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81.
Hydrogen Permeation Properties of Perovskite-type BaCe_(0.9)Mn_(0.1)O_(3-δ)Dense Ceramic Membrane 总被引:1,自引:0,他引:1
Guang Tao LI Guo Xing XIONG* Shi Shan SHENG Wei Shen YANG State Key Laboratory of Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences Dalian 《中国化学快报》2001,(10)
In recent years, mixed-conducting oxides, in which both protonic and electronic charge carriers exist, have received increasing attentions1. Ceramic membranes made of such materials are semipermeable to hydrogen at elevated temperatures. In the early 1980s, Iwahara et al. first reported protonic conduction in SrCeO3-based materials2. Later, BaCeO3 system was extensively studied because of its higher conductivities. However, the electronic conductivity of rare earth doped-BaCeO3 ceramic… 相似文献
82.
La0.15Sr0.85Ga0.3Fe0.7O3-δ(LSGFO) and La0.15Sr0.85Co0.3Fe0.7O3-δ(LSCFO) mixed oxygen-ion and electron conducting oxides were synthesized by using a combined EDTA and citrate complexing method, and the corresponding dense membranes were fabricated. The properties of the oxide powders and membranes were characterized with combined SEM, XRD, H2-TPR, O2-TPD techniques, mechanical strength and oxygen permeation measurement. The results showed that LSGFO had much higher thermochemical stability than LSCFO due to the higher valence stability of Ga3+. After the temperature-programmed reduction by 5% H2 in Ar from 20℃to 1020℃, the basic perovskite structure of LSGFO was successfully preserved. LSGFO also favors the oxygen vacancy formation better than LSCFO. Oxygen permeation measurement demonstrated that LSGFO had higher oxygen permeation flux than LSCFO, but they had similar activation energy for oxygen transportation, with a value of 110 and 117 kJ ?mol~(-1), respectively. The difference in oxygen permeation f 相似文献
83.
New diterpenoid glucosides from Siegesbeckia pubescens 总被引:5,自引:0,他引:5
Jiang XIONG Qi Duan JIN Yun Long XU* Kunming Institute of Botany The Chinese Academy of Sciences Kunming 《中国化学快报》2001,(1)
Plants of the genus Siegesbeckia are annual herbs widely distributed in tropical and temperate zones and they are used as a traditional medicine to treat rheumatic arthritis, hypertension, malaria, neurasthenia and snake-bite in China. In previous papers, we reported on five new ent-kaurane and ent-pimarane diterpenoids, siegesbeckioside, siegesbeckiol and siegesbeckic acid1, orientalin A and B, and eight know compounds2,3. The present paper describes the isolation and structural elucidation … 相似文献
84.
85.
本文通过将抗癌活性化合物cis-[RuCl2(Me2SO)4]与L-组氨酸在乙醇溶液中或在溶剂热条件下反应,均得到了配合物[RuCl(Me2SO)2(L-His)](1).X-射线单晶结构分析表明该配合物的晶体属变形八面体,空间群P3121,a=b=14.0575(16)A,c=15.637(3)A,分子中含一个结晶水.该配合物中L-组氨酸配体分别通过氨基氮、咪唑氮、羧基氧与中心原子钌(Ⅱ)配位. 相似文献
86.
Cellulose may be readily converted into ethers involving primary and secondary alcohol groups in each monomer unit and the glycosidic bonds. However, these reactions are rather more complicated than with simple substances, because the stereochemistry of the cellulose molecule is such that the vast majority of its hydroxyl groups form intra-chain hydrogen bonds or inter-chain hydrogen bonds with contiguous molecules. Carboxymethylcellulose (CMC) has played an important part in the commercial uses of cellulose derivatives. CMC becomes alkali and water soluble. The polarity can, in fact, be increased by introduction of ionizing groups, ie carboxymethyl group. CMC is generally produced by the reaction of alkali cellulose with chloroacetic acid. 相似文献
87.
Polysaccharides, special those with physiological actions and nutrition, are widely used as an important resources for food, medicine industries, health etc. Herba Glossogynes Tenuifoliae (Shii-Take) is rich in polysaccharides with physiological actions and nutrition. Guizhou lies to the southwest of China, Natural resources abound in this province, in which there is high output and many species of Shii-Fake. So study in the Shii-Take is favor of reasonably utilizing the natural resources and getting high addvalue products. And what is more, It is necessary for energetically developing west economy. 相似文献
88.
本文将中国经济高增长与消费低增长现象概括为最终消费的锁定,借助广义资本核算方法及教育预防性储蓄视角,提炼最终消费锁定现象的两项基本假说,即核算锁定论和基本需求主导论。在改进后的长期均衡计量模型指导下,以协整检验、格兰杰因果检验、脉冲响应函数及方差分解法对中国1970至2010年相关数据进行分析验证并给出锁定原因及解锁途径:刺激消费总量,提升消费结构,有赖于提高绿色收入占比,监控消费支出泡沫化走势。 相似文献
89.
讨论和研究了受限于Salagean算子且同时满足:1+1/b((D~(n+1)f(z)/(D~nf(z)))-1)φ(z)和1+1/b((D~(n+1)f~(-1)(ω)/(D~nf~(-1)(ω))-1)Ψ(ω)的bi-单叶解析函数的系数估计问题,这里φ(z)和Ψ(ω)为正实部函数.主要的研究结果直接推广了先前相应工作. 相似文献
90.
熊炳忠 《数学的实践与认识》2015,(1):56-62
将MCMC算法融合到主成分回归分析模型中,提出MCMC主成分回归分析方法.新方法既具有有效避免解释变量之间的多重共线性问题以及简化回归方程结构的主成分回归分析方法的优势,又能够充分利用MCMC算法的融合先验信息、模型信息及样本似然函数的长处.将方法应用于对嘉兴市1997年至201.0年的经济发展指标的数据建模分析,结果表明,方法能有效克服现有分析方法的不足,建立预测精度更高的模型. 相似文献