Conjugated polymers containing electron‐transporting,hole‐transporting,and light‐emitting units in the polymer main chain

Conjugated polymers containing electron‐transporting, hole‐transporting, and blue light‐emitting units were synthesized by Suzuki polycondensation. These copolymers exhibited excellent thermal and optical stability. Optical investigation indicated that the incorporation of the spirobifluorene units in the polymer main chain could markedly increase the effective conjugation length of polymers. Electrochemical studies showed that the incorporation of spirobifluorene unit could raise the electrochemical stability and improve the electron‐ and hole‐injecting abilities. The electroluminescent results also showed that the introducing of spirobifluorene units could significantly improve the device performance. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1349–1356, 2008     

Branched polymer via free radical polymerization of chain transfer monomer: A theoretical and experimental investigation

A simple mathematic model for the free radical polymerization of chain transfer monomers containing both polymerizable vinyl groups and telogen groups was proposed. The molecular architecture of the obtained polymer can be prognosticated according to the developed model, which was validated experimentally by homopolymerization of 4‐vinyl benzyl thiol (VBT) and its copolymerization with styrene. The chain transfer constant (C_T) of telogen group in a chain transfer monomer is considered to play an important role to determine the architecture of obtained polymer according to the proposed model, either in homopolymerization or copolymerization. A highly branched polymer will be formed when the C_T value is around unity, while a linear polymer with a certain extent of side chains will be obtained when the C_T value is much bigger or smaller than unity. The C_T of VBT was determined to be around 15 by using the developed model and ¹H NMR monitored experiments. The obtained poly(VBT) and its copolymers were substantiated to be mainly consisted of linear main chain with side branching chains, which is in agreement with the anticipation from the developed model. The glass transition temperature, number average molecular weight, and its distribution of those obtained polymer were primarily investigated. This model is hopefully to be used as a strategy to select appropriate chain transfer monomers for preparing hyperbranched polymers. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1449–1459, 2008     

Miscibility and isothermal crystallization behavior of polyamide 6/poly(vinyl alcohol) blend

An investigation of miscibility and isothermal crystallization behavior of Polyamide 6 (PA6)/Poly(vinyl alcohol) (PVA) blends was conducted. Fourier transform infrared spectra (FTIR) analysis indicated that the interactions between the carbonyl groups of PA6 and hydroxyl groups of PVA increase as the weight ratios of PA6 to PVA of PA6/PVA specimens increase. This interaction between PA6 and PVA leads to their miscibility in the amorphous region and even some extent effects on their crystal phase, respectively. Further isothermal crystallization behavior of PA6/PVA indicate that the miscibility of PVA in PA6 leading difficulty in crystallization of PA6. Several kinetics equations are employed to describe the effects of PVA on the crystallization properties of PA6 in PA6/PVA blends in detail. © 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 1360–1368, 2008     

Mechanism of N-octadecyl-N′-maleoyl-L-phenylalanine self-assembled into supramolecular structures

N-Octadecyl-N′-maleoyl-L-phenylalanine(ODMA-L-Phe)was synthesized through the condensation,deprotection and acid- ylation reaction of BOC-L-phenylalauine,octadecylamine and maleic anhydride,ODMA-L-Phe can self-assemble in some organic solvents and turned them into thermally reversible physical supramolecular organogels.The morphology of ODMA-L-Phe aggregates was characterized by polarized optical microscopy(POM)and field emission scanning electron microscope(FE-SEM). The aggregates of ODMA-L-Phe were needle-like fibrils with diameters of approximately 100-200 nm.The mechanism of ODMA- L-Phe serf-assembly in organic solvents was investigated using ~1H NMR and circular dichroism(CD).The results indicated that hydrogen bonding was one of the main driving forces for the self-assembly of ODMA-L-Phe.     

Two Disparate 2‐fold Interpenetrating Frameworks Constructed from ZnII, 4,4′‐Dipyridyl Disulfide and Maleic/ Fumaric Acid

The reaction of Zn^II nitrate with maleic acid (H₂mal) / fumaric acid (H₂fum) and 4,4′‐dipyridyl disulfide (4‐pds) resulted under same conditions in two distinct interpenetrated compounds, namely [Zn(4‐dps)₂(H₂O)₂]·2Hmal ( 1 ) and [Zn(4‐dps)(fum)] ( 2 ). In 1 , Hmal anion adopts bridging mode based on hydrogen bonding, affording a 2‐fold parallel interpenetrated 3D→3D α‐Po net hydrogen‐bonded framework, in which 1D double‐stranded chains are formed, and then extended to a 3D supramolecular architecture combining second‐sphere hydrogen‐bonded interactions. For 2 , fum dianion takes on bis‐dentate bridging coordination fashion, furnishing a 2‐fold interpenetrated 2D→2D (4,4) layered coordination network, in which the tetrahedral Zn^II atoms are interlinked by 4‐dps and fum. Additionally, the compound 2 shows strong fluorescence in the solid state at room temperature.     

Determination of phenolic compounds in modern and old varieties of durum wheat using liquid chromatography coupled with time-of-flight mass spectrometry

An evaluation of the grain functional components of Italian durum wheat cultivars was conducted. The raw material was obtained from the field trial performed in 2006–2007 at the Experimental Farm of the University of Bologna, (Bologna, Italy). The aim of this study was to define the phytochemical profile of ten varieties, comprised of old and modern durum wheat genotypes, including quantitative and qualitative phenolic and flavonoid content (free and bound forms). The results showed that mean values of total phenolic compound and total flavonoid content in old wheat varieties (878.2 ± 19.0 μmol gallic acid equivalent/100 g of grain and 122.6 ± 25.4 μmol catechin equivalent/100 g of grain, respectively) did not differ significantly from those detected in modern genotypes (865.9 ± 128.9 μmol gallic acid equivalent/100 g and 123.5 ± 20.6 μmol catechin equivalent/100 g, respectively). However, the HPLC–ESI-TOF-MS analysis highlighted remarkable differences between modern and old cultivars. The interpretation of the mass spectra allowed the identification of 70 phenolic compounds, including coumarins, phenolic acids, anthocyanins, flavones, isoflavones, proanthocyanidins, stilbenes and lignans. The free extracts of ancient wheat varieties showed the presence of a mean number of phenolic compounds and isomer forms (8.7 ± 2.5 and 7.7 ± 4.7 respectively) significantly higher than in modern genotypes (4.4 ± 2.9 and 2.0 ± 2.4, respectively). A similar trend was observed also for the bound phenolic fraction. Moreover, the phytochemical profiles showed the presence of unique phenolic compounds in both free and bound fractions of some of the investigated wheat genotypes. Results highlighted that investigated old wheat cultivars may offer unique nutraceutical values for their peculiar contents in bioactive phytochemicals, suggesting their uses into a wide range of regular and specialty products naturally enriched with health-promoting compounds.     

A guide for ambitious professionals

Contents of Chinese journal of lasers volume 17, number 3, March 1990