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Nishit Goradia Christoph Wiedemann Dr. Christian Herbst Dr. Matthias Görlach Prof. Dr. Stefan H. Heinemann Dr. Oliver Ohlenschläger Dr. Ramadurai Ramachandran 《Chemphyschem》2015,16(4):739-746
An efficient approach to NMR assignments in intrinsically disordered proteins is presented, making use of the good dispersion of cross peaks observed in [15N,13C′]‐ and [13C′,1HN]‐correlation spectra. The method involves the simultaneous collection of {3D (H)NCO(CAN)H and 3D (HACA)CON(CA)HA} spectra for backbone assignments via sequential HN and Hα correlations and {3D (H)NCO(CACS)HS and 3D (HS)CS(CA)CO(N)H} spectra for side‐chain 1H and 13C assignments, employing sequential 1H data acquisitions with direct detection of both the amide and aliphatic protons. The efficacy of the approach for obtaining resonance assignments with complete backbone and side‐chain chemical shifts is demonstrated experimentally for the 61‐residue [13C,15N]‐labelled peptide of a voltage‐gated potassium channel protein of the Kv1.4 channel subunit. The general applicability of the approach for the characterisation of moderately sized globular proteins is also demonstrated. 相似文献
23.
Philipp Stock Nicole Spintig Juliane Scholz Jan Dirk Epping Christian Oelsner Dennis Wiedemann 《Journal of Coordination Chemistry》2015,68(17-18):3099-3115
This work presents a detailed study of the photo-induced spin-state dynamics of the photochromic iron(II) complex 1, where the metal ion is in the field of a tripodal hexa-imine ligand with protolysable phenol groups. The nature of the complex’s ground state has been identified as a spin singlet by 1H NMR and steady-state UV/vis spectroscopies, and its distorted octahedral structure was analyzed via crystal structure determination. Sub-picosecond and nanosecond time-resolved laser flash photolysis experiments identify the long-lived quintet state of 1 as the selective product of photoexcitation in the UV/vis spectral region. Thermal barriers of spin-state interconversion as a function of solvent and added base are derived from temperature-dependent rates of transient decay. Ground-state recovery is found to be significantly affected by the solvent and is strongly enhanced, in particular, by base-driven solvolysis of the ligand’s phenol groups. Partial spontaneous deprotonation of the phenolic hydroxyl groups of 1 seems to prevail on metal oxide surfaces, i.e. on alumina. Composite materials, like 1 at Al2O3, that retain the characteristic spectral features of the parent iron(II) complex can be readily obtained by wet impregnation of hydrous alumina with solutions of 1. 相似文献
24.
Metal/superconductor/semiconductor (Ag/Hg-1212/CdSe) hetero-nanostructures have been fabricated using pulse-electrodeposition
technique and are characterized by X-ray diffraction (XRD), full-width at half-maximum (FWHM) and scanning electron microscopy
(SEM) studies. The junction capacitance of Ag/Hg-1212, Hg-1212/CdSe and Ag/Hg-1212/CdSe heterojunctions is measured in dark
and under laser irradiation at room temperature. The nature of the junction formed and built-in-junction potentials were determined.
The increase in carrier concentration across the junction due to photo-irradiation has been observed. 相似文献
25.
One of the innovative technological directions for the high-temperature superconductors has been persued by fabricating the
heteroepitaxial multilayer structures such as superconductor-semiconductor heterostructures. In the present investigation,
metal/superconductor/semiconductor (Ag/Tl-2223/CdSe) hetero-nanostructures have successfully been fabricated using dc electrodeposition
technique and were characterized by X-ray diffraction (XRD), full-width at half-maximum (FWHM) and scanning electron microscopy
(SEM) studies. The measurement of junction capacitance as a function of biasing voltage was used for the estimation of junction
built-in-potential (V
D) and to study the charge distribution in a heterojunction. The Mott-Schottky plots were measured for each junction in dark
and under the photo-irradiation. The effect of laser irradiation on C-V characteristics of hetero-nanostructure has been studied. 相似文献
26.
2-kaon and 2-pion correlation functions for an expanding thermalized source are compared. In the Yano-Koonin-Podgoretskii parametrization of the correlation function, the HBT radius parameters are shown to obeyM ∟-scaling in the absence of collective transverse flow. This scaling is broken by transverse flow. An accurate comparison of pion and kaon correlations can thus resolve issue whether the observedM ∟-dependence of the transverse radius parameter is due to transverse collective flow or other transverse gradients. Effects from resonance decays are shortly discussed. 相似文献
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Jonathan Rosenhead Paul Wiedemann 《The Journal of the Operational Research Society》1979,30(9):833-834
Robustness analysis has not previously incorporated explicitly the reactive response of other decision makers to the action of the initial decision maker. This note presents an extension of robustness analysis to incorporate this response of the decisional environment. 相似文献
30.
Conditions for adsorption of C19- and C21-steroids on florisil were testet with radioactive steroids. By this procedure the glucuronides of Androsterone, Etiocholanolone, Dehydroepiandrosterone and Testosterone and also Tetrahydrocortisol and Tetrahydrocortisone were isolated from urin. Combination of a florisil column and a column filled with amberlite, which adsorbs conjugated steroids, makes it possible to determine glucurone- and sulfate esters separately. Compared with the common extraction with organic solvents, this adsorption of hydrolysed steroids on florisil and conjugated steroids (sulfates) to amberlite is more simple, less expensive and better reproducible. 相似文献