用于像素探测器的高事例率高精度TDC ASIC原型电路的设计与仿真

像素探测器因其优异的位置分辨能力在高能粒子物理实验的内径探测器中有着广泛应用,随着应用场景的发展,许多物理实验要求探测器及其读出电子学也具备高精度时间测量的能力。针对像素探测器时间测量的需求,设计完成了一款具备高事例率处理能力、高精度特点的TDC(Time-to-Digital Conversion)ASIC(Application Specific Integrated Circuit)原型电路,将来可以作为核心组成部分集成到像素探测器前端读出ASIC中。采用粗细结合的方案完成TDC的设计,其中粗时间测量基于计数器实现,细时间测量采用TAC(Time-to-Amplitude Converter)结合ADC(Time-to-Amplitude Converter)的结构实现,基于130 nm工艺完成了原型电路的设计。对TDC进行仿真,仿真结果表明,该电路可以最多处理连续11个事例,相邻事例的最短时间间隔为500 ps,bin size达到了2 ps,DNL(Differential Non-Linearity)小于2.8 ps,时间测量精度好于5 ps RMS。     

基于立方烷结构的分子催化剂在光催化水氧化中的研究进展

随着化石燃料大量使用带来的气候变化和环境污染问题日趋严重,寻找清洁高效的可再生能源用做传统化石燃料的替代品,已经成为当前的研究热点。光驱动的水分解反应被认为是太阳能制氢的可行途径。水的全分解包括两个半反应-水的氧化和质子还原。其中水的氧化反应是一个涉及四个电子和四个质子转移的复杂过程,需要很高的活化能,被认为是全分解水反应的瓶颈步骤。因此,开发高效、稳定、廉价丰产的水氧化催化剂是人工光合作用突破的关键因素。立方烷具有类似自然界光合作用酶光系统II(PSII)活性中心Mn_4CaO_5簇的结构,世界各国的科学家受自然界光合作用的启发,开发出了许多基于过渡金属的立方烷结构的催化剂,常见的有锰、钴和铜等立方烷催化剂。本文简要地综述了近年来立方烷分子催化剂在光催化水氧化中的研究进展。首先介绍了立方烷基光催化水氧化反应历程,继而详细介绍了基于有机配体的立方烷配合物和全无机的多金属氧酸盐立方烷水氧化催化剂,其次是半导体(BiVO4或聚合的氮化碳(PCN))为捕光材料复合立方烷分子催化剂的水氧化体系最新研究进展。最后总结并展望了该领域所面临的挑战及其前景。     

An electrochemical and structural investigation of porous composite anode materials for LIB

A porous composite anode for lithium ion battery (LIB) was investigated. The composite anode was prepared by electrodepositing Sn?CSb alloy on a template-like electrode and then annealing it in the atmosphere of N₂, whereas the porous template-like electrode was obtained by forming a sponge-like porous membrane on a copper foil via a mixed phase inversion process, followed by pre-plating Cu through membrane pores in it. SEM and XRD results showed that composite structure of the anode consisted of electrodeposited Sn?CSb alloy dispersed in a PAN-pyrolyzed conjugated conducting polymer gridding, which was tightly connected with the Cu foil through transition alloy layer formed by heat treatment. Due to its relatively reasonable microcosmic structure, the composite anode presented better cycling performance and specific capacity retention during charging and discharging at diverse rates. When cycled between 0 and 2.0?V (vs Li/Li⁺) at 0.5?C rate, the reversible charge/discharge capacity of the composite material remained 415 and 414.8?mAh?g^?1, respectively, after 30 cycles, corresponding to 82.9% of the capacity retention. When charging and discharging at 2?C rate, the composite material electrode showed 71.7% capacity retention at the 30th cycle.     

One-pot dichlorinative deamidation of primary β-ketoamides

An approach to the dichlorinative deamidation of primary β-ketoamides through ketonic cleavage is described, and a series of α,α-dichloroketones were furnished mostly in the presence of TEMPO. Based on control experiments, a mechanism involving tandem dichlorination and deamidation is proposed to interpret the observed reactivity.     

Fejèr-Korovkin算子及一种内插线性算子的渐近展开

设f(x)∈C_(2π)。本文讨论两种线性算子对f(x)的逼近,全文分两个部分。 在第一部分中,我们考虑在正卷积型三角多项式线性算子中占重要地位的Fejr-Korovkin算子K_n(f,x)=1/π integral from -x to π (f(x+t)k_n(t)dt),其中k_n(t)≡1/2+sum from k=1 to n (ρ_k~((n)) cos kt)=1/2+sum from k=1 to n (F_n(k/n+2)coskt),F_n(x)=(1-x)cosπX+1/n+2 cot π/n+2·sinπx.由于它满足Korovkin条件:所以有下述结果:设f(x)∈C_(2π),f″(x)∈C_(2π)。那么,当n→∞时,成立着     

位相型全息记录介质折射率调制幅度及浮雕幅度的自动测量

提出一种自动测量位相型记录介质折射率调制幅度和浮雕深度的方法，它将刀口解调技术与计算机自动采集，处理数据的特点结合在一起，可实现快速自动测量，并具有较高的测量精度。     

环镜对激光束变换的理论分析与实验

介绍一种新型的光学元件，它可把一束激光变换成一个两维的激光平面。本文用多光束干涉的原理解释了光平面形成的原理，同时对应用前景及实用情况也作了一些估计     

Urea-assisted solvothermal synthesis of monodisperse multiporous hierarchical micro/nanostructured ZnCo<Subscript>2</Subscript>O<Subscript>4</Subscript> microspheres and their lithium storage properties

High-quality monodisperse multiporous hierarchical micro/nanostructured ZnCo₂O₄ microspheres have been fabricated by calcinating the Zn_1/3Co_2/3CO₃ precursor prepared by urea-assisted solvothermal method. The as-prepared products are characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), high-resolution transmission electron microscopy (HRTEM), and Brunauer-Emmett-Teller (BET) measurement to study the crystal phase and morphology. When tested as anode material for lithium ion batteries, the multiporous ZnCo₂O₄ microspheres exhibit an initial discharge capacity of 1,369 mAh g^?1 (3,244.5 F cm^?3) and retain stable capacity of 800 mAh g^?1 (1,896 F cm^?3) after 30 cycles. It should be noted that the good electrochemical performances can be attributed to the porous structure composed of interconnected nanoscale particles, which can promote electrolyte diffusion and reduce volume change during discharge/charge processes. More importantly, this ZnCo₂O₄ 3D hierarchical structures provide a large number of active surface position for Li⁺ diffusion, which may contribute to the improved electrochemical performance towards lithium storage.     

Electrochemical activities of yttrium doped spinel LiMn2O4

It was found for the first time that the catalysis of yttrium doping of spinel LiMn₂O₄ can enhance the electrochemical activities of manganese, leading to both improvement of electrochemical capacity and reactivity with the electrolyte of manganese. A proper amount of doping was 0.5%, and such yttrium-doped sample, Li(Y_0.005Mn_0.995)₂O₄, had an initial capacity of 130 mAh g⁻¹ over that of the undoped one with the capacity retention to reach 92.3% exceeding that of the undoped one at 100th cycle.