Ethanol adsorption, decomposition and oxidation on Ir(111): a high resolution XPS study.

Ethanol (C(2)H(5)OH) adsorption, decomposition and oxidation is studied on Ir(111) using high-energy resolution, fast XPS and temperature-programmed desorption. During heating of an adsorbed ethanol layer a part of the C(2)H(5)OH(ad) desorbs molecularly, and another part remains on the surface and decomposes around 200 K; these two decomposition pathways are identified, as via acetyl (H(3)C--C=O) and via CO(ad)+CH(3ad), respectively. Acetyl and CH(3ad) decompose around 300 K into CH(ad) (and CO(ad)). CH(ad) decomposes forming C(x) and H(2) around 520 K. In the presence of O(ad) an acetate intermediate is formed around 180 K, as well as a small amount of CH(3ad) and CO(ad). Acetate decomposes between 400-480 K into CO(2), H(2)(/H(2)O) and CH(ad).     

On the local density problem for graphs of given odd-girth

Erdős conjectured that every n-vertex triangle-free graph contains a subset of vertices that spans at most edges. Extending a recent result of Norin and Yepremyan, we confirm this conjecture for graphs homomorphic to so-called Andrásfai graphs. As a consequence, Erdős' conjecture holds for every triangle-free graph G with minimum degree and if the degree condition can be relaxed to . In fact, we obtain a more general result for graphs of higher odd-girth.     

Dynamic regulation of photoprotection determines thermal tolerance of two phylotypes of Symbiodinium clade A at two photon fluence rates

Coral bleaching is the manifestation of the dysfunction of the symbiosis between scleractinian corals and dinoflagellates of the diverse genus Symbiodinium and is induced by elevated temperatures and high irradiance. We investigated the photophysiological response of two genetically distinct Symbiodinium subtypes within clade A upon exposure to elevated temperatures at two light intensities for 3 weeks. While both subtypes displayed a characteristic photoacclimation to high light (HL) (decrease in light-harvesting pigments, lower photochemical efficiency of photosystem II, increased xanthophyll pool sizes), the tolerance toward thermal stress clearly differed between the two subtypes. Symbiodinium Ax was highly susceptible to chronic photoinhibition at temperatures ≥30°C, which was exacerbated under HL conditions. A1 showed a capacity for photoacclimation and high thermal tolerance, which might be related to higher cellular concentrations of photoprotective xanthophylls and the low-molecular antioxidant glutathione (GSx) along with the dynamic regulation of these photoprotective pathways. Whereas HL conditions induced both accumulation of diatoxanthin and GSx, thermal stress further stimulated xanthophyll cycling, which might compensate for diminished amounts of GSx at elevated temperatures. Our results show that the two clade A subtypes clearly differ in their strategies to cope with thermal stress in combination with high irradiance.     

On how surfactant depletion during foam generation influences foam properties

Although it is known that foaming a surfactant solution results in a depletion of the surfactant in the bulk phase, this effect is often overlooked and has never been quantified. Therefore, the influence of surfactant depletion on foam properties using solutions of the two nonionic surfactants, n-dodecyl-β-D-maltoside (β-C(12)G(2)) and hexaethyleneglycol monododecyl ether (C(12)E(6)), were investigated. These investigations were conducted in two steps. First, different foam volumes were generated with the same surfactant solution at a concentration of c = 2 cmc. It was found that the higher the foam volume, the larger the surfactant depletion. Second, two different bulk concentrations (c = 2 and 1.33 cmc) were used for the generation of 50 and 110 mL of foam, respectively. For a foam volume of 50 mL, no differences were observed, whereas generating 110 mL led to different results. The surfactant loss in the bulk solution was measured via surface tension measurements and then compared to the results of purely geometric considerations that take into account the amount of interface created in the foam. Both results were in very good agreement, which means that surfactant depletion can be calculated in the way suggested here. Under conditions where depletion plays a role, our approach can also be used to estimate the bubble size of a foam of known volume by measuring the surfactant concentration in the bulk solution after foaming.     

Generation of Superstable,Monodisperse Microbubbles Using a pH‐Driven Assembly of Surface‐Active Particles

Bubbling to the surface : Microscale gas bubbles can be generated in a microfluidic device by simultaneously injecting CO₂ and a dispersion of particles whose hydrophobicity increases as the pH value decreases. The CO₂ dissolves rapidly out of the bubbles, which shrink, and render the dispersion increasingly acidic. This drives the particles to the bubble surface where they form a type of “armor” against further dissolution (see picture).

     

Dynamic doping and degradation in sandwich-type light-emitting electrochemical cells

Photoluminescence spectroscopy has been performed in situ during device operation and after switch-off on ionic transition metal complex (iTMC)-based sandwich-type light-emitting electrochemical cells (LECs). It is demonstrated that the photoluminescence of the LECs decreases with increasing operating time. For operating times up to three hours the decline in photoluminescence is fully recoverable after switching off the bias. These results imply that doping of the iTMC layer is responsible, not only, for the turn-on of LECs but also for their lifetimes.     

Simulation of the detoxification of paracetamol using on-line electrochemistry/liquid chromatography/mass spectrometry

On-line electrochemistry/liquid chromatography/mass spectrometry was used to simulate the detoxification mechanism of paracetamol in the body. In an electrochemical flow-through cell, paracetamol was oxidized at a porous glassy carbon working electrode at a potential of 600 mV vs. Pd/H₂ with formation of a quinoneimine intermediate. The quinoneimine further reacted with glutathione and/or N-acetylcysteine to form isomeric adducts via the thiol function. The adducts were characterized on-line by liquid chromatography/mass spectrometry. These reactions are similar to those occurring between paracetamol and glutathione under catalysis by cytochrome P450 enzymes in the body. Awarded a Poster Prize on the occasion of the Conference of the German Mass Spectrometric Society (DGMS) in Mainz, March 5–8, 2006.