首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   49028篇
  免费   7340篇
  国内免费   5330篇
化学   34205篇
晶体学   515篇
力学   2959篇
综合类   363篇
数学   5853篇
物理学   17803篇
  2024年   151篇
  2023年   916篇
  2022年   1580篇
  2021年   1774篇
  2020年   1837篇
  2019年   1728篇
  2018年   1526篇
  2017年   1423篇
  2016年   2111篇
  2015年   2160篇
  2014年   2700篇
  2013年   3431篇
  2012年   4218篇
  2011年   4330篇
  2010年   2985篇
  2009年   2886篇
  2008年   3134篇
  2007年   2770篇
  2006年   2602篇
  2005年   2097篇
  2004年   1722篇
  2003年   1344篇
  2002年   1289篇
  2001年   1065篇
  2000年   990篇
  1999年   1074篇
  1998年   877篇
  1997年   798篇
  1996年   895篇
  1995年   767篇
  1994年   655篇
  1993年   567篇
  1992年   530篇
  1991年   441篇
  1990年   387篇
  1989年   300篇
  1988年   252篇
  1987年   234篇
  1986年   176篇
  1985年   180篇
  1984年   154篇
  1983年   136篇
  1982年   94篇
  1981年   68篇
  1980年   54篇
  1979年   37篇
  1978年   28篇
  1976年   28篇
  1975年   32篇
  1974年   27篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
31.
一种可实时化的多光谱图像融合系统   总被引:4,自引:0,他引:4  
在多光谱摄影和光电成像技术基础上,本文提出了一种可实时化的多光谱图像融合系统。与多光谱摄影相比,不仅可实现多光谱实时化摄像,而且光谱响应进一步向近红外延伸,并引入图像处理技术。实验表明:这种技术对于增加系统的识别能力具有明显的作用,可进一步构成不同用途的新型多光谱图像融合系统。  相似文献   
32.
处理原子-辐射场相互作用系统的变分方法   总被引:2,自引:2,他引:0  
用Heisenberg-Weyl(简H-W)群直积SU(2)群上的相干态表述了原子-辐射场相互作用系统的非平衡态统计力学.引入一个新定义的含时分布函数,将非平衡态下密度矩阵所满足的von Neumann方程转化成可分离变量的偏微分方程,给出了方程的形式解,算符的平均值表示.本文还就便于作微扰展开的相互作用绘景作了讨论.  相似文献   
33.
羰基镍分析报警仪运用化学发光原理构成,不仅适用于羰基镍生产车间现场的检测和报警,也适于实验室的研究工作。检出限达0.037mg/m^3(0.5ppb),响应时间2min。  相似文献   
34.
Several α-ketoalcohols of synthetic value were resolved using lipase as a catalyst. Lipoprotein lipase (LPL) provided the best rate of hydrolysis and kinetic differentiation. One of these optically pure α-ketoalcohol was converted to (5)-ibuprofen in good optical purity. The stereospecific inversion of (R)-alcohol to (S)-alcohol is described.  相似文献   
35.
A fluoroionophore sensor, N-[4-(1-pyrene)butyroyl]-L-tryptophan (PLT), has been reported. It can distinguish lead ion from other 12 metal ions via forming a pyrene dimer and it exhibits a very high sensitivity (0.15 microM) in aqueous solution (Chem. Commun., 2006, 2702). When the indole moiety in PLT was changed to benzene, in forming a new fluoroionophore of N-[4-(1-pyrene)butyroyl]-L-phenylalanine (PLP), it could not form a pyrene dimer in response to Pb(2+) in water. The present study describes the spectroscopic clarification of the intrinsic differences of the binding model between PLP and PLT in binding with Pb(2+). The model shows identical chelating bidentate coordination between COO(-) and Pb(2+) both in PLP-Pb and PLT-Pb; however, there is no indication of the interaction between the phenyl ring and the metal ion or the hydrogen bonding between amide groups in PLP-Pb. These differences in the binding model between PLP-Pb and PLT-Pb illustrate that the indole ring in PLT appears to play a crucial role in the high selectivity and sensitivity of PLT to lead(II) ion.  相似文献   
36.
关于多线性振荡奇异积分在加权Hardy-型空间上的一致估计   总被引:1,自引:0,他引:1  
吴丛明  杨大春 《数学进展》2002,31(6):527-536
本文对一类具有光滑位相函数的多线性振荡奇异积分算子建立了一致的加权(H^1(R^n),L^1(R^n))估计及一致的加权(HKp(R^n),Kp(R^n)估计。  相似文献   
37.
CoPt/Ag and [C/CoPt]n/Ag thin films have been prepared onto the glass substrates by magnetron sputtering. We investigated the evolution of texture and magnetic properties of CoPt/Ag and [C/CoPt]n/Ag films. The results show that C-doping plays an important role in improving (0 0 1) texture, improving the order parameter S, reducing the intergrain interactions, and making the magnetization reversal mechanism more close to Stoner-Wolfarth rotational mechanism. The growth mechanism of (0 0 1) texture also seems to be related strongly to the films thickness. Our results show that the highly (0 0 1)-oriented films with ordered fct phase have a significant potential for the perpendicular media of extremely high-density recording.  相似文献   
38.
Investigation of remelting and cladding processing with laminar plasma jets on several metals has been conducted looking for possible development of a new surface modification technique. The remelting tests illustrated that the new method could evidently improve the material microstructure and properties of cast iron. The cladding was done with Al2O3 ceramic powder on stainless steel. The energy dispersive spectra (EDS) analysis was used to determine the distribution of the major cladding element in the plasma-processed layers, for which the microstructure observations and hardness measurements were also performed.  相似文献   
39.
The influence of the electron-LO-phonon coupling on energy spectrum of the low-lying states ofan exciton inparabolic quantum dots is investigated as a function of dot size. Calculations are made by using the method of few-bodyphysics within the effective-mass approximation. A considerable decrease of the energy in the stronger confinement rangeis found for the low-lying states of an exciton in quantum dots, which results from the confinement of electron-phononcoupling.  相似文献   
40.
Poly(3‐hydroxybutyrate) (PHB)/layered double hydroxides (LDHs) nanocomposites were prepared by mixing PHB and poly(ethylene glycol) phosphonates (PEOPAs)‐modified LDH (PMLDH) in chloroform solution. Both X‐ray diffraction data and TEM micrographs of PHB/PMLDH nanocomposites indicate that the PMLDHs are randomly dispersed and exfoliated into the PHB matrix. In this study, the effect of PMLDH on the isothermal crystallization behavior of PHB was investigated using a differential scanning calorimeter (DSC) and polarized optical microscopy. Isothermal crystallization results of PHB/PMLDH nanocomposites show that the addition of 2 wt % PMLDH into PHB induced more heterogeneous nucleation in the crystallization significantly increasing the crystallization rate and reducing their activation energy. By adding more PMLDH into the PHB probably causes more steric hindrance of the diffusion of PHB, reducing the transportation ability of polymer chains during crystallization, thus increasing the activation energy. The correlation among crystallization kinetics, melting behavior and crystalline structure of PHB/PMLDH nanocomposites can also be discussed. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3337–3347, 2006  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号