Maximum work configurations of finite potential capacity reservoir chemical engines

An isothermal endoreversible chemical engine operating between the finite potential capacity high-chemical-potential reservoir and the infinite potential capacity low-chemical-potential reservoir has been studied in this work.Optimal control theory was applied to determine the optimal cycle configurations corresponding to the maximum work output per cycle for the fixed total cycle time and a universal mass transfer law.Analyses of special examples showed that the optimal cycle configuration with the mass tr...     

An Efficient Synthetic Method of 11,12-DihydroxylEudesmanolide Sesquiterpenoid from a-Santonin

11,12-dioxygenated eudesmanolide sesquiterpenoid is a large kind of naturally occuring sesquiterpenoids isolated from the medicinal plants, such as J. glutinosa1 and Flourensia heterolepsis 2. In constrast to much investigation of their isolation and structure characterization, the less about their synthesis have been reported. One of the reason may be the difficult hydroxylation at C-11. For example, the synthesis of a simple natural product, kudtriol3, required thirteen steps of reactions f…     

Studies on the Epoxidation of Styrene with Hydrogen Peroxide Catalyzed by MCM-41 Supported Co(II) Phenanthroline Complex

The epoxide is a kind of versatile intermediate for manufacture of a wide variety of fine chemicals. The goal of modem efficient catalytic methods is to produce desired compounds with high yield, selectivity, low cost, safety, operational simplicity and more importantly environmentally benign manner. However, there are various oxidants, which are often hazardous or expensive, being used for both laboratory and industrial epoxidation. Hydrogen peroxide (30 wt%) solution is thought as one of the ideal oxidants because water is a sole theoretical side product. Meanwhile the epoxidation of styrene is a typical one among olefins. Here, the performance of styrene epoxidation was studied with hydrogen peroxide solution catalyzed by Co(Ⅱ) phenanthroline complex encapsulated in supercages of MCM-41.     

100MeV负氢回旋加速器高频冷模腔的理论与实验研究

在回旋加速器中,高频系统为带电粒子加速提供能量,高频谐振腔作为高频系统中的关键部件,它性能的好坏直接决定着粒子是否能够被加速,所以,高频谐振腔的设计非常关键.在100MeV负氢回旋加速器的设计中,在空间限制的同时,要求加速电压从中心区的60kV到出引区的120kV变化,这对谐振腔的设计提出了很高的要求.基于上述条件,本工作利用有限差分法的软件CST MICR0wAVESTUDIO设计的双内杆结构的44MHz高频谐振腔初步设计完成,根据初步设计的结论,加工与实际腔体尺寸1:1模型,模型高频参数测量的结果与CST MICROWAVE STuDIO的计算相吻合,结果是可信的.     

含稀土合金锌粉的制备及性能

从酸性氯化物电解液体系电解共沉积Er-Pb-In-Zn合金锌粉，通过析氢及TAFEL极化测定，比较加入稀土后耐蚀性的变化，电解液中加入不同缓蚀剂后合金锌粉耐蚀性变化；通过循环伏安测定合金锌粉制成的电极的循环寿命；以合金锌粉为负极活性材料，组装成LR6实际电池，其放电性能与加汞电池基本相当。     

基于生活水平货币度量的助学贷款被助者的经济效益研究

随着国民经济的增长以及教育成本的提高,大学学费也相应逐年提高.但是我国还存在相当数量的贫困生.助学贷款是解决贫困生完成学业的重要途径.论文站在助学贷款被助者的立场上,将被助者获得的经济效益进行了具体的定量化分析.首先分别讨论了两期不考虑银行利息率和考虑银行利息率情况下,基于CES型效用函数的助学贷款被助者经济效益的计算模型,然后分析了如何计算多期银行利息率情况下贷款被助者的经济效益.最后针对被助群体进行实证分析、计算并得出结论.     

RF system design and measurement of HIRF-CSRe

An RF system for the CSRe (cooling storage experimental ring) is designed and manufactured domestically. The present paper mainly describes the RF system design in five main sections:ferrite ring, RF cavity, RF generator, low level system and cavity cooling. The cavity is based on a type of coaxial resonator which is shorted at the end with one gap and loaded with domestic ferrite rings. The RF generator is designed in the push-pull mode and the low level control system is based on a DSP+FGPA+DDS+USB interface and has three feedback loops. Finally we give the results of the measurement on our system.     

面向对象的BESⅢ探测器模拟系统

BESⅢ探测器的模拟软件包BOOST, 是基于Geant4开发的面向对象的模拟软件. BOOST全面地模拟了BESⅢ探测器的物质和几何结构, 给出了粒子在各个子探测器中的击中信息, 以ASCII码文件的形式输出原始数据和MC truth信息可供重建软件开发和物理分析使用, 初步结果显示BOOST的模拟是合理的.     

CSR实验环电子冷却装置的纵向电子束温度

电子冷却装置中, 电子束纵向温度是计算冷却力的主要参量之一. 当电子与被冷却离子的相对速度很小时, 纵向冷却力与离子速度呈线性关系, 并且线性区域的宽度与电子束纵向温度有关. 通过分析影响电子束纵向温度的主要因素, 得到了兰州重离子冷却储存环实验环(CSRe)电子冷却装置中电子束纵向温度的大小.     

D.C.优化的最速下降法的收敛性

Some properties of a class of quasi-differentiable functions(the difference of two finite convex functions) are considered in this paper. And the convergence of the steepest descent algorithm for unconstrained and constrained quasi-differentiable programming is proved.