白光LED用新型Ce,Pr掺杂的YAG单晶荧光材料的光谱性能研究

为了改善白光LED用荧光材料效率低、均匀性差、光衰大、寿命短及物化性能差等不足,本文采用单晶荧光材料取代荧光粉来制备白光LED,并对白光LED用新型YAG单晶荧光材料的制备和光谱性能进行了研究.采用提拉法生长了白光LED用Ce∶YAG及Pr,Ce∶YAG晶体,并通过吸收光谱,激发、发射光谱对晶体材料的光谱特性进行表征.研究表明,Ce∶YAG单晶荧光材料可以被发射波长460 nm左右的蓝光芯片有效激发,产生一个范围为480~650 nm宽峰发射.通过Pr3+,Ce3+离子共掺杂可以有效补偿Ce3+离子单掺杂YAG荧光材料发光中的红色发光成分.     

Controllable optical mirror of cesium atoms with four-wave mixing

The controllable optical mirror is experimentally accomplished in a Λ-type three-level atomic system coupled with standing wave. It is shown that the reflection of probe light results from electromagnetically-induced-transparency-based four-wave mixing, therefore the reflection efficiency is highly dependent on the angle for phase matching condition between the probe and coupling fields. The measured reflection spectra show good agreement with dispersion compensation theory.     

侧链含查尔酮基团的聚(甲基)丙烯酸酯的光交联特性

采用红外光谱、热重分析、紫外光谱和荧光光谱对侧链含查尔酮基团的聚（4-甲基丙烯酰氧基-4'-二甲氨基查尔酮）（PMADMAC）和聚（4-丙烯酰氧基查尔酮）（PAC）的光交联特性进行了研究。随着光照时间的增加,PMADMAC和PAC聚合物光致环加成反应迅速进行,波长短的紫外线更易使得聚合物发生[2+2]环加成反应。与溶液状态相比,固体薄膜状态下的光交联反应速率较慢。PMADMAC聚合物更容易发生光致环加成反应,其光交联速率要比PAC聚合物快,环加成反应也更彻底。采用荧光光谱研究了聚合物的发光特性,发现PAC聚合物无荧光,而PMADMAC聚合物具有溶剂极性敏感的荧光特性。在PMADMAC聚合物的稀溶液中,随着365 nm紫外光照时间的增加,荧光强度迅速降低,其荧光特征波长在紫外光照射后发生蓝移。 PMADMAC和PAC聚合物的热稳定性较好,光交联后形成热不稳定的环丁烷结构,其热稳定性有所降低。     

785 nm激光诱导银纳米三角片聚集表面增强拉曼散射效应

为实现表面增强拉曼散射（SERS）光谱的强信号快速检测分析,报道了通过785 nm激光诱导银纳米三角片（AgNPRs）聚集的方法。采用配体辅助化学还原法制备了AgNPRs,其边长约为80 nm,表面等离子体吸收峰出现在约774 nm处,对785 nm光产生有效吸收。在785 nm光辐照下,AgNPRs逐渐聚集,对巯基苯甲酸的SERS信号逐渐增强,其源于AgNPRs吸收的光转化为热而引起的AgNPRs聚集。其增强因子高达10⁹。为快速获得强SERS信号,激发光功率需大于250 mW。     

Li2O-Al2O3-SiO2微晶玻璃表面粗糙度对纳米硬度测试的影响

 介绍了纳米压痕测试技术的基础理论及纳米压痕法常用的Oliver -Pharr方法的计算原理。采用纳米压痕试验测得不同表面粗糙度的Li2O-Al2O3-SiO2微晶玻璃样品的纳米硬度、弹性模量和载荷-位移曲线。结果表明样品表面粗糙度会降低纳米压痕测试结果的稳定性、准确性和可靠性：样品表面粗糙度越小,测得的纳米硬度和弹性模量值波动越小,载荷-位移曲线重合性越高。随着最大载荷的增大,测得的弹性模量逐渐减小,其原因是压痕边缘材料发生了塑形变形。在超光滑表面样品（Ra=0.9 nm）上测得较为准确的Li2O-Al2O3-SiO2微晶玻璃纳米硬度和弹性模量值分别为8.8 GPa和7.79 GPa。纳米压痕测试结果的重合度对于评价超光滑表面完整性研究具有指导意义。     

超长氧化锌纳米线的制备及其气敏性能和紫外传感应用研究

采用一种无需催化剂和载气的简便碳热还原法制得长度约为100 μm、直径约为500 nm、长径比达到200的超长ZnO纳米线,讨论了Si基底位置、沉积时间以及反应物原料的量对ZnO纳米线形貌的影响。对ZnO纳米线的气敏性能进行研究,结果表明：在工作温度为350 ℃时,ZnO纳米线传感器能够很好地检测酒精气体,具有选择性好、响应恢复快的优点,且最低检测体积分数为5×10^-6。另外,通过一种简单、实用的介电泳法制得基于ZnO纳米线的紫外传感器。在365 nm紫外灯照射下,光电流增加了13%;而在254 nm紫外灯照射时,光电流则没发生变化,说明该传感器对不同波长的紫外光有一定的选择性。     

A Continuous Variable Quantum Key Distribution Protocol Based on Entanglement Swapping of Quasi-Bell Entangled Coherent States

A continuous variable quantum key distribution protocol with entanglement swapping of quasi-Bell entangled coherent states is proposed. As the preliminary step, a sender shares quasi-Bell entangled coherent states with a receiver. After their measurements to distinguish the cases of a zero response, a nonzero even-photon response and an odd-photon response, two legitimate participants fulfill the task of key distribution. The correlations resulting from entanglement swapping of quasi-Bell entangled coherent states and the order rearrangement of transmitted states provide the possibility to protect secret key distribution. In the ideal channel, the success probability increases with the amplitude of the coherent state, and approaches unity when the amplitude of the coherent state is larger than two. However, in the loss channel, the decoherence will introduce error in the generated key, and the error rate increases with the amplitude of the coherent state. When the amplitude of the coherent state is smaller than 0.2 (or so), the error rate approaches zero, although the success probability is less than 0.5 in this case.     

Generation of 2－10ns Excimer Laser Pulse by Optical Synchronizing Wave－clipping

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