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81.
Winfried Kaballo 《Archiv der Mathematik》1980,34(1):540-549
Ohne Zusammenfassung 相似文献
82.
Winfried Scharlau 《Inventiones Mathematicae》1967,4(4):238-264
Ohne ZusammenfassungDiese Arbeit ist im wesentlichen die gleichnamige Dissertation des Verfassers, Bonn 1967. 相似文献
83.
84.
Winfried Leidemann Victor D. Efros Giuseppina Orlandini Edward L. Tomusiak 《Few-Body Systems》2010,47(3):157-165
The threshold transverse response functions R T (q, ω) for 3He and 3H are calculated using the AV18 nucleon–nucleon potential, the UrbanaIX three-body force, and the Coulomb potential. Final states are completely taken into account via the Lorentz integral transform technique. Consistent two-body π- and ρ-meson exchange currents as deduced using the Arenhövel-Schwamb technique are included. The convergence of the method is shown and a comparison of the corresponding MEC contribution is made to that of a consistent MEC for the meson theoretical r-space BonnA potential. The response R T is calculated in the threshold region at q = 174, 324, and 487 MeV/c and compared with available data. The strong MEC contributions in the threshold region are nicely confirmed by the data at q = 324 and 487 MeV/c although some differences between theoretical and experimental results remain. A comparison is also made with other calculations, where the same theoretical input is used. The agreement is generally rather good, but leaves also some space for further improvement. 相似文献
85.
86.
87.
(51)V solid-state NMR investigations and DFT studies of model compounds for vanadium haloperoxidases
Schweitzer A Gutmann T Wächtler M Breitzke H Buchholz A Plass W Buntkowsky G 《Solid state nuclear magnetic resonance》2008,34(1-2):52-67
Three cis-dioxovanadium(V) complexes with similar N-salicylidenehydrazide ligands modeling hydrogen bonding interactions of vanadate relevant for vanadium haloperoxidases are studied by (51)V solid-state NMR spectroscopy. Their parameters describing the quadrupolar and chemical shift anisotropy interactions (quadrupolar coupling constant C(Q), asymmetry of the quadrupolar tensor eta(Q), isotropic chemical shift delta(iso), chemical shift anisotropy delta(sigma), asymmetry of the chemical shift tensor eta(sigma) and the Euler angles alpha, beta and gamma) are determined both experimentally and theoretically using DFT methods. A comparative study of different methods to determine the NMR parameters by numerical simulation of the spectra is presented. Detailed theoretical investigations on the DFT level using various basis sets and structural models show that by useful choice of the methodology, the calculated parameters agree to the experimental ones in a very good manner. 相似文献
88.
Winfried Nischkauer Marie-Alexandra Neouze Frank Vanhaecke Andreas Limbeck 《Mikrochimica acta》2015,182(15-16):2369-2376
89.
The subject is traces of Sobolev spaces with mixed Lebesgue norms on Euclidean space. Specifically, restrictions to the hyperplanes given by x1 = 0 and xn = 0 are applied to functions belonging to quasi‐homogeneous, mixed norm Lizorkin–Triebel spaces ; Sobolev spaces are obtained from these as special cases. Spaces admitting traces in the distribution sense are characterised up to the borderline cases; these are also covered in case x1 = 0. For x1 the trace spaces are proved to be mixed‐norm Lizorkin–Triebel spaces with a specific sum exponent; for xn they are similarly defined Besov spaces. The treatment includes continuous right‐inverses and higher order traces. The results rely on a sequence version of Nikol'skij's inequality, Marschall's inequality for pseudodifferential operators (and Fourier multiplier assertions), as well as dyadic ball criteria. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
90.
Eva Zahorska Francesca Rosato Kai Stober Sakonwan Kuhaudomlarp Joscha Meiers Dirk Hauck Dorina Reith Emilie Gillon Katharina Rox Anne Imberty Winfried Römer Alexander Titz 《Angewandte Chemie (International ed. in English)》2023,62(7):e202215535
Bacterial adhesion, biofilm formation and host cell invasion of the ESKAPE pathogen Pseudomonas aeruginosa require the tetravalent lectins LecA and LecB, which are therefore drug targets to fight these infections. Recently, we have reported highly potent divalent galactosides as specific LecA inhibitors. However, they suffered from very low solubility and an intrinsic chemical instability due to two acylhydrazone motifs, which precluded further biological evaluation. Here, we isosterically substituted the acylhydrazones and systematically varied linker identity and length between the two galactosides necessary for LecA binding. The optimized divalent LecA ligands showed improved stability and were up to 1000-fold more soluble. Importantly, these properties now enabled their biological characterization. The lead compound L2 potently inhibited LecA binding to lung epithelial cells, restored wound closure in a scratch assay and reduced the invasiveness of P. aeruginosa into host cells. 相似文献