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91.
We consider the problem of managing inventory and production capacity in a start-up manufacturing firm with the objective of maximising the probability of the firm surviving as well as the more common objective of maximising profit. Using Markov decision process models, we characterise and compare the form of optimal policies under the two objectives. This analysis shows the importance of coordination in the management of inventory and production capacity. The analysis also reveals that a start-up firm seeking to maximise its chance of survival will often choose to keep production capacity significantly below the profit-maximising level for a considerable time. This insight helps us to explain the seemingly cautious policies adopted by a real start-up manufacturing firm.  相似文献   
92.
This article examines elementary students' perspectives on the engagement potential of particular mathematical problems and students' views on their general classroom problem activities. Third-, fifth-, and seventh-grade children from different reform-oriented classrooms were individually interviewed about (a) how they would improve their classroom problem-solving activities and (b) the problems they find the most and least potentially engaging when presented with a range of routine and nonroutine problems. The children requested more relevant, meaningful, and interesting problem experiences in their classrooms, and the fifth and seventh graders requested more representational materials. The children's criteria for determining potentially engaging and nonengaging problems primarily pertained to problem structure and perceived cognitive demands. The nonroutine examples that focused on important reasoning processes and did not involve computation had the greatest engagement potential, while the computational problems had the least appeal.  相似文献   
93.
    
Carbon nanodots (C-dots) are promising photoluminescent nanomaterials for biomedical applications. Among them, PEG-derived C-dots demonstrate exceptional photoluminescence and passivation properties, making them particularly attractive for use in the biomedical field. In this article, we present the synthesis of photoluminescent S,N-doped PEG-derived carbon dots that are stable at ambient temperature and can be produced using an easy hydrothermal technique. To synthesize the carbon dots, the non-hazardous polymer polyethylene glycol (PEG) was used as the sole precursor rather than any other potentially hazardous compounds. The absence of L-cysteine in the reaction mixture resulted in carbon dots with no significant absorbance in the visible region but exhibited photoluminescence properties with a maximum excitation and emission at 343 and 452 nm, respectively. However, the addition of L-cysteine resulted in a visible absorbance and a red shift in both the maximum excitation and emission, at around 435 and 503 nm, respectively. The Fourier transform infrared spectroscopy (FTIR) analysis provided evidence for the presence of -SH, -SO2, -NH2, and CON-H bond stretching after the addition of L-cysteine, suggesting possible S,N-doping of the carbon dots, which likely caused the observed changes in photoluminescence properties. These findings contribute to the understanding of S,N-doping in carbon dots and highlight their potential applications in optoelectronics, sensing, and biomedical imaging.  相似文献   
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95.
A computer-controlled chemiluminescence (CL) instrument incorporating a differential scanning calorimeter was used to simultaneously acquire photochemical and enthalpic data for poly(N-vinyl-2-pyrrolidone) (PVP). Samples were subjected to a linear temperature ramp under nitrogen and their luminescence response recorded. The resultant dynamic CL peak is attributable to the decomposition of hydroperoxide groups and the subsequent mutual termination of secondary polymer peroxyl radicals. It is shown that dynamic CL can be used to characterize the level of oxidation in PVP, which in commercial samples, may be partly related to the level of residual polymerization inititor and to the drying process. The temperature at which maximum CL emission occurs correlates with the glass transition temperature (Tg) of the polymer and increases with increasing molecular weight. A marked increase in the Tg of PVP occurs after it is aged in air for 24 h at 120°C. This is due to the loss of adsorbed moisture from the polymer which was confirmed by thermogravimetric analysis. Oxidation profiles of PVP were obtained by plotting the integrated CL peak area as a function of aging time. The profiles are compared with data obtained from isothermal CL and viscosity measurements. Gas perturbation experiments suggest that when drying PVP under nitrogen at elevated temperatures significant populations of longlived macroalkyl radicals are formed which can peroxidize the polymer on exposure to air. © 1993 John Wiley & Sons, Inc.  相似文献   
96.
Motivated by a real problem, this study aims to develop models to conduct stress testing on credit card portfolios. Two modelling approaches were extended to include the impact of lenders’ actions within the model. The first approach was a regression model of the aggregate losses based on economic variables with autocorrelations of the errors. The second approach was a set of vintage-level models that highlighted the months-on-book effect on credit losses. A case study using the models was described using South African credit card data. In this case, the models were used to stress test the credit card portfolio under several economic scenarios.  相似文献   
97.
The value of the customer has been widely recognized in terms of financial planning and efficient resource allocation including the financial service industry. Previous studies have shown that directly observable information can be used in order to make reasonable predictions of customer attrition probabilities. However, these studies do not take full account of customer behavior information. In this paper, we demonstrate that efficient use of information can add value to financial services industry and improve the prediction of customer attrition. To achieve this, we apply an orthogonal polynomial approximation analysis to derive unobservable information, which is then used as explanatory variables in a probit–hazard rate model. Our results show that derived information can help our understanding of customer attrition behavior and give better predictions. We conclude that both researchers and the financial service industry should gather and use derived financial information in addition to directly observable information.  相似文献   
98.
Phase-consistent electronic transition dipole moment functions were calculated (as a function of internuclear separation) for the 80 dipole selection rule allowed transitions in the manifold of states of NaK treated previously [W. J. Stevens, D. D. Konowalow, and L. B. Ratcliff, (1984) J. Chem. Phys. 80, 1215–1224]. Agreement was found with experimental determinations of the 21Π-11Σ+ transition. Agreement of the asymptotic values with experimental and previous theoretical determinations of corresponding atomic transition moments suggests that the present computations may be relatively reliable. The positions of a number of satellite bands are predicted from the potential energy difference curves.  相似文献   
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