Detection of Trace Heavy Metals Ions by Arrays of Titania Nanotubes Annealed in Nitrogen

Redox response of trace heavy metals ions(THMIs) has better performance on highly ordered vertically oriented titania nanotube arrays(TNA) annealed in nitrogen. Experimental data showed that different THMIs possess different reaction peak shapes and charge and discharge capacities. Therefore, the TNA will become an important tool used for environmental protection and facilitating the rapid determination of THMIs. THMIs of 5×10-4 mol/L concentration were measured at a scan rate of 100 mV/s. The analytical ut...     

水溶性六元瓜环衍生物与1,ω-亚烷基吡啶主客体配合物的^1HNMR及晶体结构

利用^1HNMR技术以及单晶X衍射技术考察对称四甲基取代六元瓜环（TMeQ[6]）与几种1,ω-亚烷基吡啶阳离子（ω=2,4,6,8,10）客体的相互作用．在这些包结配合物中,TMeQ[6]的端口效应以及空腔效应同时存在,其主客体作用模式随着客体亚烷基碳链长短不一而各不相同．对于客体1,2-二乙基吡啶（Edpy）,TMeQ[6]包结Edpy的带正电荷的吡啶环部分,形成一不对称的包结配合物;对于客体1,4-二丁基吡啶（Bdpy）,TMeQ[6]选择性包结Bdpy的吡啶环部分或烷基部分存在竞争作用和快速交换;而具有较长碳链的客体1,6-二己基吡啶（Hdpy）和1,8-二丁庚基吡啶（Odpy）与TMeQ[6]通过空腔的疏水作用以及外部的离子-偶极作用形成稳定的类轮烷包结配合物;客体1,10-二癸基吡啶（Ddpy）的两个吡啶环分别被两个TMeQ[6]包结形成哑铃型的包结配合物．     

环上带有广义导子和自同构的恒等式

设R是一个素环,RF是它的左Martindale商环.如果φ(xigik△ij)是环R的某个本质理想I的一个多重线性既约且带有自同构的广义微分恒等式,那么φ(zikj)是环RF的一个广义多项式恒等式.设R是一个具有特征P≥0的半素环,RF是它的左Martindale商环.如果φ(xigik△ijfik)是环R的一个多重线性既约且带有自同构的广义微分恒等式,那么φ(zikjfike(△ij)是环RF的一个广义多项式恒等式,这里fik和e(△ij)是RF中的幂等元.     

Simpson校正公式

给出了Simpson校正公式的截断误差,分析了复化Simpson校正公式的收敛阶.数值算例验证了理论分析的正确性.     

带参数悬臂梁问题的单增正解

讨论了带有参数的悬臂梁方程u(4)(t)=λf(t,u(t)),0相似文献   

奇异摄动Darcy-Stokes问题的一个矩形有限元

构造了一个新的非协调的矩形单元,分析了单元对奇异摄动Darcy-Stokes问题的稳定性,给出了有限元误差分析结果.用数值实验验证了理论分析结果.     

Z-蕴涵代数的Z-滤子

在[4]中,我们引入了Z-蕴含代数的概念,讨论了它们的一些性质.本文中,我们进一步引入Z-蕴含代数的Z-滤子,并研究它们一些有趣的结果.     

开放式基金投资组合风险实证—基于copula的分析

利用多元阿基米德Copula捕捉多个金融资产间的相关结构,并利用非参数核密度估计描述单个金融资产的边缘分布,建立Copula-Kernel模型。利用该模型和VaR风险测度,结合Mente Carlo模拟技术,对我国股票型开放式基金-华夏成长基金的投资组合进行风险分析。     

带免赔的奖惩系统的最优索赔策略

在汽车保险的奖惩系统中加入免赔额,将有利于保证风险与保费的匹配,还可以减少小额损失带来的大量管理费用.本文应用马尔科夫最优化原理推广了汽车保险的最优索赔策略模型.根据我国现行的机动车辆保险条款,得到了加入免赔额时的最优索赔策略.     

Shape-specific detection based on fluorescence resonance energy transfer using a flexible water-soluble conjugated polymer

We present the detection of the shape-specific conformation of DNA based on the fluorescence resonance energy transfer (FRET) by using a novel flexible water-soluble cationic conjugated polymer (CCP). The flexible backbone of CCP has more conformational freedom with the potential to be responsive to analyte shape by electrostatic interaction between flexible CCP and negatively charged DNA. The analyte shape dependent recognition is accomplished by structural changes that compressed or extended the flexible CCP. The morphology-dependent spectral properties of the novel flexible polymer related to the analyte shapes are investigated in detail, where two types of chromophores, referred to as "isolated" segment and "packed" segment aggregates, within the flexible polymer are identified by means of ensemble and single molecule measurements upon binding with different geometric DNA. The change in fluorescence intensity upon binding with shape-specific DNA without obvious color shifts makes this novel flexible polymer a suitable CCP donor for FRET measurements. The results provide insights for understanding the spectral properties of flexible water-soluble CCP and CCP/DNA interaction related to the geometry of target analyte.