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41.
Zhitian Liu Lei Wang Junwu Chen Feng Wang Xiaoying Ouyang Yong Cao 《Journal of polymer science. Part A, Polymer chemistry》2007,45(5):756-767
2,5‐Bis(2‐bromofluorene‐7‐yl)silole was prepared by a modified one‐pot synthesis with a reverse addition procedure, from which novel silole‐containing polyfluorenes with binary random and alternating structures (silole contents between 4.5 and 25% and high Mw up to 509 kDa were successfully synthesized. The well‐defined repeating unit of the alternating copolymer comprises a terfluorene and a silole ring. Optoelectronic properties including UV absorption, electrochemistry, photoluminescence (PL), and electroluminescence (EL) of the copolymers were examined. The different excitation energy transfers from fluorene to silole of the copolymers in solution and in the solid state were compared. The films of the copolymers showed silole‐dominant green emissions with high absolute PL quantum yields up to 83%. EL devices of the copolymers with a configuration of ITO/PEDOT/copolymer/Ba/Al displayed exclusive silole emissions peaked at around 543 nm and the highest EL efficiency was achieved with the alternating copolymer. Using the alternating copolymer and poly(9,9‐dioctylfluorene) as the blend‐type emissive layer, a maximum external quantum efficiency of 1.99% (four times to that of the neat film) was realized, which was a high efficiency so far reported for silole‐containing polymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 756–767, 2007 相似文献
42.
The method of demodulation with two parallel matched fiber Bragg gratings( FBGs)system is introduced to enlarge the range of strain that can be detected by the FBG sensor system. 相似文献
43.
Xiao‐Hui Liu Yan‐Guo Li Ying Lin Yue‐Sheng Li 《Journal of polymer science. Part A, Polymer chemistry》2007,45(7):1272-1281
The reversible addition–fragmentation chain transfer (RAFT) polymerization of acrylonitrile (AN) mediated by 2‐cyanoprop‐2‐yl dithiobenzoate was first applied to synthesize polyacrylonitrile (PAN) with a high molecular weight up to 32,800 and a polydispersity index as low as 1.29. The key to success was ascribed to the optimization of the experimental conditions to increase the fragmentation reaction efficiency of the intermediate radical. In accordance with the atom transfer radical polymerization of AN, ethylene carbonate was also a better solvent candidate for providing higher controlled/living RAFT polymerization behaviors than dimethylformamide and dimethyl sulfoxide. The various experimental parameters, including the temperature, the molar ratio of dithiobenzoate to the initiator, the molar ratio of the monomer to dithiobenzoate, the monomer concentration, and the addition of the comonomer, were varied to improve the control of the molecular weight and polydispersity index. The molecular weights of PANs were validated by gel permeation chromatography along with a universal calibration procedure and intrinsic viscosity measurements. 1H NMR analysis confirmed the high chain‐end functionality of the resultant polymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1272–1281, 2007 相似文献
44.
The compound binomial risk model with time-correlated claims 总被引:1,自引:0,他引:1
Yuntao Xiao 《Insurance: Mathematics and Economics》2007,41(1):124-133
In this paper, we consider the compound binomial risk model with the time-correlated claims. It is assumed that every main claim will produce a by-claim but the occurrence of the by-claim may be delayed. We obtain the recursive formula of the joint distribution of the surplus immediately prior to ruin and deficit at ruin. Furthermore, the ruin probability is given by means of ruin probability and the deficit at ruin of the classical compound binomial risk model. Finally, we derive an upper bound for the ruin probability. 相似文献
45.
提出了一种基于模型驱动的元数据管理方案.方案采用了基于模型的形式化描述方法,统一了专业网管子系统间的元数据模式;通过引入模型驱动技术,从元模型的抽象层次消除了不同专业网管子系统之间存在的“信息孤岛”;方案还对综合网管环境下的元数据理论和交换机制进行了研究,并给出了元数据的管理框架以及元数据交换的Java接口映射. 相似文献
46.
Nanocrystalline FeS2 cathode material of lithium cell was synthesized from cheap materials of FeSO4, Na2S2O3, and sulfur by a hydrothermal process. The scanning electron microscopy analysis showed the obtained material was nano-sized,
about 500 nm. The X-ray powder diffraction analysis showed that the synthetic FeS2 material had two phases of the crystalline structure, pyrite and marcasite. The phase of marcasite seems to have no negative
effect on the electrochemical performance of the material. The synthetic FeS2 showed a significant improvement of electrochemical performance for Li/FeS2 cells. 相似文献
47.
Fuzzy random vector is a measurable map from a probability space to a collection of fuzzy vectors. Our aim in this paper is
to discuss the measurability criteria for fuzzy random vectors, and show that under mild assumption, the measurability criteria
for upper semicontinuous fuzzy random vectors can be expressed in several different but equivalent formulations. Finally,
applying the obtained results, we resolve an open problem about the relationship between fuzzy random vectors and fuzzy random
variables. 相似文献
48.
49.
900 MHz 1H NMR (nuclear magnetic resonance) spectroscopy was used to analyze metabolites in allantoic fluid of the chicken embryo in
the 9th incubation day without any chemical or physical sample separation. The result showed that superhigh spectral dispersion
and sensitivity at 900 MHz are useful in directly analyzing a complex mixture, particularly in resolving the overlapped NMR
resonances. In this study, we had assigned 61 metabolites and 26 chemical fragments in the allantoic fluid. The relative concentrations
of the major metabolites were also measured. Among the assigned metabolites, some were detected by NMR in chicken embryo allantoic
fluids for the first time. The biological functions of these compounds were briefly discussed.
Authors' address: Maili Liu, State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute
of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071, People's Republic of China 相似文献
50.
Hong Ming ZHANG Xian Hong WANG Xiao Jiang ZHAO Ji LI Fo Song WANG 《中国化学快报》2006,17(4):437-440
A novel method for the preparation of oligothiophene molecular wires is described via a bi-directional solid-phase synthesis. Using an alternating sequence of bromination and Stille coupling reactions, oligomers were obtained up to the heptamer in excellent yield and purity. 相似文献