基于机械振动理论的垂直侵彻弹靶作用模型

为了给侵彻引信抗高过载优化设计提供准确的力学输入,将机械振动理论引入侵彻过程建模领域,提出了一种侵彻战斗部刚体运动与一阶轴向振动相结合的垂直侵彻弹靶作用模型。在垂直侵彻过程受力分析的基础上,基于牛顿第二定律建立了战斗部刚体运动模型,基于单自由度弹簧-质量-阻尼系统建立了战斗部一阶轴向振动模型,并采用数值积分的方法获得了垂直侵彻过程中各物理量的变化规律。和火炮试验实测加速度信号的对比分析结果表明:考虑战斗部一阶轴向振动后的垂直侵彻弹靶作用模型能更准确地描述侵彻过程,能更有效地指导侵彻引信的抗高过载优化设计。     

高光谱图像中纯光谱提取方法

利用线性解混合方法处理高光谱图像数据,需要获取存在于光谱图像中的纯光谱.目前的纯光谱提取方法都需要复杂的运算,并且都没有被证明具有普遍适用的特点,在特征空间对光谱图像中信息存在形式进行有效分析的基础上,提出基于特征空间分析和光谱相关制图法相结合的纯光谱提取方法(FSASCM),具有复杂度低、对大多数高光谱图像数据普遍适用的特点,     

用中子活化分析法研究25种元素在人体肝脏亚细胞组分中的分布

采用差速离心分离技术与中子活化分析法（ＮＡＡ）相结合的方法分析了人肝２５５中元素,并用标准参考物保证结果的准确性。分析结果表明,大多数元素在各亚细胞组分中并非均匀分布。Ａｓ、Ａｕ、Ｃｏ、Ｉ、Ｍｇ、Ｓｂ、Ｓｅ在细胞核和线粒体浓度最高。Ａｌ、Ｓｓ、Ａｕ、Ｂａ、Ｆｅ、Ｉ、Ｍｇ、Ｍｏ、Ｓｂ、Ｓｃ在细胞核和线粒体浓度最高。Ａｌ、Ａｓ、Ａｕ、Ｂａ、Ｆｅ、Ｉ、Ｌａ、Ｍｇ、Ｍｎ、Ｓｂ、Ｓｅ在胞液中深度最低,生物体     

大孔径静态干涉成象光谱仪中横向剪切干涉仪的空间光线分析

介绍基于横向剪切干涉仪的大孔径静态干涉成象光谱仪的原理,用坐标变换和矢量分析的方法计算空闪光线的光程差,通过计算机仿真归纳出横向剪切干涉仪空间光线光程差的一般表达式。     

Aqueous-phase synthesis of upconversion metal-organic frameworks for ATP-responsive in situ imaging and targeted combinational cancer therapy

Herein, the nanoscaled ATP-responsive upconversion metal-organic frameworks（UCMOFs） are aqueousphase synthesized for co-delivery of therapeutic protein cytochrome c（Cyt c） and chemodrugs doxorubicin（DOX）, achieving targeted combinational therapy of human cervical cancer. The UCMOFs are rationally fabricated by growing ZIF-90 on mesoporous silica-coated upconversion nanoparticles（UCNPs）,in which the ZIF-90 layer attenuates the upconversion luminescence（UCL） and the rigid frameworks increase the s...     

转镜式光谱仪端反射镜误差容限分析

系统分析了当转镜式干涉光谱仪端反射镜发生倾斜,致使反射光束偏转时对干涉图的影响.发现光束偏转带来的误差分为三部分：1）光束偏转导致整体增加的恒定光程差;2）垂直光轴方向因不同光线而引入的偏移光程差;3）光束中心相对于光轴的偏移量.干涉强度中的有效信号减小,同时直流分量不变,因此信噪比降低.最后从调制度和相位误差角度给出了端反射镜倾斜误差容限并讨论了减小干涉图受光束偏转影响的方法.     

Formal Aza‐Wacker Cyclization by Tandem Electrochemical Oxidation and Copper Catalysis

In oxidative electrochemical organic synthesis, radical intermediates are often oxidized to cations on the way to final product formation. Herein, we describe an approach to transform electrochemically generated organic radical intermediates into neutral products by reaction with a metal catalyst. This approach combines electrochemical oxidation with Cu catalysis to effect formal aza‐Wacker cyclization of internal alkenes. The Cu catalyst is essential for transforming secondary and primary alkyl radical intermediates into alkenes. A wide range of 5‐membered N‐heterocycles including oxazolidinone, imidazolidinone, thiazolidinone, pyrrolidinone, and isoindolinone can be prepared under mild conditions.     

Room temperature ionic liquid-mediated molecularly imprinted polymer monolith for the selective recognition of quinolones in pork samples

A novel molecularly imprinted polymer monolith was prepared by the room temperature ionic liquid-mediated in situ molecular imprinting technique, using norfloxacin (NOR) as the template, methacrylic acid as the functional monomer, ethylene glycol dimethacrylate as the cross-linker. The optimal synthesis conditions and recognition properties of NOR-imprinted monolithic column were investigated. The results indicated that the imprinted monoliths exhibited good ability of selective recognition against the template and its structural analog. Using the fabricated material as solid-phase extraction sorbent, a sample pre-treatment procedure of molecularly imprinted solid-phase extraction coupling with HPLC was developed for determination of trace quinolone residues in animal tissues samples. The recoveries ranging from 78.16 to 93.50% for eight quinolones antibiotics such as marbofloxacin, NOR, ciprofloxacin, danofloxacin, difloxacin, oxolinic acid, flumequine and enrofloxacin were obtained.     

Effect of Potato Pulp Pectic Polysaccharide on the Stability of Acidified Milk Drinks

In order to broaden the application of potato pulp pectic polysaccharide (PPP) in stabilizing acidified milk drinks (AMDs) and investigate the stabilizing effect and physical properties of AMDs prepared with PPP, a comparative study was made among PPP, commercial high methoxyl pectin (HMP) and low methoxyl pectin (LMP). The zeta potential, rheology, particle size and serum separation of AMDs were evaluated after preparing with PPP, HMP and LMP, respectively. Results indicated that PPP led to lower serum separation than LMP (14.65% for AMDs prepared with 0.5% PPP compared to 25.05% for AMDs prepared with 0.5% LMP), but still higher than HMP (9.09% for AMDs prepared with 0.5% HMP). However, narrower particle size distribution and lower viscosity of AMDs was achieved by PPP than by LMP and HMP. PPP can electrostatically adsorb on the surface of casein and its abundant neutral sugar side chains would provide steric hindrance to prevent casein flocculation in AMDs. Our results might provide some new ideas for the application of PPP in improving the stability of AMDs.     

Synthesis of a novel tri-substituted triazine monomer used for UV curable intumescent flame-retardant coating

Journal of Thermal Analysis and Calorimetry - A novel tri-substituted triazine in which substituted methacrylated piperzinyl (TMAPT) was synthesized and was then blended with di(acryloyloxy propyl)...