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71.
PURE STATE APPROACH TO C(x)_αZ_nLIBINGREN;LINQING(InstituteofMathematics,AcademiaSinica,Beijing100080,China.Projectsupportedbyth?.. 相似文献
72.
四种多变量校准方法在FTIR多组分分析中的性能比较 总被引:1,自引:0,他引:1
本文对四种多变量校准方法--经典最小二乘法(CLS),偏最小二乘法(PLS),卡尔曼滤波法(KFM)以及人工神经网络法(ANN)--在多组分浓度分析方面的性能进行了比较。选择五种红外谱图严重混叠的大气有机毒物--1,3-丁二烯,苯,邻二甲苯,氯苯和丙烯醛--作为分析对象。分别计算各种方法对该5组分体系的平均预测误差MPE和平均相对误差MRE进行比较。结果表明,偏最小二乘法在处理这类问题中是最稳健的方法。 相似文献
73.
一类广义维里拉普拉斯,把在白噪声分析构架中通常定义的维里拉普拉斯作为特殊情形而包含。 相似文献
74.
用传统的预测效度估计法估计高考预测效度,其估计值往往偏低。为此,本文应用回归分析中混合估计理论提出了高考预测效度的混合估计。这种估计是预测效度的无偏估计,并解决了预测效度估计值偏低的问题。 相似文献
75.
Lin Zhengyan 《数学年刊B辑(英文版)》1998,19(3):281-292
§1.IntroductionandResultsLet{Xn,n1}beasequenceofrandomvariableswithacommondistributionfunctionF(x)andletXn1Xn2…Xnnbetheor... 相似文献
76.
LetK be a compact Hausdorff space, and letT be an irreducible Markov operator onC(K). We show that ifgεC(K) satisfies sup
N
‖Σ
j
=0N
T
j
g‖<∞, then (and only then) there existsfεC(K) with (I − T)f=g. Generalizing the result to irreducible Markov operator representations of certain semi-groups, we obtain that bounded cocycles
are (continuous) coboundaries. For minimal semi-group actions inC(K), no restriction on the semi-group is needed. 相似文献
77.
78.
In this research, a simple, sensitive chemiluminescence (CL) method for the determination of humic acid (HA) in water samples was first developed based on the redox reaction between humic acid and cerium(IV) in the acidic condition. Different with the former redox CL reaction which occurred in alkaline solution, no enhancers were needed and neither precipitation nor a second contamination would occur in the present CL system. Comparing with other spectrometric methods, we find that the proposed analysis system had better applicability and accuracy. Under the optimal experiment conditions, the CL peak height was linear with the concentration of HA in the range of 0.03 to 10.0 microg mL(-1). The detection limit is 0.01 microg mL(-1) (S/N = 3), and the relative standard deviation was 2.3% for 0.5 microg mL(-1) HA solution with eleven repeated measurements. The present CL method was successfully applied to the determination of HA in tap water, spring water and river water samples with good recovery from 90.0 to 110.0%. A possible CL mechanism was proposed based on the results of UV and fluorescence spectrometry and the CL spectrum of HA. It was speculated that the semi-quinone radicals in the excited state were the emitters. 相似文献
79.
Xiao‐Hui Liu Yan‐Guo Li Ying Lin Yue‐Sheng Li 《Journal of polymer science. Part A, Polymer chemistry》2007,45(7):1272-1281
The reversible addition–fragmentation chain transfer (RAFT) polymerization of acrylonitrile (AN) mediated by 2‐cyanoprop‐2‐yl dithiobenzoate was first applied to synthesize polyacrylonitrile (PAN) with a high molecular weight up to 32,800 and a polydispersity index as low as 1.29. The key to success was ascribed to the optimization of the experimental conditions to increase the fragmentation reaction efficiency of the intermediate radical. In accordance with the atom transfer radical polymerization of AN, ethylene carbonate was also a better solvent candidate for providing higher controlled/living RAFT polymerization behaviors than dimethylformamide and dimethyl sulfoxide. The various experimental parameters, including the temperature, the molar ratio of dithiobenzoate to the initiator, the molar ratio of the monomer to dithiobenzoate, the monomer concentration, and the addition of the comonomer, were varied to improve the control of the molecular weight and polydispersity index. The molecular weights of PANs were validated by gel permeation chromatography along with a universal calibration procedure and intrinsic viscosity measurements. 1H NMR analysis confirmed the high chain‐end functionality of the resultant polymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1272–1281, 2007 相似文献
80.
Yan Xu 《Journal of Mathematical Analysis and Applications》2007,329(2):1343-1354
In this paper, we obtain some normality criteria for families of meromorphic functions that concern the exceptional functions of derivatives. 相似文献