An environmentally benign benzylic oxidation catalyzed by hypervalent iodine intermediate in water

An effective and environmentally benign benzylic oxidation for transition of alkylarenes into the corresponding carbonyl compounds was reported.Alkylarenes were mixed and stirred with potassium bromide,m-chloroperbenzoic acid and a catalytic amount of iodobenzene in water at 60 8C for several hours,a series of the corresponding carbonyl compounds was obtained in moderate to good yields.In the reaction,iodobenzene was first oxidized by m-chloroperbenzoic acid into the hypervalent iodine intermediate which then reacted with potassium bromide to form the key radical initiator for the benzylic oxidation.     

Pyrrole alkaloids from <Emphasis Type=Italic>Alhagi sparsifolia</Emphasis>

The novel pyrrole alkaloid alhagifoline A (1) together with the two known analogs pyrrolezanthine (2) and pyrrolezanthine-6-methyl ether (3) were isolated from the aerial part of Alhagi sparsifolia. Their structures were established based on spectral (HR-ESI-MS, ¹ H and ¹³C NMR, ¹ H–¹ H COSY, HSQC, HMBC) data. Compounds 2 and 3 were isolated from the genus Alhagi for the first time.     

Existence of Surface Waves and Band Gaps in Periodic Heterogeneous Half-spaces

We find a sufficient condition for the existence of surface (Rayleigh) waves based on the Rayleigh-Ritz variational method. When specialized to a homogeneous half-space, the sufficient condition recovers the known criterion for the existence of subsonic surface waves. A simple existence criterion in terms of material properties is obtained for periodic half-spaces of general anisotropic materials. Further, we numerically compute the dispersion relation of the surface waves for a half-space of periodic laminates of two materials and demonstrate the existence of surface wave band gaps.     

Synthesis of tetrasubstituted thiophenes from pyridinium 1,4-zwitterionic thiolates and modified activated alkynes

Pyridinium 1,4-zwitterionic thiolates were applied to a formal [3 + 2] annulation reaction with modified activated alkynes, affording various tetrasubstituted thiophenes with aryl, alkenyl, alkyl or silyl group at the special position. The structural modification of alkyne substrates enabled the synthesis of diverse thiophenes to be achieved using the pyridinium 1,4-zwitterionic thiolates as the sulfur-containing building blocks. This approach is metal-free and catalyst-free.     

Circuit analysis of the compound quasi-optical power combiner

In 1991, we developed a new type of quasi-optical power combiner, called a compound quasi-optical power combiner, at Ka-band. In this paper, the circuit of such a compound quasi-optical power combiner is analysed. Its equivalent circuit model is proposed. The circuit equations, the balance condition, the injection locking and the stabilized condition of the compound quasi-optical power combiner are studed by the equivalent circuit model. As an example, a compound quasi-optical power combiner which consists of two single—cavity, two—device power combiners is analysed     

核磁共振数据的参数化谱分析方法

讨论参数化谱分析方法的基本原理以及基于高阶Yule-Walker方程组的参数计算方法,提出了一种新的从数据中估计谱线根数的方法,实验表明,该方法是有效的。     

A1Ⅱ离子3snp^1p1序列能级辐射寿命的非单调变化

本文考虑了一价铝离子双激发干扰态３ｐ４ｓ＾１ｐ１＾０对ｓｎｐ＾１Ｐ１＾０Ｒｙｄｂｅｒｇ序列的强相互作用，多组态ＨＦＲ自洽场方法计算了Ａ１Ⅱ３ｓｎｐ＾１Ｐ１０（ｎ＝３－１０）序列能级的辐射寿命，与已有的实验和理论计算结果进行了比较，结果表明该序列能级寿命随主量子数ｎ呈现非单调变化。     

低功率泵浦Ti：Al2O3自锁模激光器

本文报道了低功率泵浦的Ｔｉ：Ａｌ２Ｏ３激光器实现了稳定的自锁模运转，锁模脉冲宽度为１８０ｆｓ。分析了激光器的结构及工作特性。