磷氮型极压抗磨添加剂对钢—铝摩擦副摩擦磨损性能的影响

采用ＳＲＶ摩擦磨损试验机评价了磷酸三甲酚酯（ＴＣＰ）、磷酸二丁酯（ＤＢＰ）、十二胺（ＤＡ）和磷酸胺盐（ＰＡＳ）抗磨添加剂在液体石蜡中对钢－铝摩擦副摩擦磨损性能的影响。采用Ｘ射线光电子能谱仪分析铝试磨痕表面边界润滑膜中的Ｐ和Ｎ元素的化学状态。结果表明,含Ｐ抗磨添加剂可以有效提高铝合金的耐磨性,而其中以磷氮剂的效果最好。其它含磷添加剂也可以有效地降低磨损。ＸＰＳ分析表明,在铝合金磨损表面形成了含磷酸铝     

Effect of Carrier on Activity of Immobilized Lipase in the Resolution of Naproxen

Several kinds of immobilization carrier were used for the resolution of naproxen by lipase from Candida rogusa in an aquous-organic biphase system^[1]. It was found that the nature of carrier has obvious effect on the activity of immobilized enzyme. From the table below we can see that MCM-41 molecular sieve showed the highest activity, while the celite modified by DMCS showed the lowest activity.     

Structure and Properties of Nanostructured Material of PtPbSb Surface Alloy Studied by Electrochemistry,XPS and STM

The preparation of electrocatalysts of high performance and low cost is one of the most important subjects in electrocatalysis. The use of glassy carbon (GC) as substrate has been investigated the most extensively^[1]. In the present work, the nanostructured material of PtPbSb alloy supported on glassy carbon (PtPbSb/GC) was prepared by electrochemical co-deposition method. The structure and properties of these electrocatalysts were studied through techniques of cyclic voltammertry, X-ray photoelectron spectroscopy (XPS)pl and scanning tunneling microscopy (STM).     

A Convenient Method for Synthesis Methyl Ester of Naproxen

α-Arylpropionic acids are a class of nonsteroidal anti-inflammatory drugs with a substantial size of market. Ibuprofen and naproxen are the important members of this family. Since carbonylation catalyzed by transition metal complexes provides an environmentally benign process for their synthesis, there have been numerous patents and publications related to the carbonylation of alcohols and olefins to produce α-arylpropionic acids or their esters^[1-4]. We have studied the carbonylation of α-(6'-methoxy-2'-naphthyl) ethanol to methyl ester of naproxen using PVP-PdCl₂-CuCl₂/PPh₃ catalyst system. Good conversion and selectivity were obtained under mild conditions.     

Racemization of R-Naproxen Ester Using Microwave Oven

(S)-(+)-2-(6-methoxy-2-naphthyl) propionic acid (Naproxen) is a nonsteroidal antiinflammatory drug which belongs to the family of 2-aryl propionic acid derivatives, which is widely used as a drug for human connective tissue diseases. The physiological activity of the S-form Naproxen is 28-fold that of the R-form^[1]. Hence, only the S-form is used as a drug for human diseases.     

Accurate Burst Trigger Mode for Dragon-Ⅰ Electron Beam Measurement System

The electron beam measurement system for Dragon-I must work synchronously with the beam production and transportation accurately in order to obtain correct data．The synchronization with about 1ns is important．The output waveform of Blumlein lines in pulsed-power system is of amplitude of about 250kV and 20ns active edge time(following edge)．The electron beam will hit the conversion target in about 145ns later steadily and the jitter time is about 1—2ns．The synchronization precision with the same level of the jitter time will be reached if the sharp following edge of waveform is selected to be the time base．The synchronization trigger signal for measurement system can be obtained by the way of differentiating the following edge and the accuracy of about ns can also be reached with suitable circuit parameters．The optical fiber is also adopted to remove the interference on the measurement system from the high voltage system．This kind of burst trigger mode overcomes many disadvantages such as low accuracy, long delay time, large jitter in normal trigger mode and can provide the trigger time accurately．It can meet the need to measure the electron beam parameters at any required time．     

亲水型光敏热成像材料的化学增感

由于光敏热成像(Photothermographic,PTG)材料采用简单的干法(热)加工取代传统AgX成像材料的湿法加工,对环境友好且能耗低,可以实时实地的获得影像硬拷贝材料,可以广泛应用于医疗影像硬拷贝、航空拍摄等领域,因此PTG材料具有强大的发展潜力,是传统AgX成像材料的一种理想替代材料.     

Unified Symmetry of Nonholonomic Mechanical Systems with Non-Chetaev＇s Type Constraints

Based on the total time derivative along the trajectory of the system, the unified symmetry of nonholonomic mechanical system with non-Chetaev＇s type constraints is studied. The definition and criterion of the unified symmetry of nonholonomic mechanical systems with non-Ohetaev＇s type constraints are given. A new conserved quantity, as well as the Noether conserved quantity and the Hojman conserved quantity, deduced from the unified symmetry, is obtained. Two examples are given to illustrate the application of the results.     

Noether-Form Invariance of Nonholonomic Controllable Mechanical Systems in Phase Space

In this paper, we study the Noether-form invariance of nonholonomic mechanical controllable systems in phase space. Equations of motion of the controllable mechanical systems in phase space are presented. The definition and the criterion for this system are presented. A new conserved quantity and the Noether conserved quantity deduced from the Noether-form invariance are obtained. An example is given to illustrate the application of the results.     

铽与两种不同结构羧酸配合物的低温固相合成及发光性质研究

以两种不同结构的羧酸苯乙酸和苯基羟基乙酸与氯化铽为原料,采用低温固相反应合成了两种羧酸铽配合物。经元素分析、稀土络合滴定、摩尔电导确定了配合物的组成为： Tb(L₁)₃·H₂O,Tb(L₂)₃·4H₂O(L₁= C₆H₅ CH COO- ,L₂=C₆H₅CH(OH)COO-)。测定了配体及配合物的IR谱、1H NMR及配体的磷光光谱和铽配合物荧光激发和发射光谱。根据磷光发射光谱数据计算了配体的三重态能级值。比较两个配合物的荧光发射主峰5D₄→7F₅强度： 苯基羟基乙酸铽为苯乙酸铽的5倍。由此可见在配体亚甲基上引入拉电子基团羟基,将会扩大共轭体系π电子的离域范围,提高能量传递效率,提高稀土离子的发光强度。