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981.
Uncovering the precise effect of the conjugated polymer chain length on the semiconducting properties in thin‐film devices is confounded by the step‐growth polymerization techniques typically used. Here, we use preparatory size exclusion chromatography to isolate fractions of two diketopyrrolopyrrole‐thiophene based co‐polymers with low molar‐mass dispersity, ?M, and number average molecular weights up to 180 kDa. We find that the charge carrier mobility can vary over three orders of magnitude in the range from 9 to 70 kDa, while a factor of 3–4 increase in photovoltaic performance was noted over the same range. The effect of ?M was found to be most drastic when the largest chains were mixed with the shortest. The study of the thin‐film morphology and crystallinity by GIWAXS give further insights into the origin of these effects. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 2245–2253  相似文献   
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Cellulose - Nanocelluloses occur under various crystalline forms that are currently being selectively used for a wide variety of high performance materials. In the present study, two cellulose...  相似文献   
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The non-parametric estimation of average causal effects in observational studies often relies on controlling for confounding covariates through smoothing regression methods such as kernel, splines or local polynomial regression. Such regression methods are tuned via smoothing parameters which regulates the amount of degrees of freedom used in the fit. In this paper we propose data-driven methods for selecting smoothing parameters when the targeted parameter is an average causal effect. For this purpose, we propose to estimate the exact expression of the mean squared error of the estimators. Asymptotic approximations indicate that the smoothing parameters minimizing this mean squared error converges to zero faster than the optimal smoothing parameter for the estimation of the regression functions. In a simulation study we show that the proposed data-driven methods for selecting the smoothing parameters yield lower empirical mean squared error than other methods available such as, e.g., cross-validation.  相似文献   
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We use density functional theory, newly parameterized molecular dynamics simulations, and last generation 15N dynamic nuclear polarization surface enhanced solid‐state NMR spectroscopy (DNP SENS) to understand graft–host interactions and effects imposed by the metal–organic framework (MOF) host on peptide conformations in a peptide‐functionalized MOF. Focusing on two grafts typified by MIL‐68‐proline ( ‐Pro ) and MIL‐68‐glycine‐proline ( ‐Gly‐Pro ), we identified the most likely peptide conformations adopted in the functionalized hybrid frameworks. We found that hydrogen bond interactions between the graft and the surface hydroxyl groups of the MOF are essential in determining the peptides conformation(s). DNP SENS methodology shows unprecedented signal enhancements when applied to these peptide‐functionalized MOFs. The calculated chemical shifts of selected MIL‐68‐NH‐ Pro and MIL‐68‐NH‐ Gly‐Pro conformations are in a good agreement with the experimentally obtained 15N NMR signals. The study shows that the conformations of peptides when grafted in a MOF host are unlikely to be freely distributed, and conformational selection is directed by strong host–guest interactions.  相似文献   
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Flying Elephants (FE) is a generalization and a new interpretation of the Hyperbolic Smoothing approach. The article introduces the fundamental smoothing procedures. It contains a general overview of successful applications of the approach for solving a select set of five important problems, namely: distance geometry, covering, clustering, Fermat–Weber and hub location. For each problem the original non-smooth formulation and the succedaneous completely differentiable one are presented. Computational experiments for all related problems obtained results that exhibited a high level of performance according to all criteria: consistency, robustness and efficiency. For each problem some results to illustrate the performance of FE are also presented.  相似文献   
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