Parametric normalization for full-energy peak count rates obtained at different geometries

The Effective Interaction Depth (EID) law has been systematically studied and applied to parametric normalization for peak count rates obtained at different source-detector distances (S-D). The errors caused by EID normalization are less than 4% over the full range of S-D (from to several mm) for true coincidence-free -rays. Parametric corrections for the true coincidence (summing) effect are also established, based on simplified decay schemes and P/T ratio determinations. The total response of Ge detector for single-energy -rays (T) is clearly defined with scattering contributions from surroundings included. Errors from summing effect corrections are also less than 4%. The combined EID normalization and summing effect corrections give an error no greater than 5.7% for the worst situations (several mm S-D and cascade-crossover decay scheme), acceptable for most practical K₀ NAA.     

Conformational statistics of polymer chain terminally attached to wall (Ⅲ)——NRW model loop chain

When the two end groups of a linear polymer chain are absorbed on a solid surface,the polymer chain forms the "loop" conformation.Investigation has been made on the conformational statistics of a model loop chain by the normal landom walk (NRW) on a lattice confined in the half-infinite space.Based on the conformational distribution function of the NRW model tail chain,it is easy to deduce an analytical formula expressing the conforma-tional number of the model loop chain.It was found that the ratio of the conformational number of the model loop chain to that of the free chain varies with the power function N-2/3 when the chain length N→∞ The same result was obtained by means of the recursion equation.The ratio of the mean square end-to-end distance h2 for the model loop chain to its mean square bond length I2 is 2N/3 Compared with the free chain with the same length N,the mean square end-to-end distance of the model loop chain contracts to a certain extent.The basic relationships deduced were support     

N-(6-甲基-2-亚甲基吡啶)-( )-樟脑亚胺体系的不对称烷基化反应

目前,不对称合成光学活性化合物取得了较大进展,不对称合成α-氨基酸、β-氨基醇、α-取代苄胺的报道很多。但是,不对称合成生物碱类物质——α-取代氨甲基吡啶类化合物还未见文献报道,而此类化合物有潜在的应用前景。为此,我们以( )-樟脑为手性试剂     

Sol-gel derived carbon ceramic electrode containing methylene blue-intercalated α-zirconium phosphate micro particles

Methylene blue-intercalated alpha-zirconium phosphate (MBZrP) micro particles in deionized water were deposited onto the surface of graphite powder to prepare graphite powder-supported MBZrP, which was subsequently dispersed into methyltrimethoxysilane-derived gels to yield a conductive composite. The composite was used as electrode material to fabricate a surface-renewable, rigid, leak-free carbon ceramic composite electrode, bulk-modified with methylene blue (MB). In the configuration, alpha-zirconium phosphate was employed as a solid host for MB, which acted as a catalyst. Graphite powder ensured conductivity by percolation, the silicate provided a rigid porous backbone and the methyl groups endowed hydrophobicity and thus limited the wetting section of the modified electrode. Peak currents of the MBZrP-modified electrode were surface-confined at low scan rates but diffusion-controlled at high scan rates. Square-wave voltammetric study revealed that MBZrP immobilized in carbon ceramic matrix presented a two-electron, three-proton redox process in acidic aqueous solution with pH ranged from 0.44 to 2.94. In addition, the chemically modified electrode showed an electrocatalytic activity toward nitrite reduction at +0.15 V ( vs. Ag/AgCl) in acidic aqueous solution (pH=0.44). The linear range and detection limit are 1x10(-6)-4x10(-3) mol x L(-1) and 1.5x10(-7) mol x L(-1), respectively.     

La2/3Ca1/3MnO3中的输运机制与CMR效应

研究了超大磁阻材料La2/3Ca1/3MnO3的磁电特性，发现由电阻测量得到的绝缘体．金属相变与由磁化曲线得到的顺磁-铁磁相变温区完全一致，均随磁场的增强推向高温区。结果证明样品输运行为的变化起因于磁结构的变化，在Tc附近产生超大巨磁电阻效应。     

纳米级NiTiO3粉体的合成

以Ｈ２ＴｉＯ３，Ｈ２Ｏ２及ＮｉＣｌ２为主要原料，用化学共沉淀法制备了纳米级ＮｉＴｉＯ３。确定了反应物Ｈ２ＴｉＯ３，Ｈ２Ｏ２，ＮＨ３的最佳摩尔比为１：８：２，用不同的退火温度和退火时间对样品处理得到相应粒径的纳米级粉体。