine and uracil-phenylalanine complexes reveal broad features with
maxima at 1.8 and 2.0 eV. The results of ab initio density functional B3LYP and second order M?ller-Plesset theory calculations indicate that the excess electron occupies a
π* orbital localized on uracil. The excess electron attachment to the complex can induce a barrier-free proton transfer (BFPT)
from the carboxylic group of glycine to the O8 atom of uracil. As a result, the four most stable structures of the anion of
uracil-glycine complex can be characterized as the neutral radical of hydrogenated uracil solvated by the anion of deprotonated
glycine. The similarity between the PES spectra for the uracil complexes with glycine and phenylalanine suggests that the
BFPT is also operative in the case of the latter anionic species. The BFPT to the O8 atom of uracil may be related to the
damage of nucleic acid bases by low energy electrons because the O8 atom is involved in a hydrogen bond with adenine in the
standard Watson-Crick pairing scheme.
Received 6 April 2002 Published online 13 September 2002 相似文献
59.
Fengfu Fu Liangjun Xu Wei Ye Yiquan Chen Mingyu Jiang Xueqin Xu 《中国颗粒学报》2006,4(6):323-326
Different-sized aerosols were collected by an Andersen air sampler to observe the detailed morphology of the black carbon (BC) aerosols which were separated chemically from the other accompanying aerosols, using a Scanning Electron Microscope equipped with an Energy Dispersive X-ray Spectrometer (SEM-EDX). The results indicate that most BC aerosols are spherical particles of about 50 nm in diameter and with a homogeneous surface. Results also show that these particles aggregate with other aerosols or with themselves to form larger agglomerates in the micrometer range. The shape of these 50-nm BC spherical particles was found to be very similar to that of BC particles released from petroleum-powered vehicular internal combustion engines. These spherical BC particles were shown to be different from the previously reported fullerenes found using Matrix-Assisted Laser Desorption/Ionization Time-Of-Flight Mass Spectrometry (MALDI-TOF-MS). 相似文献
60.
Z.G. Xiao R.J. HuH.Y. Wu G.M. JinZ.Y. Li L.M. DuanH.W. Wang B.G. ZhangS.F. Wang Z.Y. WeiH.S. Xu Y.T. ZhuS.L. Li F. FuX.H. Yuan Z.Q. Feng 《Physics letters. [Part B]》2006
The inclusive reduced velocity correlation functions of the intermediate mass fragments were measured in the reactions of 36Ar + 112,124Sn at 35 MeV/u. The anti-correlation is observed to be stronger in 36Ar + 124Sn system than that in 36Ar + 112Sn. The difference of the correlation functions between the two reactions is mainly contributed by the particle pairs with high momenta. A three body Coulomb repulsive trajectory model is employed to calculate the emission time scale of the IMFs for the two systems. The time scale is 150 fm/c in 36Ar + 112Sn and 120 fm/c in the 36Ar + 124Sn, respectively. 相似文献