全文获取类型
收费全文 | 7766篇 |
免费 | 1428篇 |
国内免费 | 1757篇 |
专业分类
化学 | 6461篇 |
晶体学 | 97篇 |
力学 | 428篇 |
综合类 | 158篇 |
数学 | 1093篇 |
物理学 | 2714篇 |
出版年
2024年 | 26篇 |
2023年 | 116篇 |
2022年 | 225篇 |
2021年 | 277篇 |
2020年 | 278篇 |
2019年 | 331篇 |
2018年 | 229篇 |
2017年 | 272篇 |
2016年 | 348篇 |
2015年 | 366篇 |
2014年 | 400篇 |
2013年 | 583篇 |
2012年 | 605篇 |
2011年 | 656篇 |
2010年 | 525篇 |
2009年 | 492篇 |
2008年 | 565篇 |
2007年 | 488篇 |
2006年 | 454篇 |
2005年 | 438篇 |
2004年 | 359篇 |
2003年 | 349篇 |
2002年 | 445篇 |
2001年 | 395篇 |
2000年 | 286篇 |
1999年 | 229篇 |
1998年 | 164篇 |
1997年 | 141篇 |
1996年 | 106篇 |
1995年 | 111篇 |
1994年 | 99篇 |
1993年 | 90篇 |
1992年 | 99篇 |
1991年 | 89篇 |
1990年 | 51篇 |
1989年 | 55篇 |
1988年 | 55篇 |
1987年 | 21篇 |
1986年 | 33篇 |
1985年 | 24篇 |
1984年 | 22篇 |
1983年 | 13篇 |
1982年 | 12篇 |
1981年 | 12篇 |
1980年 | 5篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1977年 | 3篇 |
1957年 | 2篇 |
1943年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
151.
A new series of MR-IPN polyacrylamide—poly(vinyl-ethylenediamine)chelatesorbents were prepared by the reaction of ethylenediamine with MR-IPN matrixes.The newchelate sorbent showed good sorption properties for auric and platinic ions. 相似文献
152.
The influence of both light and heat on the stability of nitrofurazone aqueous solution was studied. Results show that in either heating experiments or the exposure to light at high temperatures, the degradation rate obeyed zero-order kinetics. The total rate constant ktotal caused by both light and heat can be divided into two parts: ktotal =kdark klight, where kdark and klight are the degradation rate constants caused by heat and light, respectively. The klight can be expressed as klight=Alight*exp(-Ea,light/RT)*E, where E is the illuminance of light, and Alight and Ea,light both are experimental constants. The values of these kinetic parameters were determined based on the experiments in the dark and upon exposure to three different light sources. Results show that the values of Alight and Ea, light varied with the light source. To save time, labor, and drugs, exponential heating experiments were employed and compared with the isothermal experiments. Results indicated that kinetic parameters obtained by exponential heating experiments are comparable to those obtained by isothermal experiments either in the dark or upon exposure to light. 相似文献
153.
154.
Xi Bao Gao Jiang Yu Ning Li Hong Yin Yin Jing He Yang 《中国化学快报》2007,18(10):1289-1292
A new structured metallic nanomaterial of europium nanoparticle was prepared using tannic acid as the reductive agent,and nanoeuropium protein conjugates were synthesized by the method of lipoic acid modification on the surface of nanoparticle,which opens a new field of application of lanthanides in nanotechniques.Their properties were also characterized by UV-vis absorption spectroscopy,transmission electron microscopy (TEM),and fluorescence spectroscopy.The europium nanoparticle and its protein conjugates solution were stable and water-soluble.The fluorescence intensity of the composite europium nanoparticles was significantly increased in the presence of trace protein,and was linear proportional to the concentration of proteins under optimum conditions.According to this,a fluorimetric method for the determination of protein was developed in this paper. 相似文献
155.
beta-Phenylseleno-alpha-tolylsulfonyl-substituted alkenes were synthesized via the three-component conjugate-nucleophilic addition of acetylenic sulfones, phenylselenomagnesium bromide, and carbonyl compounds, such as aldehydes, aliphatic ketones, or alpha,beta-unsaturated enals or enones. The reaction is highly regio- and stereoselective with moderate to good yields. Functionalized allylic alcohols were obtained in the case of aldehydes and aliphatic ketones. In the case of alpha,beta-unsaturated enones, functionalized allylic alcohols or functionalized gamma,delta-unsaturated ketones were obtained, depending on the structures of the ketones. 相似文献
156.
157.
Two new spirostanol glycosides named agamenoside A and B, ere isolated from the fermented leaves of Agave americana. Their structures were elucidated as (23S,25R)-5α-spirostan-3β,6α,23-triol 3-O-α-L-rhamnopyranosyl-(1→3)-β-D-glucopyranosyl-(1→2)-[β-D-xylopyranosyl-(1→3)]-β-D-glucopyranosyl-(1→4)-β-D-galactopyranoside(1) and (25R)-5α-spiro-stan-3β,6α-diol 3-O-β-D-glucopyranosyl-(1→2)-[β-D-xylopyranosyl-(1→3)]-β-D-glucopyra-nosyl-(1→4)-β-D-galactopyranoside(2) by a combination of chemical and spectral methods. 相似文献
158.
Fingerprint quality control of Tianjihuang by high-performance liquid chromatography-photodiode array detection 总被引:5,自引:0,他引:5
A novel, simple and accurate fingerprint method was developed using high-performance liquid chromatography-photodiode array detection (HPLC-DAD) for the quality control of Hypericum japonicum thunb (Tianjihuang), a Chinese herbal medicine used for the treatment of several bacterial diseases, infectious hepatitis, gastrointestinal disorder, internal hemorrhage and tumors. For the first time, the feasibility and advantages of employing chromatographic fingerprint were investigated and demonstrated for the evaluation of Tianjihuang by systematically comparing chromatograms with a professional analytical software recommended by State Food and Drug Administration (SFDA). Our results revealed that the chromatographic fingerprint combining similarity evaluation could efficiently identify and distinguish raw herbs of Tianjihuang from different sources. The effects resulted from collecting locations, harvesting time and storage time on herbal chromatographic fingerprints were also examined. 相似文献
159.
In this paper, we further develop the molecular fractionation with conjugate caps (MFCC) scheme for quantum mechanical computation of DNA-ligand interaction energy. We study three oligonuclear acid interaction systems: dinucleotide dCG/water, trinucleotide dCGT/water, and a Watson-Crick paired DNA segment, dCGT/dGCA. Using the basic MFCC approach, the nucleotide chains are cut at each phosphate group and a pair of conjugate caps (concaps) are inserted. Five cap molecules have been tested among which the dimethyl phosphate anion is proposed to be the standard concap for application. For each system, one-dimensional interaction potential curves are computed using the MFCC method and the calculated interaction energies are found to be in excellent agreement with corresponding results obtained from the full system ab initio calculations. The current study extends the application of the MFCC method to ab initio calculations for DNA- or RNA-ligand interaction energies. 相似文献
160.
IntroductionTheincreasingcommercialvalueoftransitionmetalcomplexesofxanthateshasarousedconsiderableinterestintheirchemistry .Whiletheiranalyticalapplicationsarewellknown ,1theyarenowfindingextensiveuseinvulcan izationofrubber ,frothfloatationprocessforconcentrationofsulphideores ,asantioxidants ,lubricants ,2 ,3andhavebeenfoundtopossessfungicidalandinsecticidalactivi ties .4 Recently ,molecularrecognitionbetweenhostandguestmolecules ,inclusionphenomenaandnoncovalentmolecularinteractionarefunda… 相似文献