Al纳米线不同晶向力学行为和变形机制的模拟

采用分子动力学模拟计算方法,考察具有较高层错能的Al纳米线沿不同晶向的力学行为和变形机制。在相同计算条件下与具有较低层错能的Ni、Cu、Au和Ag等FCC金属纳米线进行比较。结果表明：在力学行为方面,Al纳米线的弹性模量呈现明显的结构各向异性,满足E_[111] > E_[110] > E_[100]的关系,这一关系在FCC金属纳米线中普遍成立;Al纳米线的屈服应力随晶向呈现σ_y[100] > σ_y[111] > σ_y[110]的关系,这一关系在具有较低层错能的FCC金属纳米线中不具有普遍性,这与体系中位错形成机制密切相关。根据拉伸变形过程微观结构的演变规律,阐明Al纳米线不同晶向的变形机制,并与具有较低层错能的Ni、Cu、Au和Ag等FCC金属纳米线的变形机制进行比较。结果表明,对于尺度较小的高层错能Al纳米线,Schmid因子和广义层错能均难以准确预测其变形机制。     

高压剪切作用下三水铝石的结构稳定性

利用旋转式金刚石对顶砧压机(RDAC)结合显微激光拉曼光谱和微区X射线衍射,研究了三水铝石(γ-Al(OH)₃)在高压剪切作用下的结构稳定性。常温加压至1.5 GPa,旋转180°后,γ-Al(OH)₃的结构开始转变。初始样品在高波数段的4个羟基伸缩振动峰(3363、3434、3524和3618 cm^-1)相继消失,出现3303和3560 cm^-12个新峰。低波数段拉曼谱强度明显减弱,无非晶态宽峰;Al-O-Al变形振动双峰(568、539 cm^-1)和Al-O伸缩振动肩峰(321和307cm^-1)分别融合为一个振动峰;4个羟基变形振动峰(1052、1018、981和922 cm^-1)仍然可见。继续加压至3.5 GPa,旋转360°后卸至常压,高波数段新出现的两个羟基伸缩振动峰、原Al-O-Al变形振动峰和Al-O伸缩振动峰仍然可见。对比准静水压条件下γ-Al(OH)₃高压相的拉曼谱和相转变压力(约2.7 GPa),认为常温高压剪切作用下γ-Al(OH)₃脱羟基生成了H₂O和H₃O^-₂。卸压样品微区的X射线衍射谱进一步揭示,在高压剪切作用下,γ-Al(OH)₃的(OH)-Al-(OH)配位八面体骨架被破坏,沿c轴方向原子叠加的层间距缩小,对称性增强。这种不同于准静水压实验的结构改变来自腔体内压力的不均匀分布(0.5~4.5 GPa)。高压剪切作用下,三水铝石的结构稳定性研究对查明板块冷俯冲带中含水矿物的稳定性,推演俯冲板片的物理化学性质以及板块俯冲的速率具有重要意义。     

氯化锌修饰蓝光量子点发光二极管EI北大核心CSCD

采用氯化锌(ZnCl_(2))修饰镉基CdSe/ZnS蓝光量子点(B-QD)薄膜,发现与量子点表面结合力更强的ZnCl_(2)能够部分取代量子点长链配体油酸,有效钝化量子点表面缺陷,提高薄膜的荧光量子效率(PLQY)。此外,由于ZnCl_(2)具有偶极作用,使量子点真空能级提高0.2 eV,一方面可改善电子和空穴载流子注入平衡,另一方面可有效降低发光器件的启亮电压,提高器件的发光寿命。这种无机配体修饰量子点薄膜的方法可能为解决蓝光量子点发光二极管(B-QLEDs)因空穴注入困难和量子点表面缺陷导致器件性能不高的问题提供一个有效思路。     

非圆化磨耗激励下高速列车转向架区域噪声边频带产生机理及影响

该文通过对车辆噪声和车轮非圆化磨耗开展跟踪测试和分析,发现存在车轮非圆化磨耗的列车在运行过程中,其转向架区域噪声窄带频谱上会出现了以非圆化磨耗激励频率为中心,以过轨枕频率为间隔等间距分布的噪声峰值(即噪声边频带).这使得车轮非圆化磨耗不仅会影响其激励频率处的列车轨道结构的振动和噪声,还会对其他频段的噪声产生重要影响.为...     

密立根油滴实验问题三则

密立根油滴实验在教学上依然存在诸多问题,比如元电荷的测量值偏差较大、元电荷的“目标函数法”求解方法问题以及油滴仪上紫外灯的使用等,若处理不好,会影响教学效果.本文认为元电荷的测量值偏差较大与显微镜分划板的准确性有关,也与实验者没有对油滴像调焦有关.“目标函数法”求解元电荷精度较高,本文对此用法进行了梳理,澄清了难点.紫外灯不能仅仅做为改变油滴电量的手段,本文从初始带有一个元电荷的油滴开始,通过测量每次电离之后的平衡电压,用电压的比值可以直观地证明电量量子化.     

高压烧结法合成致密纳米BaTiO3陶瓷结构和铁电性能研究

 在6 GPa压力、1 000 ℃温度条件下制备了致密的纳米BaTiO₃陶瓷，合成样品的平均晶粒尺寸为50 nm，理论密度在97%以上。通过介电测量，观察到了样品宽化的相变峰，它与粗晶陶瓷的相变峰大不相同。由于90°电畴的减少和退极化场的存在，观察到了细长的电滞回线，它是样品铁电性存在的有力证据，表明钛酸钡陶瓷的临界尺寸在50 nm以下。     

Optimization of the three-dimensional electric f ield in IH-DTL

The tuning process of the three-dimensional electric field near the beam axis is very important in the optimization of the Interdigital H-mode Drift Tube Linac (IH-DTL). The tuning of the longitudinal field distribution, the Kilpatrik (Kp) factor, and the transverse dipole field have been discussed in detail, combined with the radio-frequency tuning process of the 53.667 MHz short IH-DTL cavity, which was designed to accelerate ²³⁸U³⁴⁺ from 0.143 MeV/u to 0.289 MeV/u in the SSC-Linac injector project at the Institute of Modern Physics. The flatness criterion and the tube tuning method are discussed in order to meet the beam dynamics requirements. In the tube tuning process, the energy gain error in the cells should be reduced to less than ±2%, and the Kp factor should be reduced to 1.6. The transverse dipole field and the method that uses a "plunger" to dismiss this dipole field are evaluated. The experience gained from the first cavity optimization benefits the tuning process of the three remaining IH-DTL cavities in the SSC-Linac project.     

Fast calibration methods using cosmic rays for a neutron detection array

An overall irradiation and calibration technique was introduced and applied to a test scintillation detector array. An integral conversion method was used to reduce the nonlinearity of the time difference spectrum, and to improve the position determination especially for positions close to the two ends of a long scintillation bar. An overall position resolution of about 3.0 cm (FWHM) was extracted from the residual analysis method and verified by a direct measurement. Energy calibration was also realized by selecting cosmic rays at different incident angles. The bulk light attenuation lengths for the four test bars were also determined. It is demonstrated that these methods are especially efficient for calibrating large and complex detector arrays.     

Thermodynamic Performance Characteristics of a Brownian Microscopic Heat Engine Driven by Discrete and Periodic Temperature Field

A Brownian microscopic heat engine with a particle hopping on a one-dimensional lattice driven by a discrete and periodic temperature field in a periodic sawtooth potential is investigated. In order to clarify the underlying physical pictures of the heat engine, the heat flow via the potential energy and the kinetic energy of the particles are considered simultaneously. Based on describing the jumps among the three states, the expressions of the efficiency and power output of the heat engine are derived analytically. The general performance characteristic curves are plotted by numerical calculation. It is found that the power output-efficiency curve is a loop-shaped one, which is similar to one for a real irreversible heat engine. The influence of the ratio of the temperature of the hot and cold reservoirs and the sawtooth potential on the maximum efficiency and power output is analyzed for some given parameters. When the heat flows via the kinetic energy is neglected, the power output-efficiency curve is an open-shaped one, which is similar to one for an endroeversible heat engine.     

Two-Photon Fluorescence Property and Ultrafast Dynamics of Two Dipolar Compounds with Dipicolinate as Electron Acceptor

Linear and nonlinear photophysical properties of two novel dipolar compounds named as trans- dimethyl-4-[4＇-（N,N-dimethylamino）-styry1]-pyridin-2,6-dicarboxylate （Xiao-1） and trans-dimethyl-4-[4＇-（N,N-diphenylamino）-styry1]-pyridin-2,6-dicarboxylate （Xiao-2） are investigated by steady-state absorption and fluorescence spectroscopy, Z-scan and two-photon excited fluorescence measurements. Strong two-photon fluorescence emission and the pronounced positive solvatochromism are observed from two compounds. The two-photon absorption cross section of Xiao-2 is about 1.5 times larger than that of Xiao-1. One-color and two-color femtosecond pump-probe experiments are employed to investigate the excited state dynamics of two compounds. The relaxation lifetime of the intra-molecular charge transfer state is determined to be in the hundreds of picosecond domain for both the compounds in THF, and several tens of picosecond in DMSO solutions.