BeH，BeD，BeT分子基态(X2Σ+)的结构与势能函数

采用量子力学从头算方法，运用二次组态相互作用QCISD(T)/aug-cc-pVTZ和电子相关单双耦合簇CCSD(T)/6-311++G(3df，2pd)研究了BeH，BeD，BeT分子基态的结构与势能函数，计算出了这些分子的光谱数据(ω_e，ω_eχ_e，B_e，α_e，D_e)，结果与实验光谱数据吻合较好.这表明上述分子基态的势能函数可用经修正的Murrell-Sorbie+c₆函数来表示. 关键词： BeH BeD BeT分子基态 分子结构 势能函数     

密闭高温高压溶样ICP-MS测定24个国际地质标样中的Sb和Bi

研究了ICP-MS分析中Bi,Sb,Te和As产生的记忆效应,其记忆效应Bi>Sb>Te>As。在低浓度硝酸介质中(0.01%～1%),贮存样品的聚丙烯瓶和ICP-MS的进样管道会对Bi元素产生严重的吸附作用。0.1%氢氟酸的清洗效果优于6%的硝酸,而6%的硝酸的清洗效果要优于0.1%高氯酸。在给定的仪器操作条件下,Sb和Bi的检出限分别为0.001和0.000 1 ng·mL-1。采用该清洗方法,结合密闭高温高压溶样,测定了24个国际地质标样中的Bi和Sb。大部分标样的测定结果与已有参考值吻合较好。文章还给出了国际标样AGV-2(安山岩)、BHVO-2(玄武岩)和BCR-2(玄武岩)中Bi和Sb的测定值。     

全球变暖背景下温室效应的光谱能量分布分析

利用一维辐射传递方程及LBLRTM逐线积分模式建立计算模型,对工业革命前与目前大气构成情况下温室效应的能量分布及其光谱吸收机理进行分析,在保持温室气体浓度为当前水平的基础上,研究温室效应能量分布与地表温度之间的相互耦合机理.结果表明:工业革命前地球的温暖环境主要来自于大气温室气体的(100~370)cm^-1、(640~710)cm^-1以及(1370~2000)cm^-1三个强吸收带对于地球长波辐射的吸收,而地球当前的变暖则源自于大气的(370~640)cm^-1和(710~1370)cm^-1两个弱吸收带的作用,其对工业革命以来所额外增加的温室效应贡献分别达到了25%和55%;地表温度升高,温室效应在全波段范围内也会随之增强,但不同谱带处的温室效应贡献以地球平均温度所对应的辐射峰值波数为界线,峰值波数右侧的温室效应贡献将会增加,在其左侧的贡献比例则会减小.     

基于Vega的红外图像仿真

介绍了红外成像仿真的基本理论,讨论了利用Vega传感器模块将输入的可见目标图像生成红外图像的技术。该技术使用Creator软件进行三维几何建模和纹理映射,使用TMM软件进行红外材质建模;然后,用Mat软件进行大气衰减的计算;最后,用SensorWorks软件进行传感器特性建模,通过光电转换生成红外图像。以阿帕奇AH6直升机为例进行了红外图像仿真,结果表明,利用Vega传感器模块进行传感器建模,建模效果较好,成本低,易于工程实现。     

Evaluation and prediction of the degradation of space Si solar cells induced by a low-earth-orbit radiation environment

Space-graded silicon solar cells are evaluated by 1 MeV and 2 MeV electron-irradiation. The mean degradation of the maximum power (P_max) is presented and analyzed. The degradation at both electron energies has been correlated with the displacement damage dose (D_d). A good linearity between the electron D_d and the mean P_max degradation is obtained. The concept of D_d has also been used to predict the Si solar cell response in a low-earth-orbit (Altitude 799 km, Inclination 99^o) radiation environment, considering the shielded effect of a 120 μ m-thick silica coverglass on reducing the radiation. Compared with the on-orbit data from a Si solar array of a Chinese satellite (duration from April 2007 to July 2010), a good match can be found between the on-orbit data and the predicted results using D_d methodology, indicating the method is appropriate for evaluating the radiation damage of the solar cells, and also to provide a new technique for studying radiation effects on the optoelectronic detectors used in many high energy physics applications, where harsh radiation environments produce damage in optoelectronic device materials.     

Total cross sections for electrons scattering from simple molecules containing the larger atom sulfur at 30-5000eV

A complex optical model potential modified by the concept of bonded atom, which takes into consideration the overlapping effect of electron clouds, is employed to calculate the total cross sections for electrons scattering from simple molecules （SO2, H2S, OCS, CS2 and SO3） containing the larger atom, sulfur, at 30-5000eV by using the additivity rule model at Hartree-Fock level. The quantitative molecular total cross section results are compared with those obtained in experiments and other calculations wherever available, and good agreement is obtained. It is shown that the additivity rule model together with the complex optical model potential modified by the concept of bonded atom can give the results closer to the experiments than the one unmodified by it. So, the introduction of bonded-atom concept in complex optical model potential betters the accuracy of the total cross section calculations of electrons from the molecules containing the larger atom, sulfur.     

一种新型桥路型HTSFCL的实验研究

在研究一种新型桥路型高温超导限流器的限流原理的基础上，研制开发了一台三相600V、故障电流峰值100A的实验室样机．本文介绍了该限流器的功率电路、控制器、低温容器和高温超导磁体等部分的结构特点和功能．在三相系统中进行了各种短路故障限流实验，结果表明该限流器有较强的限流能力和重合闸能力，说明新型高温超导限流器的研究对改善电网动态性能和提高电网电能质量有十分重要的意义．     

尘埃粒子计数器中光源对传感器光通量的影响分析

在Mie散射理论基础上，由单分散射的光强表达式导出在偏振光的入射条件下一定立体角内的散射光通量的表达式，并与自然光入射作比较。计算了在相同强度不同光源入射下，尘埃粒子计数器的两种常用散射光收集系统收集的散射光通量。结果表明：采用近前向散射光收集系统得到的光通量相等；而采用直角方向散射光收集系统时两者并不相等，且在平面偏振光入射时，收集的散射光通量还跟探测器中心与入射光偏振方向夹角有关。用MATLAB编程计算，得出了在探测器中心与偏振方向的夹角成90°或270°位置时，收集的散射光通量有极值的结论，为激光尘埃计数器传感器光学设计提供了依据。     

RIBLL终端LASCAR闪烁体阵列探测器研制进展

介绍了RIBLL终端LASCAR闪烁体阵列探测器的工作原理和结构特点. 描述了为满足放射性核束实验的要求而对阵列所作的重要改进. 给出了LASCAR构型优化改造的工作设想和实施步骤. The principles and structure characteristics of LASCAR scintillator array detector at RIBLL terminal are described. Special emphases are laid upon the latest progress for the development of LASCAR array detector to meet the requirements of the RIB experiments. The working plan and steps for optimizing configuration of the LASCAR multi unit neutron scintillator array detector are also presented.     

废轮胎热解油的成分分析及二次热解反应

对废轮胎在中试回转窑中进行中温热解(450~650℃)所得热解油进行了GC-MS研究。通过对热解油化学组成 的全面分析,讨论了轮胎热解反应,尤其是较高热解温度和较长气相停留时间下的二次热解反应途径。通过与不同反应器 的比较研究,进一步得出了微负压回转窑热解技术的反应特点,并为回转窑热解油的应用提供了重要参考依据。