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851.
852.
Polycarbonates and copolycarbonates based on BPSi and BPA were easily made using the standard interfacial technique. Molecular weight and NMR data indicate that up to 4 mol % of the BPSi decomposes during polymerization via a base-catalyzed rearrangement of BPSi to arylsiloxanes. Oxygen index studies show an increased flame resistance with increasing BPSi monomer content. DSC measurements show a decrease in glass transition with BPSi monomer concentration while TGA shows an increase in char residue with BPSi monomer content. In addition, TGA indicates no change in either thermal or thermooxidative stability with the relative BPSi/BPA concentrations. Outdoor weathering of BPSi PC and BPA PC films indicates that BPSi PC is ca. 5 times more weathering resistant than BPA PC. This latter result can be attributed to a combination of BPSi PC's lower UV absorptivity, higher water repellency, and lower likelihood for side chain photooxidation. © 1993 John Wiley & Sons, Inc. 相似文献
853.
854.
P. Schuurmans J. Wouters P. De Moor N. Severijns W. Vanderpoorten J. Vanhaverbeke L. Vanneste 《Hyperfine Interactions》1992,75(1-4):423-430
Anisotropic α-emission from nuclei in the decay chain from223Ra to207Tl has been observed using low temperature nuclear orientation in combination with high resolution α-detection at 4.2 K. Information
on partial wave amplitudes as well as hyperfine interactions has been extracted. 相似文献
855.
W. Królas A. Maj P. Bednarczyk B. Fornal W. Mceczynski J. Styczeń M. Zicebliński 《Zeitschrift für Physik A Hadrons and Nuclei》1992,344(2):145-147
High-energy gamma-rays emitted in the decay of the giant dipole resonance built on excited states of55Mn nucleus were measured with a bismuth germanate detector. Resonance parameters were extracted from the fits to the experimental spectra. Two new high-energy calibration points originating from slow-neutron capture in germanium isotopes of bismuth germanate crystal are proposed for large-volume BGO detectors. 相似文献
856.
H. Tsertos E. Berdermann F. Bosch M. Clemente S. Huchler P. Kienle W. Koenig C. Kozhuharov 《Zeitschrift für Physik A Hadrons and Nuclei》1992,342(1):79-94
We present the results obtained from systematic studies of positron creation for a series of heavy-collision systems, with united chargeZ u =Z 1 +Z 2 ranging fromZ u =164 (Pb + Pb) toZ u =184 (U+U) at bombarding energies close to the Coulomb barrier, using the Orangeβ-spectrometer at GSI. For each collision system studied, the dominating continuous distributions due to quasiatomic and nuclear positron emission are determined accurately. This is essential in obtaining the characteristics of the still unexplained monoenergetic positron lines which appear in the energy range between 200 keV and 400 keV. Our results are compared with coupled-channels calculations for quasi-atomic positron creation. The latter describe quite well the global features of the measured spectra, but overestimate systematically their absolute values. From the comparison, a common normalization factor of about 0.75 can be established for the calculated spectra. In particular, the dependence onZ u of the measured emission probabilities was found to follow a power law (∝Z u 195±1), in fair agreement with the theoretical prediction. 相似文献
857.
858.
L. P. Smol'skaya S. P. Panova S. G. Kuznetsova V. P. Il'kin L. S. Danyushkin 《Journal of Applied Spectroscopy》1992,56(2):170-173
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 56, No. 2, pp. 259–263, February, 1992. 相似文献
859.
The kinetics of the anion-induced (5 × 20) → (1 × 1) surface structural transition of reconstructed Au(100) electrodes was studied in sulfate-containing solutions by current transients. It is shown that lifting of the reconstruction follows a nucleation-and-growth type behavior which can be described by the Avrami equation. Moreover, for high positive potentials, i.e., high anion coverages, the current-transient analysis reveals instantaneous nucleation, whereas for low transition overpotentials and long transition times a mechanism with constant transition rate prevails. Apparent activation energies, which depend strongly on the electrode potential, are derived from the temperature dependence of the Avrami plots. 相似文献
860.
Within the framework of a simple electrostatic model, as compared to recent experimental results, we here discuss the stability
of very weakly bound molecular negative ions. In contrast with the case of conventional valence anions, the excess electron
is then located in a very diffuse orbital and is mainly bound by electrostatic dipolar, quadrupolar, and polarization forces,
at large distances from the neutral molecular core. By fitting a single repulsion parameter of the model to the available
experimental data, it is possible to make quantitative predictions of the excess-electron binding energies in these species.
Critical values of the dipole moment, quadrupole moment or polarizability required for the observation of stable multipole-bound
negative ions are predicted and compared to available experimental data and ab initio calculations.
Received October 24, 2001; accepted for publication November 16, 2001 相似文献