首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   68454篇
  免费   15024篇
  国内免费   5711篇
化学   63849篇
晶体学   726篇
力学   2643篇
综合类   445篇
数学   6017篇
物理学   15509篇
  2024年   74篇
  2023年   771篇
  2022年   998篇
  2021年   1326篇
  2020年   2639篇
  2019年   3787篇
  2018年   2127篇
  2017年   1728篇
  2016年   4847篇
  2015年   4903篇
  2014年   5131篇
  2013年   6266篇
  2012年   5887篇
  2011年   5121篇
  2010年   4877篇
  2009年   4726篇
  2008年   4471篇
  2007年   3712篇
  2006年   3250篇
  2005年   3130篇
  2004年   2672篇
  2003年   2478篇
  2002年   3244篇
  2001年   2497篇
  2000年   2150篇
  1999年   1281篇
  1998年   708篇
  1997年   618篇
  1996年   574篇
  1995年   514篇
  1994年   437篇
  1993年   398篇
  1992年   350篇
  1991年   315篇
  1990年   306篇
  1989年   201篇
  1988年   147篇
  1987年   106篇
  1986年   124篇
  1985年   89篇
  1984年   57篇
  1983年   51篇
  1982年   40篇
  1981年   24篇
  1980年   13篇
  1979年   8篇
  1976年   2篇
  1968年   2篇
  1957年   4篇
  1936年   3篇
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
1.
2.
Zhu  Jie-Xiang 《Potential Analysis》2021,55(1):167-188
Potential Analysis - We establish some exact asymptotic results for a matching problem with respect to a family of beta distributions. Let X1,…,Xn be independent random variables with common...  相似文献   
3.
Journal of Optimization Theory and Applications - We consider a distributionally robust formulation of stochastic optimization problems arising in statistical learning, where robustness is with...  相似文献   
4.
Hua  Saixiang  Zhu  Huichao  Wang  Xiao  Wu  Mingyuan  Wu  Qingyun  Liu  Jiuyi  Yang  Jianjun  Zhang  Jianan 《Cellulose (London, England)》2022,29(13):7465-7475
Cellulose - Ultraviolet (UV) protective cotton fabric is a convenient and reliable way to protect human body from sunlight. Herein, a polymerizable UV-absorber,...  相似文献   
5.
Li  Mingjun  Zhu  Li 《应用数学和力学(英文版)》2021,42(8):1171-1182
This study is to numerically test the interfacial instability of ferrofluid flow under the presence of a vacuum magnetic field. The ferrofluid parabolized stability equations(PSEs) are derived from the ferrofluid stability equations and the Rosensweig equations, and the characteristic values of the ferrofluid PSEs are given to describe the ellipticity of ferrofluid flow. Three numerical models representing specific cases considering with/without a vacuum magnetic field or viscosity are created to mathematically examine the interfacial instability by the computation of characteristic values. Numerical investigation shows strong dependence of the basic characteristic of ferrofluid Rayleigh-Taylor instability(RTI) on viscosity of ferrofluid and independence of the vacuum magnetic field.For the shock wave striking helium bubble, the magnetic field is not able to trigger the symmetry breaking of bubble but change the speed of the bubble movement. In the process of droplet formation from a submerged orifice, the collision between the droplet and the liquid surface causes symmetry breaking. Both the viscosity and the magnetic field exacerbate symmetry breaking. The computational results agree with the published experimental results.  相似文献   
6.
Photoelectrochemical (PEC) cytosensors, a combination of the PEC process and the living-cell assay, have emerged as a powerful tool in the analytical and biological science. This mini review provides a brief introduction of this arena and summaries the key steps about the development of PEC cytosensors with representative examples, followed by future prospects based on our own opinions.  相似文献   
7.
Incorporating nanoscale Si into a carbon matrix with high dispersity is desirable for the preparation of lithium-ion batteries (LIBs) but remains challenging. A space-confined catalytic strategy is proposed for direct superassembly of Si nanodots within a carbon (Si NDs⊂C) framework by copyrolysis of triphenyltin hydride (TPT) and diphenylsilane (DPS), where Sn atomic clusters created from TPT pyrolysis serve as the catalyst for DPS pyrolysis and Si catalytic growth. The use of Sn atomic cluster catalysts alters the reaction pathway to avoid SiC generation and enable formation of Si NDs with reduced dimensions. A typical Si NDs⊂C framework demonstrates a remarkable comprehensive performance comparable to other Si-based high-performance half LIBs, and higher energy densities compared to commercial full LIBs, as a consequence of the high dispersity of Si NDs with low lithiation stress. Supported by mechanic simulations, this study paves the way for construction of Si/C composites suitable for applications in future energy technologies.  相似文献   
8.
A ruthenium-catalyzed formal anti-Markovnikov hydroamination of allylic alcohols for the synthesis of chiral γ-amino alcohols is presented. Proceeding via an asymmetric hydrogen-borrowing process, the catalysis allows racemic secondary allylic alcohols to react with various amines, affording enantiomerically enriched chiral γ-amino alcohols with broad substrate scope and excellent enantioselectivities (68 examples, up to >99 % ee).  相似文献   
9.
10.
The development of high‐surface‐area carbon electrodes with a defined pore size distribution and the incorporation of pseudo‐active materials to optimize the overall capacitance and conductivity without destroying the stability are at present important research areas. Composite electrodes of carbon nano‐onions (CNOs) and polypyrrole (Ppy) were fabricated to improve the specific capacitance of a supercapacitor. The carbon nanostructures were uniformly coated with Ppy by chemical polymerization or by electrochemical potentiostatic deposition to form homogenous composites or bilayers. The materials were characterized by transmission‐ and scanning electron microscopy, differential thermogravimetric analyses, FTIR spectroscopy, piezoelectric microgravimetry, and cyclic voltammetry. The composites show higher mechanical and electrochemical stabilities, with high specific capacitances of up to about 800 F g?1 for the CNOs/SDS/Ppy composites (chemical synthesis) and about 1300 F g?1 for the CNOs/Ppy bilayer (electrochemical deposition).  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号