A Study of Polarographic Adsorption Catalytic Wave of Trace Amounts of Yttrium

Determination of single rare earth element is relatively difficult since the properties of rare earth elements are so similar. Determination of trace amounts of yttrium in rare earth ores by adsorption catalytic polarographic has not been reported. In this paper, after several experiments, it is found that in NH₃-NH₄CL buffer solution which pH 9.2,yttrium, pyrocatechol violet(PV), 1.lO-phenanthroline(phen) and cetyltrimethylammniu bromide-(ClMAB) may form stable tetrabasic complex, which can produce penetrating and sensitive adsorption catalytic polarographic wave on multiple functional polarograph of PAR 384B-4.     

三个新茂钛催化剂的合成及苯乙烯间规聚合

合成了三个新茂钛催化剂:茂基三呋喃甲氧基钛,茂基三(四氢呋喃甲氧基)钛,茂基三苄氧基钛,其结构均经元素分析、^1HNMR、^1^3CNMR、IR及MS确证。它们与甲基铝氧烷(MAO)组成的催化体系对苯乙烯间规均聚合有良好的催化活性。     

光外差-塞曼调制磁旋转光谱技术的线型研究

光外差－塞曼调制磁旋光谱技术是一种高灵敏的吸收光谱技术。它同时对激光频率和样品的塞曼效应进行调制,然后通过双解调来提取微弱的光谱信号。文内导出了该信号的数学表达式,并对影响线型和灵敏度的多种物理参数进行了分析,获得了与实验相符合的结果。     

Exact Solitons of a d-Dimensional Discrete Modified KdV Equation

We show by using the real exponential approach that the d-dimensional discrete modified KdV equation has more general exact solitary wave solutions than the known bright soliton and kink solutions. Depending on the values of the parameters, the new solutions can describe both bright and dark solitary waves.     

Spatiotemporal Chaos Control with Pinning Signals in Distributed Systems

We suggest a local pinning feedback control for stabilizing periodic pattern in spatially extended systems. Analytical and numerical investigations of this method for a system described by the one-dimensional complex Ginzburg-Landau equation are carried out. We found that it is possible to suppress spatiotemporal chaos by using a few pinning signals in the presence of a large gradient force. Our analytical predictions well coincide with numerical observations.     

用CCD相机观测HL—1M弹丸消融过程

利用高速ＣＣＤ相机拍摄了ＨＬ－１Ｍ等离子体中注入氢弹丸时的Ｈａ辐射照片。得到的弹丸不同形状消融云照片表明：弹丸轨迹发生弯曲和出现条纹。通过对照片的处理获得了辐射光强的空间分布、弹丸的速度与轨迹,分析了弹丸与等离子体相互作用的物理机制,为进一步在弹丸注入条件下用ＣＣＤ测量等离子体局部磁场和电流分布打下了基础。     

应用UHF-INDO方法对氰乙酸自由基结构的计算

本文应用UHF-INDO方法研究了氰乙酸自由基的结构.计算了氰乙酸自由基的本征值.本征向量、价电子密度、自旋密度、各向异性耦合常数、各向同性耦合常数以及总能量、键能和偶极矩:计算的各向同性耦合常数和各向异性耦合常数与实验值符合很好.     

千米级斜拉桥施工过程中主梁的预转折角研究

斜拉桥安装、张拉、起拱等系统的施工金过程分析和控制技术是一项涉及斜拉桥质量和安全的关键技术问题。本文以某千米级斜拉桥为例,采用一阶最优化计算方法来确定斜拉桥的合理施工状态。以成桥后主梁的线形为目标函数,施工中主梁节段的预转折角为设计变量,建立了斜拉桥施工控制的空间非线性有限元分析模型,模拟了钢箱主梁的悬臂拼装过程,求出各施工阶段节段的预转折角。     

Frequency-Dependent Stochastic Resonance in Globally Coupled Systems

A model of globally coupled bistable systems consisting of two kinds of sites, subject to a periodic driving and spatially uncorrelated stochastic force, is investigated. In the large system size limit, the problem of large number of coupled Langevin equations can be reduced to a simple problem of two coupled ordinary differential equations. Considering the finite size effect, we can derive two coupled Langevin equations. All the above three kinds of equations are numerically computed and compared with each other. Fkequency-dependent stochastic resonance is found, and the reduced equations can represent the high-dimensional system when the system size is large.     

高聚物介质中7-羟基喹啉的光谱特性

通过观测７－羟基喹啉（７ＨＱ）在甲基丙烯酸甲酯（ＭＭＡ）和甲基丙烯酸（ＭＡＡ）以不同配比共聚的基质中的吸收光谱和荧光光谱,研究基质对７ＨＱ各物种相对含量的变化和对７ＨＱ激发态质子转移的影响。结果表明基质中羧基数目增加,可使７ＨＱ各物种的相对含量发生变化,并有利于７ＨＱ发生激发态质子转移。