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971.
series of chitosan samlpes with 91% deacetylation but different molecular weight were obtained by varying the time of chitosan solution in acetic acid aqueous solution at 70℃.The viscosities and flow behavior of the concentrated solutions of chitosan were investigated in 10% (vol%) formic acid aqueous solution after the solutions were prepared for two days by using RPX-705 Rheopexy Analyzer.For each chitosan sample,at the concentration of 3.5 g/100ml,the log (ηr/η0)versus lgγη0,M curves superimpose each other within the same rheogramme. Then the relationship between log nr and lgM was studied under different shear rates.For the highest M sample, the experimental data deviate from the straight lines greatly. This was because the chitosan chain degradated in acid solution during dissolving. The molecular weights were measured in acid solution after two days of dissolving, they were right on their own straight lines. However,no obvious degradation was observed after two days in the same solution for the other lower M chitosan sam-ples. In addition, the plot of nr against M was not a straight line,probaly due to particular interaction of chitosan. 相似文献
972.
Using renewable green hydrogen and carbon dioxide (CO2) to produce methanol is one of the fundamental ways to reduce CO2 emissions in the future, and research and development related to catalysts for efficient and stable methanol synthesis is one of the key factors in determining the entire synthesis process. Metal nanoparticles stabilized on a support are frequently employed to catalyze the methanol synthesis reaction. Metal-support interactions (MSIs) in these supported catalysts can play a significant role in catalysis. Tuning the MSI is an effective strategy to modulate the activity, selectivity, and stability of heterogeneous catalysts. Numerous studies have been conducted on this topic; however, a systematic understanding of the role of various strengths of MSI is lacking. Herein, three Cu/ZnO-SiO2 catalysts with different strengths of MSI, namely, normal precipitation Cu/ZnO-SiO2 (Nor-CZS), co-precipitation Cu/ZnO-SiO2 (Co-CZS), and reverse precipitation Cu/ZnO-SiO2 (Re-CZS), were successfully prepared to determine the role of such interactions in the hydrogenation of CO2 to methanol. The results of temperature-programmed reduction (H2-TPR) and X-ray photoelectron spectroscopy (XPS) characterization illustrated that the MSI of the catalysts was considerably affected by the precipitation sequence. Fourier transform infrared reflection spectroscopy (FT-IR) results indicated that the Cu species existed as CuO in all cases and that copper phyllosilicate was absent (except for strong Cu-SiO2 interaction). Transmission electron microscopy (TEM), X-ray diffraction (XRD), and N2O chemical titration results revealed that strong interactions between the Cu and Zn species would promote the dispersion of Cu species, thereby leading to a higher CO2 conversion rate and improved catalytic stability. As expected, the Re-CZS catalyst exhibited the highest activity with 12.4% CO2 conversion, followed by the Co-CZS catalyst (12.1%), and the Nor-CZS catalyst (9.8%). After the same reaction time, the normalized CO2 conversion of the three catalysts decreased in the following order: Re-CZS (75%) > Co-CZS (70%) > Nor-CZS (65%). Notably, the methanol selectivity of the Re-CZS catalyst was found to level off after a prolonged period, in contrast to that of Co-CZS and Nor-CZS. Investigation of the structural evolution of the catalyst with time on stream revealed that the high methanol selectivity of the catalyst was caused by the reconstruction of the catalyst, which was induced by the strong MSI between the Cu and Zn species, and the migration of ZnO onto Cu species, which caused an enlargement of the Cu/ZnO interface. This work offers an alternative strategy for the rational and optimized design of efficient catalysts. 相似文献
973.
Electron impact mass spectra of eight of the title compounds are reported. Abundant fragment ions were produced under electron impact (EI) conditions and, with one exception, the ($?hbox?ArC??equiv$ O) ions were the base peaks. The EI fragmentation mechanisms of two representative compounds were studied with the aid of high-resolution and mass-analyzed ion kinetic energy spectrometry (MIKES) data. The M(+) ions fragment to give both an odd-electron ion and an even-electron fragment ion. Two H-atom rearrangements proceeding via four-membered ring intermediates and three losses of CO through i- and alpha-fragmentations were observed under EI. On comparing fragmentations under EI conditions with those under FAB conditions for two of the compounds, the fragmentation mechanisms were reasonably similar, with additional fragmentations rationalized in terms of the ionization proton being located on the oxygen atom of the beta-ethoxy group. 相似文献
974.
A highly sensitive and selective catalytic adsorptive cathodic striping procedure for the determination of trace germanium is presented. The method is based on adsorptive accumulation of the Ge(IV)‐gallic acid (GA) complex onto a hanging mercury drop electrode, followed by reduction of the adsorbed species. The reduction current is enhanced catalytically by addition of vanadium(IV)‐EDTA. The optimal experimental conditions include the use of 0.03 mol/L HClO4 (pH1.6), 6.0×10?3 mol/L GA, 3.0×10?3 mol/L V(IV), 4.0×10?3 mol/L EDTA, an accumulation potential of ?0.10 V(vs. Ag/AgCl), an accumulation time of 120 s and a differential pulse potential scan mode. The peak current is proportional to the concentration of Ge(IV) over the range of 3.0×10?11 to 1.0×10?8 mol/L and the detection limit is 2×10?11 mol/L for a 120 s adsorption time. The relative standard deviation at 5.0×10?10 mol/L level is 3.1%. No serious interferences were found. The method was applied to the determination of germanium in ore, mineral water and vegetable samples with satisfactory results. 相似文献
975.
Dr. Dingfeng Yang Junzhu Yang Xuejun Quan Bin Zhang Guoyu Wang Xu Lu Xiaoyuan Zhou 《Chemphyschem》2021,22(24):2579-2584
Understanding the correlation between crystal structure and thermal conductivity in semiconductors is very important for designing heat-transport-related devices, such as high-performance thermoelectric materials and heat dissipation in micro-nano-scale devices. In this work, the lattice thermal conductivity ( ) of the cage-like compounds Cu3VSe4 and Cu3NbSe4 was investigated by experimental measurements and first-principles calculations. The experimental of Cu3NbSe4 is approximately 25 % lower than that of Cu3VSe4 at 300 K. The relevant important physical parameters, including the sound velocity, heat capacity, weighted phonon phase space (W), and third-order force constants along with atomic mass were theoretically analyzed. It is found that W is the dominant parameter in determining the , and the other factors only play a minor role. The physical origin is the relatively “soft” lattice of Cu3NbSe4 with heavier atomic mass. This research provides deep insight into the correlation between the thermal conductivity and crystal structure and paves the way for discovering high-performance thermal management device and thermoelectric materials with intrinsically low . 相似文献
976.
A simple approach for deriving expressions for the limiting steady-state response of the open tubular electrode, under conditions of intermediate electrolytic yields, is described. This approach couples the principles of laminar fluid dynamics with the theory of the porous electrode reactor. The dependence of the limiting current, I1, on flow rate, Vf, has the form of I1 α Vmf , with m ? , depending upon the electrolytic yield. The effects of electroactive species depletion upon the detector response are discussed. Experimental results are incorporated to support the theoretical conclusions. For a tubular electrode (4-cm long) the degree of conversion decreases from 0.21 to 0.03 and m decreases from 0.42 to 0.32 as the flow rate increases from 0.15 to 3.5 ml min-1. 相似文献
977.
F W Wang 《Macromolecules》1976,9(1):97-101
An equation for the translational diffusion coefficient of block copolymers in dilute solution has been obtained by modifying Zimm's equation for homopolymers to take into account the existence of dissimilar segments in block copolymers. Illustrative calculations for homopolymers and block copolymers have been made and the results for homopolymers have been compared with experiments and with the calculations of Yamakawa and Fujii. A procedure has been proposed to determine the molecular weight of a block copolymer from measurements of its limiting viscosity number and its sedimentation coefficient or translational diffusion coefficient. 相似文献
978.
According to the new method of preparing core-shell nanospheres developed by our group, by using two monomers, 2-hydroxypropyl
methacrylate(HPMA) and vinyl acetate(VAc), two kinds of core-shell nanospheres with poly(ɛ-caprolactone) (PCL) as the core
and crosslinked poly(2-hydroxypropyl methacrylate) (PHPMA) or poly(vinyl acetate) (PVAc) as the shell were successfully prepared
under similar conditions. After degrading the PCL cores of the two kinds of nanospheres by lipase, the corresponding crosslinked
poly(methyl acrylic acid) hollow spheres and crosslinked poly(vinyl alcohol) hollow spheres were obtained. Results indicate
that the new method we proposed for preparing core-shell polymeric nanospheres via in-situ polymerization can be generalized to a certain extent, and it is suitable for many systems provided the monomer used is soluble
in water, while its corresponding polymer is insoluble in water.
Translated from Chemical Journal of Chinese University, 2006, 27(9): 1762–1766 [译自: 高等学校化学学报] 相似文献
979.
William R. Dolbier Jr. Jian-Xin Duan Xiao X. Rong 《Journal of fluorine chemistry》2007,128(10):1091-1093
Selective, high yield partial fluorination of p-bis-(trichloromethyl)benzene to p-bis-(chlorodifluoromethyl)benzene has been accomplished by warming a slurry of the p-bis-(trichloromethyl)benzene in anhydrous HF which also contains a small quantity of inert solvent, such as 1,2-dichloroethane. 相似文献
980.
Xianmei Xie Xiurong Ren Jinping Li Xiaojun Hu Zhizhong Wang 《天然气化学杂志》2006,15(2):100-104
Ultrasonic technology has been intensively studied recently due to its special features. In this paper, an ultrasonic crystallization method was introduced for the preparation of ZnAl-Hydrotalcite-Like compounds (ZnAl-HTLcs). Samples with high crystallinity, small particle size and narrow particle size distribution were obtained and fully characterized using conventional techniques of XRD, FT-IR and TGDTA. The results prove that both ultrasonic frequency and ultrasonic power have effects on the sizes of the product particles. By varying the ultrasonic power from 250 W to 88 W, with the ultrasonic frequency fixed at 59 kHz, the median particle size of the samples increased from 0.37 μm to 0.82 μm. By altering the hydrothermal treatment time from 1 h to 5 h at 110℃, the median particle size of ZnAl-HTLcs synthesized via ultrasonic crystallization increased from 0.88 μm to 1.11 μm. 相似文献