Structural and Photoluminescence Properties of β-Ga2O3 Nanofibres Fabricated by Electrospinning Method

We have prepared the 13-Ga2 O3 nanofibres by electrospinning method followed by calcining in air at 900℃. The morphology and structure of the nanofibres are characterized by field emission scanning electron microscopy （FE-SEM）, x-ray diffraction （XRD） and Raman technique. These nanofibres have diameters ranging from 60 to 130hm and lengths up to several millimetres. Photoluminescence （PL） spectrum under excitation at 325 nm shows that theseβ-Ga2 O3 nanofibres have a blue emission peaking at 466nm, which may be attributed to defects such as the oxygen vacancies, gallium vacancies and gallium-oxygen vacancy pairs.     

Effect of Aspect Ratio Distribution on Localized Surface Plasmon Resonance Extinction Spectrum of Gold Nanorods

Gold nanorods with different aspect ratios are prepared in micells using a seeded growth method. Their extinction spectra are observed with an UV-visible spectrophotometer and analysed theoretically. It is known that there are two plasmon resonance peaks for gold nanorod corresponding to transverse and longitudinal plasmon resonance respectively. Moreover, the longitudinal plasmon resonance peak shifts to long wavelength when we increase the aspect ratio determined from TEM. Especially, we model the extinction spectrum using Gans' theory and compare it with our experimental result. Considering the aspect radios distribution of gold nanorods, it is found that longitudinal plasmon resonance peak will be wider than the nanorods with single aspect ratio, which is consistent with our experimental result. In addition, the effect of dielectric constant of surrounding medium is considered.     

Photonic Crystal Fibre SERS Sensors Based on Silver Nanoparticle Colloid

A photonic crystal fibre （PCF） surface enhanced Raman scattering （SERS） sensor is developed based on silver nanoparticle colloid. Analyte solution and silver nanoparticles are injected into the air holes of PCF by a simple modified syringe to overcome mass-transport constraints, allowing more silver nanoparticles involved in SERS activity. This sensor offers significant benefit over the conventional SERS sensor with high flexibility, easy manufacture. We demonstrate the detection of 4-mercaptobenzoic acid （4-MBA ） molecules with the injecting way and the common dipping measurement. The injecting way shows obviously better results than the dipping one. Theoretical analysis indicates that this PCF SERS substrate offers enhancement of about 7 orders of magnitude in SERS active area.     

钙原子4p_(1/2,3/2)ng(J=3)自电离Rydberg光谱的研究

利用Monte Carlo(MC)方法模拟研究了薄膜生长的初始阶段岛的形貌和岛的尺寸与基底温度和入射粒子剩余能量之间的关系.模型中考虑了粒子的沉积、吸附粒子的扩散和蒸发等过程.结果表明当基底温度从200K变化到260K时,岛的形貌经历了一个从分散生长逐渐过渡到分形生长的过程,并且在较低温度(200K)下,随入射粒子剩余能量的增加,岛的形貌也经历了同样的变化过程.进一步研究证明,随着基底温度的升高或入射粒子剩余能量的增加,沉积粒子的扩散能力显著增强,从而使岛的形貌发生了改变.     

退火对Pb辐照Al2O3单晶发光特性的影响

研究了230MeV的²⁰⁸Pb²⁷⁺辐照Al₂O₃样品及随后在600,900,1100K高温条件下退火后的光致发光特性。从辐照样品的测试结果可以清楚地看到在波长为390,450nm处出现了强的发光峰。辐照量为1×10¹³ions/cm²时,样品的发光峰最强。经过600K退火2h后测试结果显示,380nm发光峰剧烈增强,而其他发光峰显示不明显。在900K退火条件下,380nm的发光峰开始减弱,而在360,510nm出现了明显的发光峰,至到1100K退火完毕后380nm的发光峰完全消失,而360,510nm的发光峰相对增强。从被辐照样品的FTIR谱中看到,波数在460~510cm^-1间的吸收是振动模式,经过离子辐照后,吸收带展宽,随着辐照量的增大,Al₂O₃振动吸收峰消失,说明Al₂O₃振动模式被完全破坏。1000~1300cm^-1之间为Al—O—Al桥氧的伸缩振动模式,辐照后吸收带向高波数方向移动,说明其振动模式受到影响。辐照剂量较小的样品,损伤程度相对较低,经退火晶化后,振动模式基本恢复到单晶状态;辐照剂量较高的样品,损伤程度大,退火处理后表面变得较粗糙,振动模式并未出现,说明结构破坏严重。     

高效率金属微腔OLEDs性能

以半透明Ag膜为阳极出光面,利用MoO₃作为空穴注入层,在普通玻璃衬底上制备了底发射微腔OLEDs器件,其中微腔由接近全反射厚度为100nm的Al阴极和反射率约为50%左右厚度为22nm的半透明Ag阳极构成,由于采用了有效的空穴和电子注入层MoO₃和LiF,以Alq₃作为发光材料,器件的起亮电压为2.5V,在10V外加电压下正向亮度超过了15000cd/m²,最大电流效率接近6cd/A,大约是制备于ITO玻璃衬底阳极上的常规器件的两倍(3.2cd/A),并研究了光谱窄化以及随观测角度变化的微腔效应。     

激光点火系统温度效应及其控制技术的研究

激光点火系统应用于武器系统必须符合高低温性能的要求。研究了激光点火系统的高低温特性,得到了激光二极管阈值电流和输出光功率随温度变化的规律。基于对规律的分析,研制了带温控技术的激光点火系统。该系统以单片机为控制部件,以TEC为温控部件,以负温度系数热敏电阻为测温元件。     

多脉冲激光对K9玻璃的表面损伤实验研究

 实验研究了波长为1 064 nm、脉宽为10 ns、重复频率为1 Hz的激光脉冲对K9玻璃的表面损伤特点,给出了脉冲透过能量随激光脉冲作用次数变化的规律。采用3维立体显微镜对损伤形貌进行观察,发现K9玻璃的损伤表面呈环状分布,分为烧蚀区、微裂纹区和断裂区。随着激光脉冲个数的增加,损伤由点状破坏演变为损伤区,微裂纹逐渐增长,损伤面积逐渐增大。基于激光支持的爆轰波理论分析,激光与脆性材料的相互作用可引起微裂纹的大量增长。在多脉冲激光的作用下,K9玻璃损伤的累积效应明显,表面损伤阈值明显降低,表面裂纹增长明显,损伤面积逐渐增大;但随着激光脉冲的继续增加,这种损伤趋于稳定。     

多注毫米波行波管收集极的热设计

 为解决多注毫米波行波管收集极的散热问题,保障行波管工作可靠性与稳定性,利用 ANSYS 有限元软件模拟分析了收集极的传热特性,针对性地调整和优化了收集极相关参数与结构。研究结果表明：接触热阻是造成收集极具有较高温升的一个重要因素,由接触热阻所造成的温升约占收集极内外温度差的1/3;并不是第二电极与磁环接触宽度越宽所对应的收集极散热能力就越强,而是在一定工作条件下其散热能力存在极限值;对于绝缘陶瓷材料,应根据绝缘陶瓷的温度特性以及行波管的功率大小来进行选择;翼片式散热器是一种符合设计要求的理想散热结构。     

Na_2分子X~1Σ_g~ ,A~1Σ_u~ 和B~1Π_u态的势能函数

使用SAC/SAC-CI方法,利用6-311 g,6-311g**及cc-PVTZ等基组,对Na2分子的基态(X1Σg )、第一激发态(A1Σu )和第二激发态(B1Πu)的平衡结构和谐振频率进行计算.通过对3个基组的计算结果的比较,得出6-311g**基组为3个基组中最优基组的结论;使用6-311g**基组,分别利用SAC的GSUM(Group Sum of Operators)方法对基态(X1Σg ),SAC-CI的GSUM方法对激发态(A1Σu )和(B1Πu)进行单点能扫描计算,用正规方程组拟合Murrell-Sorbie函数,得到相应电子态的完整势能函数.用得到的势能函数计算与基态(X1Σg ),第一激发态(A1Σu )和第二激发态(B1Πu)相对应的光谱常数(Be,αe,ωe和ωeχe),结果与实验数据基本吻合.