Size-dependent photodegradation of CdS particles deposited onto TiO2 mesoporous films by SILAR method

Carbonaceous nanomaterials, such as fullerene C₆₀, carbon nanotubes, and their functionalized derivatives have been demonstrated to possess high sorption capacity for organic and heavy metal contaminants, indicating a potential for remediation application. The actual application of these nanomaterials, however, is often hindered by the high cost of materials and the limited understanding of their mobility in porous media. In this work, carbon nano-onions (CNOs), a relatively new addition to the carbonaceous nanomaterials, were synthesized in a cost-effective way using a laser-assisted combustion synthesis process, and carefully characterized for their potential remediation application. Surface oxidized CNOs possessed 10 times higher sorption capacity than C₆₀ for heavy metal ion contaminants including Pb²⁺, Cu²⁺, Cd²⁺, Ni²⁺, and Zn²⁺. CNOs aqueous suspension can be very stable in NaCl solution at ionic strength up to 30?mM and CaCl₂ solution at ionic strength up to 4?mM CaCl₂ when pH ranged from 5 to 9, which are consistent with environmentally relevant conditions. Interactions of CNOs with iron oxide and silica surfaces under favorable condition were found to be electrostatic in origin. Mobility of CNOs in quartz sands was controlled by electrolyte type and concentration. Approximately 4.4, 25.1, and 92.5?% of injected CNO mass were retained in the sand column in ultrapure water, 1?mM?NaCl, and 1?mM CaCl₂ solutions, respectively.     

Liquid-phase EPR, ENDOR, and TRIPLE resonance studies on corrole and isocorrole cation radicals

The “Contracted Porphyrins” corrole and the recently synthesized isocorrole (as octaethyl derivatives) represent novel porphyrinoid macrocycles of biochemical interest. The radical cations of the free-bases of both corrole and its isomer are studied by EPR, ENDOR, and TRIPLE resonance in liquid solution to measure isotropic hyperfine couplings including signs. They yield detailed information of the electronic structure of the radical cations. The experimental findings are compared with results of all-valence-electrons self-consistent field molecular orbital calculations (RHF-INDO/SP). The comparison shows that the free-bases of corrole and isocorrole undergo protonation when oxidized to cation radicals in CH₂Cl₂ solution. Excellent agreement of the measured and calculated spin density distributions is achieved for the protonated dication radicals, which exhibit the C₂ symmetry observed for the hyperfine structure. The analysis of the hyperfine data discriminates against NH tautomerism as the sole source for an effective C₂ symmetry of the macrocycle.     

Shape change and fast M1 transitions in Kr

A shape transition from a probably asymmetric shape at low excitation to a more axial-symmetric shape above 21/2⁺ has been found in ⁸¹Kr. This shape change and the drastic increase of the M1 transition probabilities above spin 21/2 are attributed to the alignment of two g_9/2 protons.     

Detection of a flow induced magnetic field eigenmode in the riga dynamo facility

In a closed volume of molten sodium an intense single-vortex-like helical flow has been produced by an outside powered propeller. At a flow rate of 0.67 m(3)/s a slowly growing magnetic field eigenmode was detected. For a slightly lower flow, additional measurements showed a slow decay of this mode. The measured results correspond satisfactorily with numerical predictions for the growth rates and frequencies.     

A short,highly efficient synthesis of coenzyme Q(10)

The most efficient synthesis reported to date of ubiquinone (CoQ10) is described. A sequence consisting of six operations is involved which leads to crystalline material in an overall yield of >64%.     

Properties and applications of precision oligomer materials; where organic and polymer chemistry join forces

Precise oligomeric materials constitute a growing area of research with implications for various applications as well as fundamental studies. Notably, this field of science which can be termed macro-organic chemistry, draws inspiration from both traditional polymer chemistry and organic synthesis, combining the molecular precision of organic chemistry with the materials properties of macromolecules. Discrete oligomers enable access to unprecedented materials properties, for example, in self-assembled structures, crystallization, or optical properties. The degree of control over oligomer structures resembles many biological systems and enables the design of materials with tailored properties and the development of fundamental structure–property relationships. This Review highlights recent developments in macro-organic chemistry from synthetic concepts to materials properties, with a focus on self-assembly and molecular recognition. Finally, an outlook for future research directions is provided.