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841.
为了克服传统层去反求测量中图像衬比度较低的缺陷,提出一种新的基于棱镜反射原理的层去反求图像摄取方法。该方法利用棱镜的全发射和折射作用提高图像衬比度,根据物体反射率的高低可分别采用垂直照明和倾斜照明,分别可获得高衬比度的亮目标暗背景和暗目标亮背景图像,为了校正由于折反射引入的几何变形,推出了相应的数学变换模型。该研究已成功投入实际产品校正的应用中,研究表明这种新的层去法比起传统的层去法不仅在于图像衬比度高,而且物体截面图像的轮廓更清晰可靠、无需填充反差材料,有望在零件及模型的反求测量中发挥较大的作用。 相似文献
842.
Bing‐Xin Liu Duan‐Jun Xu 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(2):m39-m41
The title compound, [Cd(C4H4O4)(C7H6N2)2(H2O)]n, is a three‐dimensional polymeric complex. The CdII atom is located on an inversion centre and assumes an elongated octahedral coordination geometry, with a long Cd—O distance of 2.5381 (5) Å to the coordinated bridging water molecule. The succinate dianion, located on another inversion centre, bridges adjacent Cd atoms to form succinate‐bridged polymeric chains. The coordinated water molecule is located on a twofold axis and links adjacent succinate‐bridged chains to form a water‐bridged polymeric chain. 相似文献
843.
844.
845.
Lijun Duan Sunny N. Wallace Abigail Engelberth Justin K. Lovelady Edgar C. Clausen Jerry W. King Danielle Julie Carrier 《Applied biochemistry and biotechnology》2009,158(2):362-373
In an effort to increase revenues from a given feedstock, valuable co-products could be extracted prior to biochemical or
thermochemical conversion with subcritical water. Although subcritical water shows significant promise in replacing organic
solvents as an extraction solvent, compound degradation has been observed at elevated extraction temperatures. First order
thermal degradation kinetics from a model system, silymarin extracted from Silybum marianum, in water at pH 5.1 and 100, 120, 140, and 160 °C were investigated. Water pressure was maintained slightly above its vapor
pressure. Silymarin is a mixture of taxifolin, silichristin, silidianin, silibinin, and isosilibinin. The degradation rate
constants ranged from 0.0104 min−1 at 100 °C for silichristin to a maximum of 0.0840 min−1 at 160 °C for silybin B. Half-lives, calculated from the rate constants, ranged from a low of 6.2 min at 160 °C to a high
of 58.3 min at 100 °C, both for silichristin. The respective activation energies for the compounds ranged from 37.2 kJ/gmole
for silidianin to 45.2 kJ/gmole for silichristin. In extracting the silymarin with pure ethanol at 140 °C, no degradation
was observed. However, when extracting with ethanol/water mixtures at and 140 °C, degradation increased exponentially as the
concentration of water increased.
An erratum to this article can be found at 相似文献
846.
The properties of groups on TiO2 surface were evaluated by infrared (IR) spectra and thermal analysis. It could be found that water and ethanol are removed mainly between 343 and 363 K and the process is accompanied by an endothermic change. The results also show that ethanol could be removed completely below 673 K and the physically bonded or hydrogen‐bonded water could be removed almost completely above 873 K. The exothermic peaks ranging from 573 to 773 K are caused by the changes that chemisorbed water (Ti‐O‐H) on the surface condenses and evolves into water. There appears broad and unstable endothermic process in all temperature ranges due to the adhesions or transformations among the crystal particles. Thermogravimetry (TG) results show that with heat treatment at increasing temperatures, the groups on TiO2 surface decreases gradually. The half peak breadth of X‐ray diffractometer (XRD) results suggest that TiO2 crystallize better with higher temperature calcination. The photo‐catalytic efficiency was evaluated by UV‐Vis spectrophotometer. TiO2 with heat treatment at higher temperature shows more effective photo‐catalytic property. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
847.
In this Letter, a pair of novel naphthalimide derivatives with long-wavelength emission (>600 nm) and larger Stokes shift (>140 nm) have been developed through the photochemical cycloaromatization, in which intramolecular radical-induced 1,3-aromatic hydrogen transfer might be occurred. Cell uptake experiments showed that dye 2 could be used as a potential NIR fluorescence imaging agent. 相似文献
848.
Two new triterpenes,2α,3β-dihydroxyurs-12-en-18,19-epoxy-28-oic acid(1)and 18,19-seco,2α,3α-dihydroxyl-19-oxo-urs-11, 13(18)-dien-28-oic acid(2)were isolated from the herbaceous part of Duchesnea indica.Their structures were elucidated by spectroscopic analysis,including 2D NMR technique.The isolated compounds exhibited moderate cytotoxic activities against HeLa and L929 cell lines. 相似文献
849.
Li J Li WZ Huang W Cheung AW Bi CW Duan R Guo AJ Dong TT Tsim KW 《Journal of chromatography. A》2009,1216(11):2071-2078
A high-performance liquid chromatography coupled with diode array detector and mass spectrometry (HPLC-DAD-MS) method was developed to evaluate the quality of Rhizoma Belamcandae (Belamcanda chinensis (L.) DC.) through establishing chromatographic fingerprint and simultaneous determination of seven phenolic compounds. The analysis was achieved on an Alltima C(18) analytical column (250 mm x 4.6 mm i.d. 5 microm) using linear gradient elution of acetonitrile-0.1% trifluoroacetic acid. The correlation coefficients of similarity were determined from the HPLC fingerprints, and they shared a close similarity. By using an online APCI-MS/MS, twenty phenols were identified. In addition, seven of these phenols including mangiferin, 7-O-methylmangiferin, tectoridin, resveratrol, tectorigenin, irigenin and irisflorentin were quantified by the validated HPLC-DAD method. These phenols are considered to be major constituents in Rhizoma Belamcandae, and are generally regarded as the index for quality assessment of this herb. This developed method by having a combination of chromatographic fingerprint and quantification analysis could be applied to the quality control of Rhizoma Belamcandae. 相似文献
850.
Jiankun Duan 《Talanta》2009,79(3):734-738
A flow injection online speciation procedure by using micro-column packed with Cu(II) loaded nanometer-sized Al2O3 coupled to inductively coupled plasma mass spectrometry (ICP-MS) for the separation and determination of selenomethionine (SeMet) and selenocystine (SeCys2) has been developed. The main factors affecting the separation and preconcentration of SeMet and SeCys2 including pH value, sample flow rate, eluent concentration, eluent volume and flow rate, and interfering ions have been investigated. It was found that SeCys2 could be selectively retained by micro-column packed with Cu(II) loaded nanometer-sized Al2O3 at pH 4.0, and the retained SeCys2 could be eluted by 1.0 mol L−1 HNO3, while SeMet was not retained and passed through the micro-column directly at this pH. Both SeMet and SeCys2 could be quantitatively adsorbed by the micro-column at pH 9.0, and the retained SeMet and SeCys2 could be easily eluted with 1.0 mol L−1 HNO3. The content of SeMet was obtained by subtracting the SeCys2 from the total content of seleno amino acids. With the enrichment factor of 7.8 and 7.7, the limits of detection (LODs) for SeMet and SeCys2 were found to be 24 pg Se mL−1 and 21 pg Se mL−1, respectively. The relative standard deviations (RSDs) for SeCys2 and SeMet with seven replicate determinations of 1.0 ng mL−1 SeMet and SeCys2, were 2.1% and 1.6%, respectively, the sampling frequency of 8 h−1 was obtained. The proposed method was applied to the speciation of SeMet and SeCys2 in selenized yeast, human urine and serum with satisfactory results. 相似文献