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31.
Three different crystal forms were obtained from the crystallisation of a flexible imidazole based ligand and CdBr(2) under different conditions. Structural analysis reveals that the correlation between the three metallocyclic compounds can be described in terms of isostructurality, solvatomorphism and supramolecular isomerism. 相似文献
32.
比较了Snyder经验公式中的K0w 与S和溶质计量置换保留模型 (SDM R)中溶质保留参数Z(1mol溶剂化溶质被溶剂化固定相吸附时 ,在其接触表面处释放出溶剂或置换剂的总摩尔数 )与lgI(与 1mol溶质对固定相的亲和势有关的常数 )之间的定量关系。SDM R中的两个参数间不仅对同系物溶质可以有很好的线性关系 ,而且对非同系物溶质也有很好的线性关系。其线性关系的好坏主要取决于这两个参数数值范围的大小 ,与文献中报告的线性关系取决于是否单因素影响溶质的保留和完全由统计学规律决定的结论不同。 相似文献
33.
Cevher Gündoğdu Hızlıateş Sibel Gülle Yavuz Ergün 《Journal of heterocyclic chemistry》2016,53(1):249-254
The novel heterocyclic compounds that have cycloalk[b]indole moiety bearing spiropiperidinone and spiropiperidinedione ( 3a , 3b , 3c , 5a , 5b , 8a , 8b , and 10a ) were synthesized for the first time. The synthesis of spiropiperidinone and spiropiperidinedione structures was performed by a new method. These compounds are similar to sedative and hypnotic drugs such as methyprylon, glutethimide, and thalidomide. 相似文献
34.
Remote sample characterization based on fluorescence monitoring 总被引:3,自引:0,他引:3
The possibilities and limitations of remote sample characterization using induced fluorescence are discussed. General equations for remote sensing of fluorescence are presented and discussed. The implications of different elements of a system for remote fluorescence sensing on different parameters of the equations are treated. Background light influence and signal processing are considered. Pulsed lasers, flashlamps and cw lamps as excitation sources are compared when matched to the proper detection scheme employing boxcar integration or lock-in detection. Model experiments have been performed to demonstrate different measurement strategies. Examples from remote oil-slick characterization are chosen as illustrations. 相似文献
35.
36.
du Rietz R Hinde DJ Dasgupta M Thomas RG Gasques LR Evers M Lobanov N Wakhle A 《Physical review letters》2011,106(5):052701
The inhibition of fusion by quasifission is crucial in limiting the formation of superheavy elements in collisions of heavy nuclei. Time scales of ~10(-18) s inferred for fissionlike events from recent crystal blocking measurements were interpreted to show either that quasifission itself is slower than previously believed, or that the fraction of slow fusion-fission is higher than expected. New measurements of mass-angle distributions for (48)Ti and (64)Ni bombarding W targets show that in these reactions quasifission is the dominant process, typically occurring before the system formed after contact has made a single rotation, corresponding to time scales of ≤10(-20) s. 相似文献
37.
Mustafa Özdemir Melek Erdoğdu Hakan Şimşek 《Advances in Applied Clifford Algebras》2014,24(1):179-192
In this paper, we examine eigenvalue problem of a rotation matrix in Minkowski 3 space by using split quaternions. We express the eigenvalues and the eigenvectors of a rotation matrix in term of the coefficients of the corresponding unit timelike split quaternion. We give the characterizations of eigenvalues (complex or real) of a rotation matrix in Minkowski 3 space according to only first component of the corresponding quaternion. Moreover, we find that the casual characters of rotation axis depend only on first component of the corresponding quaternion. Finally, we give the way to generate an orthogonal basis for ${\mathbb{E}^{3}_{1}}$ by using eigenvectors of a rotation matrix. 相似文献
38.
39.
Vuyisa Sigwela Maryna De Wit Alba du Toit Gernot Osthoff Arno Hugo 《Molecules (Basel, Switzerland)》2021,26(16)
Natural food items and the additional benefits they provide have received considerable attention in recent years. Betalains are nutritious pigments which have valuable biological properties, e.g., antioxidant and free radical scavenging activity. In this study, aqueous betalain extracts were obtained from different coloured cactus pears (purple, red/pink, and orange), amaranth, and beetroot, with and without the addition of ascorbic acid, microwave-heated, and freeze-dried and subsequently analysed by thin layer chromatography (TLC). Beetroot samples without the addition of ascorbic acid (AA) had lower phenols, flavonoids, and ascorbic acid content than beetroot samples extracted with the addition of AA. Amaranth had significantly higher contents of antioxidants than all the other plants. Results for phenolic compounds showed that there were no significant differences between cactus pear cultivars, however, significant differences were seen between the two beetroot samples (microwave-heated with and without AA) as well as amaranth. For flavonoid compounds, amaranth had significantly higher values than all other samples. The lowest flavonoid content was found in beetroot without AA (0.49 mgCE/g). For ascorbic acid, significant differences were noticed between amaranth (71.71 mg/100 g) and samples from cactus pear and beetroot. TLC results showed that purple and red cactus pear samples had the most vivid colours, a reflection of the high betacyanin and betaxanthin contents in the cultivars. Moreover, extracts from cactus pear, beetroot, and amaranth were classified according to a decision tree which was designed by the Code of Federal Regulations/Food Additives Regulation of the EU. The classification of betalain pigment extracts as colouring foods was achieved through enrichment factor calculations and the colourant decision tree. The results showed that the betalain pigment extraction method used is inexpensive, time-saving, energy-saving, non-toxic, and chemical solvent free and yields high concentrations of betalains. 相似文献
40.
A study of the electrochemical reduction of the mesotrione pesticide on a hanging mercury drop electrode (HMDE) was performed
as a basis for the development of a sensitive analytical method for natural samples. The electrochemical characteristics of
herbicide mesotrione dissolved in a phosphate buffer (pH 7.0) have been determined by means of electrochemical techniques
such as cyclic voltammetry (CV) and differential pulse voltammetry (DPV) over a wide range of pH from 2.0 to 10.0. The experimental
parameters, such as electrolyte type and its pH, pulse amplitude, and scan rate were optimized. The method was applied to
the determination of the pesticide in a spiked soil samples. Using this method, a linear calibration curve for mesotrione
was obtained up to the 0.1 μM range in pH 7 phosphate buffer solution with a detection limit (S/N = 3) of 50 nM. The method
can be applied successfully to the determination of mesotrione in soils.
The text was submitted by the authors in English. 相似文献