首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   152792篇
  免费   24933篇
  国内免费   18937篇
化学   107351篇
晶体学   1823篇
力学   9888篇
综合类   1253篇
数学   18926篇
物理学   57421篇
  2024年   309篇
  2023年   2683篇
  2022年   3739篇
  2021年   4936篇
  2020年   5736篇
  2019年   5620篇
  2018年   4871篇
  2017年   4755篇
  2016年   6807篇
  2015年   6880篇
  2014年   8446篇
  2013年   11079篇
  2012年   13561篇
  2011年   14050篇
  2010年   9877篇
  2009年   9662篇
  2008年   10509篇
  2007年   9274篇
  2006年   8640篇
  2005年   7289篇
  2004年   5813篇
  2003年   4731篇
  2002年   4640篇
  2001年   3839篇
  2000年   3350篇
  1999年   3343篇
  1998年   2733篇
  1997年   2512篇
  1996年   2545篇
  1995年   2112篇
  1994年   1946篇
  1993年   1585篇
  1992年   1435篇
  1991年   1236篇
  1990年   1081篇
  1989年   803篇
  1988年   690篇
  1987年   616篇
  1986年   532篇
  1985年   476篇
  1984年   352篇
  1983年   279篇
  1982年   206篇
  1981年   163篇
  1980年   143篇
  1979年   99篇
  1978年   82篇
  1977年   82篇
  1976年   73篇
  1975年   70篇
排序方式: 共有10000条查询结果,搜索用时 328 毫秒
81.
Gao  Peiyu  Min  Fuhong  Li  Chunbiao  Zhang  Lei 《Nonlinear dynamics》2021,106(3):2203-2228
Nonlinear Dynamics - In this paper, the current-controlled DC–DC buck converter from a new perspective are studied through the switching theory of flow, and the analytical conditions of the...  相似文献   
82.
miRNA (miR)-155 is a potential biomarker for breast cancers. We aimed at developing a nanosensor for miR-155 detection by integrating hybridization chain reaction (HCR) and silver nanoclusters (AgNCs). HCR serves as an enzyme-free and isothermal amplification method, whereas AgNCs provide a built-in fluorogenic detection probe that could simplify the downstream analysis. The two components were integrated by adding a nucleation sequence of AgNCs to the hairpin of HCR. The working principle was based on the influence of microenvironment towards the hosted AgNCs, whereby unfolding of hairpin upon HCR has manipulated the distance between the hosted AgNCs and cytosine-rich toehold region of hairpin. As such, the dominant emission of AgNCs changed from red to yellow in the absence and presence of miR-155, enabling a ratiometric measurement of miR with high sensitivity. The limit of detection (LOD) of our HCR-AgNCs nanosensor is 1.13 fM in buffered solution. We have also tested the assay in diluted serum samples, with comparable LOD of 1.58 fM obtained. This shows the great promise of our HCR-AgNCs nanosensor for clinical application.  相似文献   
83.
In order to investigate the characteristics of force chains in a granular flow system, a parallel plate shear cell is constructed to simulate the shear movement of an infinite parallel plate and observe variations in relevant parameters. The shear dilatancy process is divided into three stages, namely, plastic strain, macroscopic failure, and granular recombination. The stickslip phenomenon is highly connected with the evolution of force chains during the shear dilatancy process. The load–distribution rate curves and patterns of the force chains are utilized to describe the load-carrying behaviors and morphologic changes of force chains separately. Force chains, namely, “diagonal gridding,” “tadpole-shaped,” and “pinnate” are defined according to the form of the force chains in the corresponding three stages.  相似文献   
84.
In the view of substrate availability, atomic efficiency and cost, directly using arenols as coupling partners in cross‐coupling, would be one of the most attractive goals. Up to date, many efforts have been made to activate the C—O bond of phenols with different strategies, for example, through in‐situ formed intermediates, through a catalytic reductive dearomatization‐condensation‐rearomatization sequence or catalytic deoxygenation. In this review, we summarized recent advances in cross‐couplings of arenols as the electrophiles via C—O activation.  相似文献   
85.
Three‐dimensional (3D) nanometal films serving as current collectors have attracted much interest recently owing to their promising application in high‐performance supercapacitors. In the process of the electrochemical reaction, the 3D structure can provide a short diffusion path for fast ion transport, and the highly conductive nanometal may serve as a backbone for facile electron transfer. In this work, a novel polypyrrole (PPy) shell@3D‐Ni‐core composite is developed to enhance the electrochemical performance of conventional PPy. With the introduction of a Ni metal core, the as‐prepared material exhibits a high specific capacitance (726 F g?1 at a charge/discharge rate of 1 A g?1), good rate capability (a decay of 33 % in Csp with charge/discharge rates increasing from 1 to 20 A g?1), and high cycle stability (only a small decrease of 4.2 % in Csp after 1000 cycles at a scan rate of 100 mV s?1). Furthermore, an aqueous symmetric supercapacitor device is fabricated by using the as‐prepared composite as electrodes; the device demonstrates a high energy density (≈21.2 Wh kg?1) and superior long‐term cycle ability (only 4.4 % and 18.6 % loss in Csp after 2000 and 5000 cycles, respectively).  相似文献   
86.
87.
A facile synthetic strategy towards conformationally stable chiral chromophores based on dimeric porphyrinoids has been established. A peculiar class of face-to-face intramolecularly interlocked corrole dimers were formed by the oxidative C−C coupling linked at the inner carbon sites upon simple treatment of copper(II) ions. Their intrinsic electronic structures were modulated by the peripheral corrole ring annulations, which lead to distinct optical properties and redox profiles. The stereogenic carbon centers implemented in the confused corrole skeleton provided a rationale for designing novel chiral materials.  相似文献   
88.
Lithium-sulfur batteries (LSBs) with high energy density and low cost have been recognized as one of the most promising next-generation energy storage systems. Although it has taken decades of development, the practical application of LSBs has been hindered by several inherent obstacles, particularly the severe shuttle effect and sluggish reaction kinetics in the sulfur cathode. Various strategies have been proposed to address these problems via rational design of electrode materials and configurations. Freestanding sulfur cathode could be a promising strategy to improve the sulfur mass loading at the cathode level and energy density of LSBs. This minireview will briefly summary the recent advances in freestanding cathodes for LSBs. The advantages and disadvantages of various freestanding cathodes are discussed and the prospects for the development of flexible cathodes are envisioned.  相似文献   
89.
Yin  Pengpeng  Liu  Chang  Wang  Ying  Guan  Lei  Chen  Xian  Xiong  Xuejia  Jin  Hongzhe 《Russian Journal of General Chemistry》2021,91(5):897-903
Russian Journal of General Chemistry - A dinuclear Tb complex, Tb2(H2L)3(phen)2 (1), and two similar N-donor coordination complexes, Fe(phen)3·HL (2), Fe(bipy)3·HL·5H2O (3) (Na2H2L =...  相似文献   
90.
Wu  Xuze  Sun  Yu  Wang  Yu  Chen  Yu 《Nonlinear dynamics》2020,99(3):1937-1958
Nonlinear Dynamics - Oblique collisions are more likely to happen in the realistic translational joint with clearance, compared to the full front impacts. It can be a quite demanding task to...  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号