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961.
The orientation of E7 liquid crystal (LC) confined within 200 nm diameter cylindrical cavities of Anodisc membranes are investigated by FTIR dichroism techniques. The cavity walls of the confining pores were chemically modified with different length perfluorinated carboxylic acids (PCAs, C n F2n+1COOH, n = 3, 4, 5, 6) at 1, 3 and 5 mM concentrations. From the FTIR spectra of PCA-treated alumina Anodsic membranes, we found salt formation between the -COOH group of the PCAs and the Anodisc membranes. From the FTIR spectra of LC-filled Anodisc membranes, we found an abrupt alignment direction change, from parallel to perpendicular, of the LC molecules along the long axis of the cavities between n = 4 and n = 5 for the 1 mM concentration of PCA. However, for the 5 mM concentration of PCA, the parallel-to-perpendicular alignment direction of LC molecules changed between n = 3 and n = 4. These LC orientation changes for PCA-treated Anodisc membranes occurred at shorter length than for hydrocarbon carboxylic acid (HCA, C n H2n+1COOH)-treated Anodisc membranes. This change may be caused by the lower surface energy of the -(CF2) n CF3 chain of PCA than that of the -(CH2) n CH3 chain of HCA. 相似文献
962.
The aim of this paper is to derive, in the Hilbert space setting, an integral representation formula for the effective elasticity tensor for a two‐component composite of elastic materials, not necessarily well‐ordered. This integral representation formula implies a relation which links the effective elastic moduli to the N‐point correlation functions of the microstructure. Such relation not only facilitates a powerful scheme for systematic incorporation of microstructural information into bounds on the effective elastic moduli but also provides a theoretical foundation for inverse‐homogenization. The analysis presented in this paper can be generalized to an n‐component composite of elastic materials. The relations developed here can be applied to the inverse‐homogenization for a special class of linear viscoelastic composites. The results will be presented in another paper. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
963.
Jae-Ou Chae Vladimir Demidiouk Jae-Won Hwang Tae Gyun Jung V. Ravi 《Reaction Kinetics and Catalysis Letters》2005,85(1):167-173
Summary A number of supported metal oxide catalysts were prepared and tested for nitrogen oxide removal from diesel engine exhaust. More than 50% of nitrogen oxides were removed using many prepared catalysts in the temperature range of 150oC-350oC. 相似文献
964.
Generic initial ideals of Artinian ideals having Lefschetz properties or the strong Stanley property
For a standard Artinian k-algebra A=R/I, we give equivalent conditions for A to have the weak (or strong) Lefschetz property or the strong Stanley property in terms of the minimal system of generators of gin(I). Using the equivalent condition for the weak Lefschetz property, we show that some graded Betti numbers of gin(I) are determined just by the Hilbert function of I if A has the weak Lefschetz property. Furthermore, for the case that A is a standard Artinian k-algebra of codimension 3, we show that every graded Betti number of gin(I) is determined by the graded Betti numbers of I if A has the weak Lefschetz property. And if A has the strong Lefschetz (respectively Stanley) property, then we show that the minimal system of generators of gin(I) is determined by the graded Betti numbers (respectively by the Hilbert function) of I. 相似文献
965.
Metal-mediated allylations of difluoroacetyltriakylsilanes with various allyl bromides in aqueous media form homoallylic alcohols exclusively. The common Brook rearrangement, carbon to oxygen-silyl migration, is totally suppressed with no detectable formation of silyl enol ether. Influence of solvents on reaction is studied. Reactivity differences between indium and zinc are also described. 相似文献
966.
Jin-Seung Jung Kyong-Hoon Choi Yong-Rok Kim Leszek Malkinski Weilie Zhou Charles J O'Connor 《Journal of Physics and Chemistry of Solids》2003,64(3):385-390
Superparamagnetic nickel nanoparticles were prepared by incorporating nickel ion into AlMCM41 as a nanoreactor and then reduced with sodium borohydride or H2 gas. Products were characterized by elemental analysis, transmission electron microscopy, X-ray powder diffraction, and magnetic susceptibility. The nickel particle size and blocking temperature depend on the reduction method. 相似文献
967.
Sang Kyu Lee Byung‐Jun Jung Taek Ahn Young Kwan Jung Jeong‐Ik Lee In‐Nam Kang Jonghee Lee Jong‐Hwa Park Hong Ku Shim 《Journal of polymer science. Part A, Polymer chemistry》2007,45(15):3380-3390
A series of fluorene‐based copolymers composed of blue‐ and orange‐light‐emitting comonomers were synthesized through palladium‐catalyzed Suzuki coupling reactions. 9,9‐Dihexylfluorene and 2‐(2,6‐bis‐{2‐[1‐(9,9‐dihexyl‐9H‐fluoren‐2‐yl)‐1,2,3,4‐tetrahydroquinolin‐6‐yl]‐vinyl}‐pyran‐4‐ylidene)‐malononitrile (DCMF) were used as the blue‐ and orange‐light‐emitting chromophores, respectively. The resulting single polymers exhibited simultaneous blue (423/450 nm) and orange (580–600 nm) emissions from these two chromophores. By adjusting the fluorene and DCMF contents, white light emission could be obtained from a single polymer; a device with an ITO/PEDOT:PSS/polymer/Ca/Al configuration was found to exhibit pure white electroluminescence with Commission Internationale de L'Eclairage (CIE) coordinates of (0.33, 0.31), a maximum brightness of 1180 cd/m2, and a current efficiency of 0.60 cd/A. Furthermore, the white light emission of this device was found to be very stable with respect to variation of the driving voltage. The CIE coordinates of the device were (0.32, 0.29), (0.32, 0.29), and (0.33, 0.31) for driving voltages of 7, 8, and 10 V, respectively. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3380–3390, 2007 相似文献
968.
A gas chromatographic–mass spectrometric method has been developed for rapid and sensitive determination of odorous compounds in water. The water sample (200 mL), at pH 6.5, was extracted with 1 mL pentane in a 250-mL separatory funnel. Fluorobenzene was added to the water sample as internal standard and the solution was mechanically shaken for 5 min and analyzed by GC–MS, with selected ion monitoring, without further concentration or purification steps. The peaks had good chromatographic properties and extraction of the compounds from water resulted in relatively high recoveries with small variations. The detection limits of the assay were 0.1 ng L–1 for 2-isopropyl-3-methoxypyrazine, 2-isobutyl-3-methoxypyrazine, 2-methylisoborneol, and geosmin, 0.5 ng L–1 for anisole, and 1.0 ng L–1 for 2,4,6-trichloroanisole and trans, trans-2,4-heptadienal. Turn-around time was one day for up to approximately 40 samples. The method is simple, convenient, and can be learned easily by relatively inexperienced personnel. It was used to analyze seven odorous compounds in water from Decheung-Lake in Korea, and raw and treated water originating from the same lake. In the summer of 2001 significant levels of anisole (up to 225 ng L–1) were observed, and geosmin and 2-methylisoborneol were detected at concentrations of up to 23.8 and 26.7 ng L–1, respectively. 2-Isopropyl-3-methoxypyrazine, 2-isobutyl-3-methoxypyrazine, and trans, trans-2,4-heptadienal levels during that period were not significant. The method can used for simultaneous detection of several odorous compounds in water. 相似文献
969.
In TeV-scale gravity, scattering of particles with center-of-mass energy of the order of a few TeV can lead to the creation of nonperturbative, extended, higher-dimensional gravitational objects: Branes. Neutral or charged, spinning or spinless, Einsteinian or supersymmetric, low-energy branes could dramatically change our picture of high-energy physics. Will we create branes in future particle colliders, observe them from ultra high energy cosmic rays, and discover them to be dark matter? 相似文献
970.