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91.
Nagendranath Mahata V. Vishwanathan 《Journal of molecular catalysis. A, Chemical》1997,120(1-3):267-270
Kinetics of vapor phase hydrogenation of phenol to cyclohexanone over Pd/MgO system has been studied in a flow microreactor under normal atmospheric pressure. The reaction rate is found to be negative order with respect to the partial pressure of phenol and has increased from −0.5 to 0.5 with increasing temperature (473 to 563 K). The apparent activation energy (Ea) of the process is found to be close to 65 kJ per mol. On the basis of kinetic results a surface mechanism is proposed. 相似文献
92.
Photobleaching was studied during recording of confocal scanning laser microscopy. Studies on fluorescent gels of FITC-labeled
dextran were used to evaluate differential bleaching along thez-axis. Differential bleaching along the z-axis was observed and it was seen that this was related to the numerical aperture
of the objective in use. This points to the conclusion that photon energy flux density is an important parameter in photobleaching.
To check if photon energy flux density heterogeneity is affected by local variation in the refractive index of the sample,
photobleaching rates were calculated for different fluorescent objects (sections of seeds, animal cells stained with nuclear
stains, immunocytochemistry preparations) and a pronounced similarity was found between photobleaching rates and DIC images. 相似文献
93.
94.
Ya. V. Fattakhov M. F. Galyautdinov T. N. L’vova I. B. Khaibullin 《Technical Physics》1997,42(12):1457-1459
The first results regarding the formation of a two-dimensional periodic structure of local melting regions on a silicon surface
upon pulsed light irradiation are presented. The conditions are established, and the mechanism of the formation of such structures
is discussed.
Zh. Tekh. Fiz. 67, 97–99 (December 1997) 相似文献
95.
F. A. van Goor S. V. Mitko V. N. Ochkin W. J. Witteman 《Journal of Russian Laser Research》1997,18(2):107-120
Experimental and theoretical results are presented on an XeF(C?A) blue-green laser driven by 5-kJ energy. The laser was pumped by a ferrite-induced discharge of 90 cm in length. The output energy of 0.22 J was obtained with a plane-parallel resonator. A program to simulate laser operation has been developed. Numerical results for a wide range of conditions are compared with experiments performed by us and by other authors. It is found that intracavity refractive losses limit laser operation for XeF pressures above 3 torr. The laser efficiency strongly depends on the discharge-to-cavity length ratio. Possible ways to increase the laser power and efficiency are discussed. 相似文献
96.
97.
98.
本文研究了胆绿素的表面增强拉曼光谱。结果表明,在溶液酸度不同时,拉曼光谱特征频率的变化表现出胆绿素的质子化。铜离子与胆绿素的相互作用实验结果说明金属铜离子可与胆绿素生成金属配合物。 相似文献
99.
100.
Yoshiaki Murata Cheng-Huang Lin Totaro Imasaka 《Fresenius' Journal of Analytical Chemistry》1993,346(6-9):543-544
Summary A supersonic jet spectrum of 9,10-dichloroanthracene is measured by stimulated-emission-pumping fluorescence dip spectrometry and conventional fluorescence spectrometry. The performance obtained is compared for these spectrometric methods, providing same information concerned with the energy level of the ground state. The former is more preferential for measurement of a high-resolution spectrum, since the spectral resolution is determined by the linewidth of the dumping laser. On the other hand, the latter is more preferential for measurement with better sensitivity at the expense of the spectral resolution, since the fluorescence throughput can be improved by increasing the slit width of the monochromator.Dedicated to Professor Dr. Wilhelm Fresenius on the occasion of his 80th birthday 相似文献