全文获取类型
收费全文 | 152篇 |
免费 | 3篇 |
国内免费 | 5篇 |
专业分类
化学 | 109篇 |
晶体学 | 2篇 |
力学 | 1篇 |
数学 | 27篇 |
物理学 | 21篇 |
出版年
2022年 | 4篇 |
2021年 | 5篇 |
2020年 | 1篇 |
2019年 | 3篇 |
2018年 | 2篇 |
2017年 | 4篇 |
2016年 | 2篇 |
2015年 | 1篇 |
2014年 | 2篇 |
2013年 | 4篇 |
2012年 | 12篇 |
2011年 | 9篇 |
2010年 | 6篇 |
2009年 | 8篇 |
2008年 | 6篇 |
2007年 | 11篇 |
2006年 | 8篇 |
2005年 | 16篇 |
2004年 | 8篇 |
2003年 | 3篇 |
2002年 | 4篇 |
2001年 | 3篇 |
2000年 | 3篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1996年 | 4篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1993年 | 3篇 |
1992年 | 1篇 |
1991年 | 3篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1978年 | 1篇 |
排序方式: 共有160条查询结果,搜索用时 0 毫秒
21.
22.
Valdés A Prosmiti R Villarreal P Delgado-Barrio G 《The Journal of chemical physics》2011,135(24):244309
Benchmark, full-dimensional calculations on the ground and excited vibrational states for the tetra-, and penta-atomic weakly bound He(2,3)ICl complexes are reported. The representation of the potential energy surfaces includes three-body HeICl potentials parameterized to coupled-cluster singles, doubles, and perturbative triples ab initio data. These terms are important in accurately describing the interactions of such highly floppy systems. The corresponding 6D/9D computations are performed with the multi-configuration time dependent Hartree method, using natural potential fits, and a mode combination scheme to optimize the computational effort in the improved relaxation calculations. For these complexes several low-lying vibrational states are computed, and their binding energies and radial/angular probability density distributions are obtained. We found various isomers which are assigned to different structural models related with combinations of the triatomic isomers, like linear, T-shaped, and antilinear ones. Comparison of these results with recent experimental data is presented, and the quantitative deviations found with respect to the experiment are discussed. 相似文献
23.
T. González-Lezana G. Delgado-Barrio P. Villarreal F.X. Gadéa 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,20(2):227-232
The stabilization method is applied to the case of interacting resonances in the photo-dissociation of van der Waals clusters
composed by a rare gas atom bound to a dihalogen molecule. The study of an illustrative two-dimensional model consisting in
a T-shaped NeI2 molecule shows the adequacy of the method whenever the projection of the stabilization wave functions on the assumed prepared
initial state is accounted for. The agreement of the fragmentation cross-sections with some previous results using the effective
resolvent method and accurate close-coupling calculations is excellent. The method reveals its utility as a complementary
tool since allows, through the analysis of the stabilization wave function in terms of zero-order levels, a precise characterization
of the resonant states involved.
Received 5 April 2002 / Received in final form 24 May 2002 Published online 19 July 2002 相似文献
24.
Nitration of estrone has been investigated with different types of metal salts in the presence of solid surfaces under various conditions. 相似文献
25.
Rafael H. Villarreal 《manuscripta mathematica》1998,97(3):309-317
Let G be a graph such that none of its components is bipartite. We describe the facets of the cone generated by the columns of
the incidence matrix of G. Let k[G] be the subring generated by the monomials of degree two defining the edges of G, where k is a field. Some estimates for the a-invariant of k[G] are shown when G is the cone of a normal connected non bipartite graph or G is the join of two normal connected non bipartite graphs.
Received: 24 July 1997 / Revised version: 3 March 1998 相似文献
26.
Frank D. Blum Jane E. Dickson Wilmer G. Miller 《Journal of Polymer Science.Polymer Physics》1984,22(2):211-221
The effect of diluents and temperature on segmental motion in poly(vinyl acetate) was investigated by both NMR and ESR spectroscopy. Three classes of diluents were studied: chloroform, a thermodynamically good solvent; water, a poor solvent which slightly swells the polymer and lowers its glass transition temperature; and decane, a nonsolvent so poor it does not appear to swell the polymer nor lower the calorimetric glass transition temperature. At all temperatures investigated each type of diluent increased the segmental motion of the polymer over that of the bulk sample. Under the conditions studied, 13C and 2H NMR and nitroxide spin-label ESR data gave similar views of segmental motion of the polymer, indicating that in this amorphous polymer the segmental motion of the polymer may be safely inferred from spin-label data. 相似文献
27.
28.
The main aim of this study was to present evidence of the ways in which different media have conditioned and dramatically reorganized education, in general, and mathematics education, in particular. After an introduction of the theme, we discuss the epistemological perspective that provides the foundation for our analysis: the notion of humans-with-media. Then, we briefly illustrate how the medium is related to the scientific production of mathematical knowledge. We take a detour into the world of art to examine how devices and instruments have historically been associated with the production of mathematical knowledge. Then, we review studies on the history of education to show how traditional media were introduced into schools and have influenced education. In particular, we examine how devices such as blackboards and notebooks, which were novelties a 100 years ago, came to be accepted in schools and the mathematical activities that were promoted with their use. Finally, we discuss how information technology has changed education and how the Internet may have an impact on mathematics education comparable to that of the notebook over a century ago. 相似文献
29.