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61.
Summary Reactions of Group VIII metal halides [CoCl2, NiCl2, K2PdCl4, PdCl2(PhCN)2 and PtCl2] with tetrasulphurtetranitrogendioxide, S4N4O2, have been investigated. The cobalt reaction yields Co(S2N2H)2, Co(S2N2H)(S3N) and Co(S3N)2. The usefulness of metal centres for trapping reactive sulphur-nitrogen centres is discussed. 相似文献
62.
Highly Strained Heterocycles Constructed from Boron–Boron Multiple Bonds and Heavy Chalcogens 下载免费PDF全文
Prof. Dr. Holger Braunschweig Philipp Constantinidis Theresa Dellermann Dr. William C. Ewing Prof. Dr. Ingo Fischer Merlin Hess Dr. Fergus R. Knight Anna Rempel Christoph Schneider Stefan Ullrich Dr. Alfredo Vargas Prof. J. Derek Woollins 《Angewandte Chemie (International ed. in English)》2016,55(18):5606-5609
The reactions of a diborene with elemental selenium or tellurium are shown to afford a diboraselenirane or diboratellurirane, respectively. These reactions are reminiscent of the sequestration of subvalent oxygen and nitrogen in the formation of oxiranes and aziridines; however, such reactivity is not known between alkenes and the heavy chalcogens. Although carbon is too electronegative to affect the reduction of elements with lower relative electronegativity, the highly reducing nature of the B?B double bond enables reactions with Se0 and Te0. The capacity of multiple bonds between boron atoms to donate electron density is highlighted in reactions where diborynes behave as nucleophiles, attacking one of the two Te atoms of diaryltellurides, forming salts consisting of diboratellurenium cations and aryltelluride anions. 相似文献
63.
Reaction of (PhPSe2)2(Woollins reagent) with NaOR (R = Me, Et, (i)Pr) gives the non-symmetric phosphonodiselenoato anions [Ph(RO)PSe2]- which can be complexed to a range of metals. The nickel complex Ni[Ph(MeO)PSe2]2 adopts a square-planar ML2 structure while the cadmium complex Cd[Ph(MeO)PSe2]2 displays a dimeric M2L4 structure. Two different lead complexes are observed, one consisting of PbL2 units joined by Pb...Se interactions to form distinct dimeric pairs. The other displays a novel dimeric structure built around a central four-membered Pb2Se2 ring. All new compounds have been characterised spectroscopically (31P, 1H, 13C NMR, IR, mass spectroscopy), by elemental analysis and five demonstrative X-ray structures are reported. 相似文献
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Mark R.S.J. Foreman Alexandra M.Z. Slawin J. Derek Woollins 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1):469-472
Diferrocenyl dithiadiphosphetane disulfide (Fc2P2S4) had been found act as a source of a reactive species, believed to be FcPS2, which reacts with dialkyl cyanamides, imines, aldehydes and strained alkenes to form a variety of phosphorus compounds. These reactions include a convenient route to thiaphosphetanes. 相似文献
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Dipak Kumar Dutta J. Derek Woollins Alexandra M.Z. Slawin Amy L. Fuller Biswajit Deb Podma Pollov Sarmah Madan Gopal Pathak Dilip Konwar 《Journal of molecular catalysis. A, Chemical》2009,313(1-2):100-106
The reaction of dimeric rhodium precursor [Rh(CO)2Cl]2 with two molar equivalent of 1,1,1-tris(diphenylphosphinomethyl)ethane trichalcogenide ligands, [CH3C(CH2P(X)Ph2)3](L), where X = O(a), S(b) and Se(c) affords the complexes of the type [Rh(CO)2Cl(L)] (1a–1c). The complexes 1a–1c have been characterized by elemental analyses, mass spectrometry, IR and NMR (1H, 31P and 13C) spectroscopy and the ligands a–c are structurally determined by single crystal X-ray diffraction. 1a–1c undergo oxidative addition (OA) reactions with different electrophiles such as CH3I, C2H5I and C6H5CH2Cl to give Rh(III) complexes of the types [Rh(CO)(COR)ClXL] {R = –CH3 (2a–2c), –C2H5 (3a–3c); X = I and R = –CH2C6H5 (4a–4c); X = Cl}. Kinetic data for the reaction of a–c with CH3I indicate a first-order reaction. The catalytic activity of 1a–1c for the carbonylation of methanol to acetic acid and its ester is evaluated and a higher turn over number (TON = 1564–1723) is obtained compared to that of the well-known commercial species [Rh(CO)2I2]− (TON = 1000) under the reaction conditions: temperature 130 ± 2 °C, pressure 30 ± 2 bar and time 1 h. 相似文献
69.
Reaction of 8-methoxy-1-naphthyllithium (2) with one equivalent of chlorodiphenylphosphine gives the novel (8-methoxynaphth-1-yl)diphenylphosphine (3) which was oxidised to the corresponding sulfide (4) and selenide (5) by reaction with sulfur and selenium, respectively. The P?O peri distance is significantly increased in 4 and 5 at 2.819(3) [2.793(3)] and 2.827(3) [2.806(3)] ? [values in square brackets are for the second independent molecules in each case] relative to the value in 3 of 2.678(2) Å. There are short E?O interactions ie O(1)?S(1) 3.165(3) [3.124(3)], O(1)?Se(1) 3.247(3) [3.200(2)] ? and these may be repulsive and responsible for the increased P?O separation. The use of the naphthalene backbone in the synthesis of a potential hemilabile ligand is demonstrated by the synthesis and X-ray structure of (8-methoxynaphth-1-yl)diethoxyphosphine ruthenium p-cymene dichloride (6). 相似文献
70.
Fiona A. M. Rudolph Amy L. Fuller Alexandra M. Z. Slawin Michael Bühl R. Alan Aitken J. Derek Woollins 《Journal of chemical crystallography》2010,40(3):253-265