固相微萃取气相色谱法测定非那雄胺中残留的二氯甲烷和三氯甲烷

利用固相微萃取气相色谱法测定非那雄胺中的溶剂残留,对固相微萃取的萃取温度、萃取时间、解吸时间和溶液的离子强度等分析条件进行了优化.该方法具有较好的线性,相关系数:二氯甲烷为0.997,三氯甲烷为0.998;相对标准偏差:二氯甲烷为2.7%,三氯甲烷为1.8%.     

Production of Atosiban’s Key Intermediate Pentapeptide: Synthetic Approaches to the Development of a Peptide Synthesis with Less Racemization and Simplifier Purification Process

The key intermediate NH₂-Ile-Thr(Bzl)-Asn-Cys(Bzl)-Pro-COOH of Atosiban was prepared from N-Boc-S-Bzl-cysteine by the stepwise lengthening of the chain according to the repetitive N,O-bis(trimethylsilyl)acetamide/N-hydroxysuccinimide ester (BSA/NHS) strategy. This synthetic route required no chromatography purification and can be readily performed, yielding a highly pure pentapeptide compound.     

Stable Zinc-Based Metal-Organic Framework Photocatalyst for Effective Visible-Light-Driven Hydrogen Production

Herein, a new Zn-MOF material, [Zn(L1)(L2)], 1, was built successfully through a one-pot solvothermal method. The 3D MOF structure was determined by Single X-ray diffraction analysis, IR, and elemental analysis. A series of PXRD tests of 1 after being immersed in different solvents and pH solutions demonstrated the good stability of 1. Interestingly, this material displayed high catalytic activity for the visible-light-driven hydrogen generation under the illumination of white LED in pure water or a mixture of DMF and H₂O without additional photosensitizers and cocatalysts. Besides, the studies also showed that the catalytic activity changed constantly as well as the solvent ratio adjustment of DMF and H₂O from 4:6 to 2:8. Additionally, the catalytic activity reached the best value (743 μmol g⁻¹ h⁻¹) when the solvent ratio was 4:6. The heterogeneous nature and recyclability of the MOF catalyst, as well as several factors that affect the catalytic activity, were investigated and described in detail. Moreover, the photocatalytic mechanism for the hydrogen generation of 1 was also proposed based on the fluorescence spectra and UV-vis absorption.     

亚表面引发原子转移自由基聚合构筑温度响应型纳米纤维油水分离膜

亚表面引发聚合是一种用于制备共价嵌入型聚合物刷的新型改性策略.该方法在发展高稳定性聚合物刷功能化表界面材料方面具有显著的优势.本工作利用亚表面引发原子转移自由基聚合(sSI-ATRP)对静电纺丝聚丙烯腈(PAN)基纳米纤维膜进行亚表面改性,通过接枝聚N-异丙基丙烯酰胺(PNIPAM)制备了温度响应型纳米纤维油水分离膜(...     

Consistency in formulation of spin current and torque associated with a variance of angular momentum

Based on the Noether's theorem, we develop systematically and rigorously the spin-dependent formulation of the conservation laws. The effect of the electronic polarization due to the spin-orbit coupling is included in the Maxwell equations. The polarization is related to the antisymmetric components of spin current, and it provides a possibility to measure the spin current directly. The variances of spin and orbit angular momentum currents imply a torque on the "electric dipole" associated with the moving electron. The dependencies of the torque on the polarization and the force on the motions of spin-polarized electrons in a two-dimensional electron gas with the Rashba spin-orbit coupling are discussed.     

Working group report: Flavor physics and model building

This is the report of flavor physics and model building working group at WHEPP-9. While activites in flavor physics have been mainly focused on B-physics, those in model building have been primarily devoted to neutrino physics. We present summary of working group discussions carried out during the workshop in the above fields, and also briefly review the progress made in some projects subsequently.     

Soft ZnSe nanobelts: Characterization and feasibility for assembling tubular ZnSe nanostructures

Soft ZnSe nanobelts were synthesized by taking Triton X-100 as the template surfactant in a microemulsion. Orderly alternating grooves and bulges on the surface of the nanobelts were first observed via TEM images, and potentially divide a nanobelt into quantum wire bundles. We found that the as-prepared nanobelts show remarkable varied photon scattering and optical properties. A tubular ZnSe structure was successfully obtained with extra treatment. This is an important phenomenon because that the regular folded nanobelts should help us to understand the plastic mechanical properties in a nanoscale assembled tubular structure of nanomaterials and modulate the optical properties of semiconductors.     

Multiparametric Evaluation of Dysphonic Severity

SUMMARY: In recent years, the multiparametric approach for evaluating perceptual rating of voice quality has been advocated. This study evaluates the accuracy of predicting perceived overall severity of voice quality with a minimal set of aerodynamic, voice range profile (phonetogram), and acoustic perturbation measures. One hundred and twelve dysphonic persons (93 women and 19 men) with laryngeal pathologies and 41 normal controls (35 women and six men) with normal voices participated in this study. Perceptual severity judgement was carried out by four listeners rating the G (overall grade) parameter of the GRBAS scale. The minimal set of instrumental measures was selected based on the ability of the measure to discriminate between dysphonic and normal voices, and to attain at least a moderate correlation with perceived overall severity. Results indicated that perceived overall severity was best described by maximum phonation time of sustained /a/, peak intraoral pressure of the consonant-vowel /pi/ strings production, voice range profile area, and acoustic jitter. Direct-entry discriminant function analysis revealed that these four voice measures in combination correctly predicted 67.3% of perceived overall severity levels.     

Influence of Co–Zr substitution on coercivity in Ba ferrites

Polycrystalline BaCo_xZr_xFe_11.5−2xO_18.25 samples with 0?x?0.6$0?x?0.6$ ions per formula units were prepared by modified citrate precursor method with the initial ratio of Ba:Fe equal to 1:11.5. The cationic site preferences of Co²⁺ and Zr⁴⁺ in Co–Zr substituted Ba ferrite were investigated by magnetic measurements and X-ray diffractometer (XRD) analysis. The coercivity H_c was decreasing with increasing Co–Zr substitution. The datum showed that the max coercive force (H_c) was obtained when substitution of 0.2, while the best saturation magnetizations (M_s) was obtained when substitution of 0.4.