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991.
Tian S.-J. Xi G.-X. Cheng Q.-T. Lou X.-D. Li J.-H. 《Journal of Thermal Analysis and Calorimetry》1998,53(3):825-833
The inclusion complex of benzaldehyde (BA) with β-cyclodextrin (β-CD) was prepared and was studied by thermal analysis and
X-ray diffractometry. The composition of the complex was identified by TG and elemental analysis as β-CD·BA·9H2O. TG and DSC studies showed that the thermal dissociation of β-CD·BA·9H2O took place in three stages: dehydration in the range 70-120°C; dissociation of β-CD·BA in the range 235-270°C; and decomposition
of β-CD above 280°C. The kinetics of dissociation of β-CD·BA in flowing dry nitrogen was studied by means of TG both at constant
temperature and at linearly increasing temperature. The results showed that the dissociation of β-CD·BA was dominated by a
one-dimensional random nucleation and subsequent growth process (A2). The activation energy E was 124. 8 kJ mol-1, and the pre-exponential factor A 5.04·1011 min-1.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
992.
The carbohydrate chains decorating cell membranes and secreted proteins participate in a range of important biological processes. However, their ultimate significance and possible therapeutic potential have not been fully explored due to the lack of economical methods for their production. This study is an example of the use of a genetically engineered bacterial strain in the preparation of diverse oligosaccharides. Based on an ex vivo biosynthetic pathway, an artificial gene cluster was constructed by linking the genes of five associated enzymes on a plasmid vector. This plasmid was inserted into the E. coli NM522 strain to form globotriose-producing cells ('superbug' pLDR20-CKTUF). The specific strain was conveniently applied to the synthesis of globotriose trisaccharide and its derivatives, as potential neutralizers for Shiga toxin. This work demonstrates a novel and economical method for generating ligand diversity for carbohydrate drug development. 相似文献
993.
Xiong C Zhang J Davis P Wang W Ying J Porreca F Hruby VJ 《Chemical communications (Cambridge, England)》2003,(13):1598-1599
Novel constrained beta-turn dipeptide mimetics, 8-phenyl thiaindolizidinone amino acids 3, have been synthesized stereoselectively and incorporated into Leu-enkephalin peptides as a replacement of dipeptide Gly3-Phe4 to afford four individual isomers of Leu-enkephalin analogues 6. 相似文献
994.
Resonance double light scattering method for the determination of proteins with morin-CTMAB 总被引:3,自引:0,他引:3
Liu R Yang J Wu X Lan Z 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2002,58(14):3077-3083
A new determination method of proteins with the limit of determination at nanogram levels is proposed by using a common spectrofluorimeter to detect intensity of resonance double line scattering (RDLS). Proteins including bovine serum albumin (BSA), human serum albumin (HSA) can combine with morin and cetyltrimethylammonium briomide (CTMAB) in the pH range 7.0-8.0 and produce enhanced RDLS signal at lambda(ex)/lambda(em) 305.0/610.0 nm. Optimization conditions for the morin-protein-CTMAB interaction were tested. In the studied system, BSA/CTMAB/morin = 1:2:3. The association constant of morin with BSA is 5.2 x 10(4). Under the optimum conditions, the linear range is 7.5 x 10(-8)-1.0 x 10(-5) g/ml for BSA, 2.5 x 10(-8)-5.0 x 10(-6) g/ml for HSA. The detection limits (S/N = 3) are 66.0 ng/ml for BSA and 23.0 ng/ml for HSA, respectively. Four synthetic samples were analyzed satisfactorily. 相似文献
995.
Structure and properties of compatibilized recycled poly(ethylene terephthalate)/linear low density polyethylene blends 总被引:1,自引:0,他引:1
Blends of recycled poly(ethylene terephthalate) (R-PET) and linear low density polyethylene (LLDPE) were compatibilized with poly(styrene-ethylene/butyldiene-styrene) (SEBS) and maleic anhydride-grafted poly(styrene-ethylene/butyldiene-styrene) (SEBS-g-MA). Effects of compatilizer were evaluated systematically by study of mechanical, thermal and morphology properties together with crystallization behavior of PET. Tensile properties of the blends were improved effectively by the addition of 10 wt% SEBS-g-MA, elongation at break and charpy impact strength were increased with the increasing content of compatilizer. SEBS-g-MA is more effectual on mechanical properties of R-PET/LLDPE blends than SEBS. DSC analysis illustrates crystallinities of PET and LLDPE were increased by compatilizer at annealing condition. WAXD and FT-IR spectra show that annealing influences crystallization behavior of PET. Different compatilizer content results in different morphology structure, in particular, higher SEBS-g-MA content can induce the formation of a salami microstructure. 相似文献
996.
仲碳伯胺萃淋树脂吸萃金的性能及机理 总被引:3,自引:0,他引:3
研究了仲碳伯胺(N1923)萃淋树脂吸萃金的机理,溶液酸效应、吸附等温线、吸附速率、盐析剂效应及柱操作条件的影响等,将该树脂用于矿样中金含量的测定,结果与717^#离子交换树脂吸附法一致,取得了较好的结果。 相似文献
997.
过氧化氢氧化酸碱滴定法测定苯甲醛的含量 总被引:2,自引:1,他引:2
本文提出和建立了一种分析醛类化合物的方法,并用此方法测定了分析纯苯甲醛的含量为99.4%,相对标准偏差为0.21%,实验苯甲醛中所带的寻质苯甲醇以及乙醇,甲醇均不干扰测定,苯甲酸的干扰可以扣除,本法操作简单,终点易于掌握,推广应用方便。 相似文献
998.
笼形聚偕胺肟树脂的研究HX/ACAO树脂吸附贵金属 总被引:3,自引:0,他引:3
氢卤酸、硝酸、硫酸、磷酸和硼酸处理的笼形聚偕胺肟树脂(HX/A-CAO)对Ag+和等贵金属离子的吸附能力按如下顺序:PdCl42-:H3BO3/ACAO>BCAO>H3PO4/ACAO>HI/ACAO>H2SO4/ACAO>HCl/ACAO>HNO3/ACAO>HF/ACAO.IrCl62-:BCAO>H3PO4/ACAO>H3BO3/ACAO>HCl/ACAO>HF/ACAO>HI/ACAO>H2SO4/ACAO≥HNO3/ACAO.PtCl62:BCAO>H3BO3/ACAO>H2SO4/ACAO>HNO3/ACAO>HCl/ACAO>HF/ACAO>H3PO4/ACAO>HI/ACAO.Ag+:BCAO>H3BO3/ACAO>HI/ACAO>H2SO4/ACAO>HF/ACAO>HCl/ACAO>H3PO4/ACAO>HNO3/ACAO.AuCl4-:BCAO>H3BO3>H3PO4/ACAO>HF/ACAO>HCl/A-CAO>H2SO4/ACAO>HI/ACAO>HNO3/A-CAO.研究了H3BO3/ACAO树脂对Ag+和离子的吸附动力学,讨论了吸附机理. 相似文献
999.
1000.
超声波作用下羰基化合物的还原偶联反应 总被引:5,自引:0,他引:5
超声波在一些有机反应中有明显的促进作用「“,Luche等认为超声波的作用有两种主要类型[’j.一类是涉及电子转移的自由基或离子一自由基型反应,由于超声波的空化作用所产生的局部高温高压可以促进电子转移,从而明显地加快反应速度;对大多数离子型反应,超声波只能起到机械的物理作用.我们曾报道偕二卤化合物在Li、Na、Mg等金属作用下产生卡宾的反应是单电子转移过程,该反应可由于超声辐射而大大加速[‘];而在芳基叔脚的断裂反应中,超声波可以促进三苯基俄与金属馊反应生成二苯基脚负离子,但对它进一步的亲核取代反应却没有明… 相似文献