Secondary Metabolites with Anti-Inflammatory from the Roots of Cimicifuga taiwanensis

The genus Cimicifuga is one of the smallest genera in the family Ranunculaceae. Cimicifugae Rhizoma originated from rhizomes of Cimicifuga simplex, and C. dahurica, C. racemosa, C. foetida, and C. heracleifolia have been used as anti-inflammatory, analgesic and antipyretic remedies in Chinese traditional medicine. Inflammation is related to many diseases. Cimicifuga taiwanensis was often used in folk therapy in Taiwan for inflammation. Phytochemical investigation and chromatographic separation of extracts from the roots of Cimicifuga taiwanensis has led to the isolation of six new compounds: cimicitaiwanins A–F (1–6, respectively). The structures of the new compounds were unambiguously elucidated on the basis of extensive spectroscopic data analysis (1D- and 2D-NMR, MS, and UV) and comparison with the literature data. The effect of some isolates on the inhibition of NO production in lipopolysaccharide-activated RAW 264.7 murine macrophages was evaluated. Of the isolates, 3–6 exhibited potent anti-NO production activity, with IC₅₀ values ranging from 6.54 to 24.58 μM, respectively, compared with that of quercetin, an iNOS inhibitor with an IC₅₀ value of 34.58 μM. This is the first report on metabolite from the endemic Taiwanese plant-C. taiwanensis.     

Numerical study of InGaN tandem solar cells with intermediate bands

Theoretical investigations of InGaN tandem solar cells with intermediate bands (IBs) have been conducted through calculating the diode equation taking into account the radiative and nonradiative recombination currents. The calculated maximum ef?ciencies of the double‐junction cell with one IB in each subcell are 57.85% and 68.37% under AM1.5G one‐sun and 46000‐sun illuminations, respectively. It has also been observed that the combined device with the top‐cell bandgaps of 2.9–3.4 eV (2.6–3.4 eV for full concentration) may have an opportunity to realize the application of over 50% efficiency. We suggest that the optimized width of the IB layer be designed in the range of 1–6 μm if its absorption coefficient is 10⁴–10⁵ cm^–1 in the IB region.     

Experimental study of wave propagation through a rapidly createdplasma

Frequency upconversion and converting a CW source microwave into a frequency upshifted and chirped periodic pulse have been demonstrated by two experiments. In the first one, the CW source microwave propagates through a periodically microwave-discharged plasma. The CW source microwave is converted into a periodic pulse having upshifted carrier frequency. The second one uses a high-voltage (~100-kV) DC discharge to generate a dense plasma suddenly between two parallel plates. A frequency upshifted and chirped pulse (~2 ns) converting from the CW source microwave interacting with the suddenly created plasma is observed. The central frequency (~6.4 GHz) of the pulse is upshifted from the frequency (~4.7 GHz) of the source wave by about 40%. Moreover, frequency components which are upshifted as high as 80% are also observed     

Interference patterns of zonal gratings: Application to rheology of polymers

Résumé Cet article présente la théorie des franges de moiré créées par des réseaux circulaires de pas égal ou légérement différent. Nous avons établi les équations différentielles reliant les lignes de reférence et les lignes du modèle avec les franges de moiré produites par la superposition de ces deux familles de lignes. Les franges de moiré fournissent les ellipses de déplacement dans un champ de déformation uniforme. Ces franges ont été utilisées pour mésurer simultanément la complaisance de fluage et le coefficient de contraction latérale d'une matière viscoelastique linéaire le long de son spectre viscoélastique entier.On est arrivé à demontrer que le coefficient de la contraction latérale est une fonction monotone croissante qui tend asymptotiquement vers la valuer limite de 0.5 valable pour toute matière incompressible. Les fonctions caractéristiques de la complaisance de fluage à la traction et le coefficient de contraction latérale sont suffisantes pour la définition viscoélastique complète de la matière.Les résultats obtenus ont été comparés avec succès à ceux qui ont été déduits d'une méthode indirecte qui utilise une seule fonction caractéristique le long du spectre viscoélastique entier de la matière et la valeur initiale d'une autre fonction.     

Transmission Characteristics of 90° Bent Photonic Crystal Waveguides

There are several key factors that affect the transmission characteristics of the 90° (L-shaped) bent photonic crystal waveguides. The first factor is the direct coupling efficiency from the incident lights into the waveguides. The second one is the bandgap deviations of the photonic crystals. And the third factor is the optical reflections in the bent corners. In this article, we compare three types of L-shaped bent photonic crystal waveguides. One is the original type, which has an abrupt right-angle bend. Another is an improved 90° bend with a 45°-mirror. The other is an L-shaped bent photonic crystal waveguide with a 45°-transitional section. We investigate their respective frequency responses and observe the improvements in the total transmission efficiencies provided by the latter types.     

Free-space Fresnel diffraction for the approximation of fractional Fourier transform

Fractional Fourier transformation of an object can be approximated by the object's free-space Fresnel diffraction pattern under some restricted conditions and plane wave illumination according to Hua's method. A better approximation is achieved under least-squared conditions developed in this paper. Simulation results verify that our theoretical development works for any fractional order a compared with the previous approach.     

Evaluation of natural recharge of Chingshui geothermal reservoir using tritium as a tracer

Naturally existing tritium in groundwater was applied as a tracer to evaluate the natural recharge of the Chingshui geothermal reservoir. The residence time (or, age) of Chingshui geothermal water was first determined with tritium data at 15.2 and 11.3 year using the plug flow and dispersive model, respectively. The annual natural recharge was then estimated by combining the use of the residence time and the fluid-in-place of the Chingshui geothermal reservoir. The natural recharge for Chingshui geothermal reservoir was estimated at 5.0 × 10⁵ and 6.7 × 10⁵ m³ year^?1 using the plug flow and dispersive model, respectively. Chingshui geothermal water is largely from a fractured zone in the Jentse Member of the Miocene Lushan Formation. The dispersive model more adequately represents the fracture flow system than the simple plug flow model.     

Radical–anion coupling through reagent design: hydroxylation of aryl halides

The design and development of an oxime-based hydroxylation reagent, which can chemoselectively convert aryl halides (X = F, Cl, Br, I) into phenols under operationally simple, transition-metal-free conditions is described. Key to the success of this approach was the identification of a reducing oxime anion which can interact and couple with open-shell aryl radicals. Experimental and computational studies support the proposed radical-nucleophilic substitution chain mechanism.

The design and development of an oxime-based hydroxylation reagent, which can chemoselectively convert aryl halides (X = F, Cl, Br, I) into phenols under operationally simple, transition-metal-free conditions is described.