On the formation of the [M ? OH]+ ion in m-nitrobenzaldoxime. evidence for a cyclohexadiene-type intermediate ion

In m-nitrobenzaldoxime a strongly enhanced loss of OH? is observed as compared with the p-nitro compound. Evidence is presented for a fragmentation mechanism involving the formation of a cyclohexadiene-type intermediate ion formed by a rearrangement of the hydroxyl hydrogen to the phenyl ring.     

Analysis of anthracycline antitumour drugs in tissues and body fluids using liquid chromatography

Anthracyclines, with doxorubicin as the major representative, are amongst the most important chemotherapeutic agents used in cancer therapy. In order to reduce the severe side effects associated with their use, and to increase therapeutic efficacy, analogue development still continues, and analytical requirements change concomitantly. The available methods for bioanalysis of anthracyclines are summarized, with emphasis on high-performance liquid chromatography. Attention is paid to sample pretreatment, the possibilities of liquid—liquid and solid-phase extraction, and the chromatographic behaviour of the anthracyclines.     

The Structure of the (Outer) Automorphism Group of a Bieberbach Group

Referring to Tits alternative, we develop a necessary and sufficient condition to decide whether the normalizer of a finite group of integral matrices is polycyclic-by-finite or is containing a non-Abelian free group. This result is of fundamental importance to conclude whether the (outer) automorphism group of a Bieberbach group is polycyclic-by-finite or has a non-cyclic free subgroup.     

A risk model driven by Lévy processes

We present a general risk model where the aggregate claims, as well as the premium function, evolve by jumps. This is achieved by incorporating a Lévy process into the model. This seeks to account for the discrete nature of claims and asset prices. We give several explicit examples of Lévy processes that can be used to drive a risk model. This allows us to incorporate aggregate claims and premium fluctuations in the same process. We discuss important features of such processes and their relevance to risk modeling. We also extend classical results on ruin probabilities to this model. Copyright © 2003 John Wiley & Sons, Ltd.     

Implementation of a separate fluid-neutral energy equation in SOLPS-ITER and its impact on the validity range of advanced fluid-neutral models

In plasma edge transport codes for nuclear fusion devices, fluid-neutral models offer an interesting alternative to the currently used kinetic Monte Carlo simulations, especially for cases of high ion-neutral collisionality. In this paper, we elaborate a separate neutral energy equation in the state-of-the-art SOLPS-ITER code suite, which previously assumed perfect ion-neutral temperature equilibration. Furthermore, we study the coupled plasma-neutral solutions for a range of divertor operating regimes, proving the validity of these fluid-neutral models for high-recycling and detached regimes.     

Non-Abelian Random Polygons: A New Model in Statistical Physics

A model in statistical physics is presented based on assigning non-Abelian phase factors to the turning points of polygons in three dimensions. This model allows for an exact solution and exhibits an unexpectedly rich phase structure. The model as well as the solution are obtained by a generalization of the methods of Kac and Ward and by mapping the problem to a Markov process as was done by Feynman for the two-dimensional Ising model     

Rod-climbing effect in Newtonian fluids

When a rotating rod is brought into a polymer melt or concentrated polymer solution, the meniscus climbs the rod. This spectacular rod climbing is due to the normal stresses present in the polymer fluid and is thus a purely non-Newtonian effect. A similar rod climbing of an interface between two fluids has therefore been taken as a signature that one of the fluids exhibits normal stress effects. We show here, however, that the effect can occur with simple Newtonian fluids: it occurs when a Taylor-Couette instability happens in the less viscous of the two liquids but not in the more viscous one.