全文获取类型
收费全文 | 511篇 |
免费 | 11篇 |
国内免费 | 6篇 |
专业分类
化学 | 254篇 |
晶体学 | 5篇 |
力学 | 9篇 |
数学 | 153篇 |
物理学 | 107篇 |
出版年
2022年 | 4篇 |
2021年 | 20篇 |
2020年 | 4篇 |
2019年 | 9篇 |
2018年 | 8篇 |
2017年 | 4篇 |
2016年 | 20篇 |
2015年 | 16篇 |
2014年 | 11篇 |
2013年 | 29篇 |
2012年 | 28篇 |
2011年 | 24篇 |
2010年 | 26篇 |
2009年 | 16篇 |
2008年 | 14篇 |
2007年 | 19篇 |
2006年 | 9篇 |
2005年 | 17篇 |
2004年 | 21篇 |
2003年 | 16篇 |
2002年 | 12篇 |
2001年 | 5篇 |
1999年 | 5篇 |
1998年 | 3篇 |
1997年 | 8篇 |
1996年 | 8篇 |
1995年 | 9篇 |
1994年 | 5篇 |
1993年 | 9篇 |
1992年 | 4篇 |
1991年 | 7篇 |
1989年 | 5篇 |
1987年 | 4篇 |
1986年 | 5篇 |
1985年 | 12篇 |
1984年 | 11篇 |
1983年 | 5篇 |
1982年 | 6篇 |
1981年 | 11篇 |
1979年 | 4篇 |
1978年 | 4篇 |
1975年 | 3篇 |
1936年 | 8篇 |
1935年 | 9篇 |
1934年 | 4篇 |
1930年 | 6篇 |
1929年 | 5篇 |
1928年 | 5篇 |
1926年 | 2篇 |
1924年 | 4篇 |
排序方式: 共有528条查询结果,搜索用时 15 毫秒
31.
The synthesis and spectroscopic properties of the (5′ → 5″)-ester of adenosine 5′-diphosphate with ribofuranose cyclic 1″, 2″-phosphate 3 , a recently discovered metabolite produced during tRNA splicing, are reported. 相似文献
32.
Electrochemical studies of famotidine were carried out using voltammetric techniques: cyclic voltammetry, linear sweep and square wave adsorptive stripping voltammetry. The dependence of the current on pH, buffer concentration, nature of the buffer, and scan rate was investigated. The best results for the determination of famotidine were obtained in MOPS buffer solution at pH 6.7. This electroanalytical procedure enabled to determine famotidine in the concentration range 1 × 10−9–4 × 10−8 mol L−1 by linear sweep adsorptive stripping voltammetry (LS AdSV) and 5 × 10−10–6 × 10−8 mol L−1 by square wave adsorptive stripping voltammetry (SW AdSV). Repeatability, precision and accuracy of the developed methods were checked. The detection and quantification limits were found to be 1.8 × 10−10 and 6.2 × 10−10 mol L−1 for LS AdSV and 4.9 × 10−11 and 1.6 × 10−10 mol L−1 for SW AdSV, respectively. The method was applied for the determination of famotidine in urine. 相似文献
33.
Barbara Franczuk Witold Danikiewicz 《Journal of the American Society for Mass Spectrometry》2018,29(3):588-599
Ion-molecule reactions of Me2S2 with a wide range of aliphatic carbanions differing by structure and proton affinity values have been studied in the gas phase using mass spectrometry techniques and DFT calculations. The analysis of the spectra shows a variety of product ions formed via different reaction mechanisms, depending on the structure and proton affinity of the carbanion. Product ions of thiophilic reaction (m/z 47), SN2 (m/z 79), and E2 elimination – addition sequence of reactions (m/z 93) can be observed. Primary products of thiophilic reaction can undergo subsequent SN2 and proton transfer reactions. Gibbs free energy profiles calculated for experimentally observed reactions using PBE0/6-311+G(2d,p) method show good agreement with experimental results. 相似文献
34.
Witold Mizerski Marek K. Kalinowski 《Monatshefte für Chemie / Chemical Monthly》1992,123(8-9):665-674
Summary Electrostatic potentials in the vicinity of isolated molecules of typical nonaqueous solvents were computed in the MNDO approximation. It was found that the calculated dipole moments are in good agreement with experimental values. However, it turned out that in many cases electrostatic interactions of ions with solvent molecules cannot be described in the frame of ion-dipole interactions. Thus, two computable parameters,UN andUP describing short-range electrostatic interactions of a solvent molecule with a cation or an anion of radiusR were proposed. The dependence ofUN andUP uponR is analyzed in the context of ion-solvent interactions.
Elektrostatische Potentiale von Molekülen und Voraussage von Lewis-Säure-Base-Eigenschaften von Lösungsmitteln, 1. Mitt.: Allgemeine Grundlagen
Zusammenfassung Es wurden die elektrostatischen Potentiale in der Umgebung von isolierten Molekülen typischer nichtwäßriger Lösungsmittel in der MNDO-Näherung berechnet. Die berechneten Dipolmomente waren in guter Übereinstimmung mit den experimentellen Werten. Es wurde jedoch beobachtet, daß in vielen Fällen die elektrostatischen Wechselwirkungen von Ionen mit Lösungsmittelmolekülen nicht im Rahmen von Ionen-Dipol-Wechselwirkungen beschrieben werden können. Dafür wurden zwei berechenbare ParameterUN undUP zur Beschreibung von elektrostatischen Wechselwirkungen im Nahbereich eines Lösungsmittelmoleküls mit einem Kationen- oder AnionenradiusR vorgeschlagen. Die Abhängigkeit vonUN undUP vonR wurde im Zusammenhang von Ionen-Solvens-Wechselwirkungen untersucht.相似文献
35.
36.
It is shown that in every dimension n = 3j + 2, j = 1, 2, 3, . . ., there exist compact pseudo-Riemannian manifolds with parallel Weyl tensor, which are Ricci-recurrent, but
neither conformally flat nor locally symmetric, and represent all indefinite metric signatures. The manifolds in question
are diffeomorphic to nontrivial torus bundles over the circle. They all arise from a construction that a priori yields bundles
over the circle, having as the fibre either a torus, or a 2-step nilmanifold with a complete flat torsionfree connection;
our argument only realizes the torus case. 相似文献
37.
Stevo Stevi Bratislav Iri
anin Witold Kosmala Zdenk marda 《Mathematical Methods in the Applied Sciences》2019,42(5):1687-1701
Some formulas for well‐defined solutions to four very special cases of a nonlinear fifth‐order difference equation have been presented recently in this journal, where some of them were proved by the method of induction, some are only quoted, and no any theory behind the formulas was given. Here, we show in an elegant constructive way how the general solution to the difference equation can be obtained, from which the special cases very easily follow, which is also demonstrated here. We also give some comments on the local stability results on the special cases of the nonlinear fifth‐order difference equation previously publish in this journal. 相似文献
38.
Dušan Repovš Witold Rosicki Žiga Virk Andreas Zastrow 《Topology and its Applications》2012,159(10-11):2609-2620
This paper shows that a construction, which was introduced by Piotr Minc in connection with a problem that came from Helly type theorems and that allows to replace three PL-arcs with a “sheltered middle path”, can in the case of general (non-PL) paths result in the topologist?s sine curve. 相似文献
39.
Xin Wang Xiaodong Liu Witold PedryczXiaolei Zhu Guangfei Hu 《European Journal of Operational Research》2012,218(1):202-210
In this paper, we propose a novel method to mine association rules for classification problems namely AFSRC (AFS association rules for classification) realized in the framework of the axiomatic fuzzy set (AFS) theory. This model provides a simple and efficient rule generation mechanism. It can also retain meaningful rules for imbalanced classes by fuzzifying the concept of the class support of a rule. In addition, AFSRC can handle different data types occurring simultaneously. Furthermore, the new model can produce membership functions automatically by processing available data. An extensive suite of experiments are reported which offer a comprehensive comparison of the performance of the method with the performance of some other methods available in the literature. The experimental result shows that AFSRC outperforms most of other methods when being quantified in terms of accuracy and interpretability. AFSRC forms a classifier with high accuracy and more interpretable rule base of smaller size while retaining a sound balance between these two characteristics. 相似文献
40.
Piotr Bogusaw Mucha Witold Sadowski 《Mathematical Methods in the Applied Sciences》2005,28(15):1867-1880
The paper analyses long time behaviour of solutions of the Navier–Stokes equations in a two‐dimensional pipe‐like domain. The system is studied with perfect slip boundary conditions with arbitrary inflow conditions at infinity. The main results show the existence of global in time solutions and of an attractor for the dynamical system generated by the model. The paper also establishes an upper bound for the Hausdorff dimension of the attractor. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献